ATTACHMENT B 
Weekly-Monthly-Annual Sampling Program and Analyses. 
 
Annual Sampling Program 
Analysis 
Method 
Container 
preservative 
Holding 
time 
sample 
type 
Turn-
Around 
Time 
# Analyses per 
Event 
TOC 
SM5310B 
1 - 250 ml amber 
glass 
H2SO4 / Cool to 4 deg C 
28 days 
grab 
Standard 
5 
Sulfate & 
Chloride 
9056A 
1 - 125 ml poly 
Cool 4 deg C 
28 days 
grab 
Standard 
5 
Nitrate 
353.2 
1 - 125 ml poly 
H2SO4 / Cool to 4 deg C 
48 hours 
grab 
Standard 
5 
Ethane and 
Ethene 
RSK-175 
3 - 40 ml vials 
HCL to <2 / Cool to 4 deg 
C 
14 days 
grab 
Standard 
5 
TCL VOCs 
SOM01.2 
5 - 40 ml vials 
Cool to 4 deg C 
14 days 
grab 
Standard 
37 
 
Monthly Sampling Program 
Analysis 
Method 
Container 
preservative 
Holding 
time 
sample 
type 
Turn-
Around 
Time 
# Analyses per 
Month 
TO-15 Air 
Analysis 
TO-15 
Summa Cannister 
None 
30 days 
grab 
Standard 
2 
TCL VOCs 
SOM01.2 
5 - 40 ml vials 
Cool to 4 deg C 
14 days 
grab 
Standard 
8 
TSS 
2540D 
1 - 250 ml poly 
Cool to 4 deg C 
7 days 
grab 
Standard 
1 
TOC 
415.1 
1 - 250 ml poly 
H2SO4 / Cool to 4 deg C 
48 hours 
grab 
Standard 
1 
 
Weekly Sampling Program 
Analysis 
Method 
Container 
preservative 
Holding 
time 
sample 
type 
Turn-
Around 
Time 
# Analyses per 
Week 
TSS 
2540D 
1 - 250 ml poly 
Cool to 4 deg C 
14 days 
grab 
Standard 
2 
TOC 
SM5310B 
3-40 ml amber 
H2SO4 / Cool to 4 deg C 
14 days 
grab 
Standard 
2