Site: Site Name: Site Location: HRS Score: Date Listed on the NPL: RECORD OF DECISION FACT SHEET EPA REGION II Virgin Island Chemical Superfund Site St. Croix, U.S. Virgin Island 50.00 June 17, 1996 SDMS Document 81207 Record of Decision: Date Signed: Selected Remedy: The major components ofthe Selected Remedy are as follows: 1. Treatment of contaminated soils and groundwater in the Above-groimd Storage Tank (AST) Area using Soil Vapor Extraction and Air Sparging (SVE/AS) 2. Monitored Natural Attenuation (MNA) of contaminated groundwater in the Former Process Pit (FPP) Area. 3. Institutional controls to restrict land and groundwater use at the Site until the remedial action objectives are met. In addition, groundwater extraction and treatment has been retained as a contingency remedy for the AST and FPP Area, which would be implemented in the event that SVE and MNA is subsequently determined after implementation to not be adequately protective or reasonably effective. 500005 Estimated Date of Construction Completion: September 2002 Incurred Capital Cost: Additional Capital Cost Present Worth O&M Cost for SVE/AS Treatment: Present Worth O&M Cost for MNA and Long-term Monitoring: Total Present Worth Cost: Lead; Lead Agency: Primary Contact: Secondary Contact: Main PRPs: Waste: Waste Type: Waste Origin: Estimated Waste Quantity: Contaminated Media: $565,000 $285,760 $84,000 $469,500 $1,404,260 U.S. Environmental Protection Agency, Region II Emergency and Remedial Response Branch Caroline Kwan, RPM (212)637-4275 Melvin Hauptman, Leader - Sediments/Carribean Team (212)637-3952 Pharmacia, Berlex Laboratories Volatile organic compounds - (i.e., mainly ethylbenzene, xylene, chloroform) Pharmaceutical manufacturing and blending operations 8,700 cubic yards of contaminated soils, 980,000 gallons of contaminated groundwater Subsurface soils, groundwater 5 0 0 0 0 6 RECORD OF DECISION VIRGIN ISLAND CHEMICAL SUPERFUND SITE ST. CROIX, U.S. VIRGIN ISLANDS UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION II NEW YORK, NEW YORK 500007 DECLARATION FOR THE RECORD OF DECISION SITE NAME AND LOCATION Virgin Island Chemical Superfiind Site Estate Bethlehem Middle Works St. Croix, U.S. Virgin Islands CERCLIS ID No. VID980651095 STATEMENT OF BASIS AND PURPOSE This decision document presents the U.S. Environmental Protection Agency's (EPA's) Selected Remedy for the Virgin Island Chemical Superfiind Site ("the Site"), located in Estate Bethlehem Middle Works in the south-central portion of St. Croix in the U.S. Virgin Islands, which was chosen in accordance with the requirements ofthe Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), 42 U.S.C. Sections 9601-9675, as amended, and to the extent practicable, the National Oil and Hazardous Substances Pollution Contingency Plan (NCP), 40 CFR Part 300. This decision document explains the factual and legal basis for selecting the remedy for the Site. The information supporting this remedial action decision is contained in the administrative record for the Site. The administrative record index is attached (see Appendix D). The Virgin Islands Department of Planning and Natural Resources (VIDPNR) has been consulted and concurs with the Selected Remedy (see Appendix E). ASSESSMENT OF THE SITE The response action selected in this Record of Decision (ROD) is necessary to protect public health or welfare or the environment from actual or threatened releases of pollutants or contaminants fi-om the Site which may present an imminent and substantial endangerment to public health or welfare or the envirorunent. DESCRIPTION OF THE SELECTED REMEDY The remedy selected is the only operable unit for the Site. EPA's Selected Remedy for the Site includes soil vapor extraction/air sparging (SVE/AS), monitored natural attenuation (MNA), and institutional controls. The Selected Remedy was presented in the Final Feasibility Study Report (FS) and is described in further detail below. The FS evaluated and screened remedial altematives for contaminated soil and groundwater at the Site. The FS used a comparative analysis to evaluate five altematives and identify the advantages and disadvantages of each. EPA selected the remedy for the Site based upon the results ofthe FS. The Selected Remedy for contaminated soil and groundwater includes the following features: 500008 Use and expansion ofthe existing SVE/AS system to treat contaminated groimdwater, saturated soil, and unsaturated soil at the Abovegroimd Storage Tank (AST) source area; • Use of MNA to address low-level residual contamination in groundwater at the Former Process Pit (FPP) area and downgradient areas; and The Department of Planning and Natural Resources in consultation with EPA, will utilize institutional controls (in the form of existing well permitting laws and regulations) to limit the pumping of groundwater at the Site to prevent interference with the selected remedy and to also prevent human exposure to contaminated groundwater until MCLs are achieved. The Selected Remedy is protective of human health and the environment through the following: 1. Active source control and contaminant mass removal will occur at the AST area via use of an SVE/AS system to remove ethylbenzene and xylene fi-om the source area soils and from groundwater to achieve soil SSLs and groundwater MCLs. AS treatment will also enhance conditions for aerobic biodegradation ofthese contaminants. 2. Natural attenuation of low-level residual volatile organic compotmd (VOC) contamination, mainly chloroform, in groimdwater will continue in the FPP area under closely monitored conditions until groundwater MCLs are achieved. 3. The Department of Planning and Natural Resources will utilize institutional controls (in the form of existing well permitting laws) to limit the pumping of groundwater at the Site to prevent interference with the selected remedy and to also prevent human exposure to contaminated groundwater until MCLs are achieved. In addition to the Selected Remedy, EPA has retained groundwater extraction and treatment as a contingency remedy for the groundwater in the AST and FPP areas. This contingency remedy will be implemented in the event that analyses of groundwater monitoring data indicate that; 1) the groundwater plume exceeding MCLs is migrating downgradient and could potentially move beyond the Island Chemical property boundary line or 2) MCLs will not be achieved anywhere in the aquifer within a time frame that is reasonable compared to that offered by the contingency remedy. The decision to implement the contingency remedy will be made by EPA, in its sole discretion, according to criteria specified iii Section 11.3 ofthe ROD. 5 0 0 0 0 9 STATUTORY DETERMINATIONS The Selected Remedy attains the mandates of CERCLA Section 121 and, to the extent practical, the NCP. Specifically, the Selected Remedy is protective of human health and the environment, complies with federal and territorial requirements that are applicable or relevant and appropriate to the remedial action, is cost-effective, and utilizes permanent solutions and altemative treatment technologies to the maximum extent practicable. This remedy also satisfies the statutory preference for treatment as a principal element ofthe remedy (i.e., reduces the toxicity, mobility, or volume of hazardous substances, pollutants, or contaminants as a principal element through treatment). Because this remedy may result in hazardous substances, pollutants, or contaminants remaining on-Site above levels that allow for unlimited use and unrestricted exposure for approximately 5 years, a review will be conducted no less often than once every five years after initiation of remedial action to ensure that the remedy is, or will be, protective of human health and the environment. ROD DATA CERTIFICATION CHECKLIST The following information is included in the Decision Summary section of this ROD. Additional information can be found in the Administrative Record file for this Site. • Chemicals of concem (COCs) and their respective concentrations. • Baseline risk represented by the COCs. • Cleanup levels established for COCs and the basis for these levels. • Techniques for addressing source materials that constitute principal threats. • Current and reasonably anticipated future land use assumptions and current and potential fiiture beneficial uses of ground water used in the baseline risk assessment and ROD. • Potential land and ground-water use that will be available at the Site as a result ofthe Selected Remedy. • Estimated capital, armual operation and maintenance, and total present worth costs, discount rate, and the number of years over which the remedy cost estimates are projected. • Key factors that led to selecting the remedy. |Y\ Kenny / ] Date al Administrator nvironmental Protection Agency, Region II u O-Z. 500010 RECORD OF DECISION DECISION SUMMARY VIRGIN ISLAND CHEMICAL SUPERFUND SITE ST. CROIX, U.S. VIRGIN ISLANDS 5 0 0 0 1 1 TABLE OF CONTENTS Section Page 1.0 INTRODUCTION 1 1.1 Site Name, Location, and Description 1 1.2 Site History and Removal Action 1 2.0 HIGHLIGHTS OF COMMUNITY PARTICIPATION 3 3.0 SCOPE AND ROLE OF ACTION 5 4.0 SUMMARY OF SITE CHARACTERISTICS 5 4.1 Geology and Hydrogeology 6 4.2 Soil 7 4.3 Groundwater 8 4.4 Gut System 8 4.5 Fate and Transport 9 5.0 CURRENT AND POTENTIAL FUTURE LAND USE 9 5.1 Current Land Use 9 5.2 Future Land Use 9 6.0 SUMMARY OF SITE RISKS 10 6.1 Human Health Risk 10 6.2 Environmental Concems 11 7.0 REMEDIAL ACTION OBJECTIVES 12 8.0 DESCRIPTION OF ALTERNATIVES 13 8.1 Altemative 1: No Further Action 14 8.2 Altemative 2: MNA with Institutional Controls 14 8.3 Altemative 3: SVE/AS for the AST Area, MNA for the FPP Area, and Institutional Controls 15 8.4 Altemative 4: SVE/AS for the AST Area, Groundwater Extraction and Treatment For the FPP Area, and Institutional Controls 15 8.5 Altemative 5: Groundwater Extraction and Treatment for the AST Area, MNA for the FPP Area, and Institutional Controls 16 5 0 0 0 1 2 TABLE OF CONTENTS Section Page 9.0 SUMMARY OF COMPARATIVE ANALYSIS OF ALTERNATIVES 17 9.1 NCP Evaluation and Comparison Criteria 17 9.2 Evaluation of the Altematives Against the NCP Criteria 18 10.0 PRINCIPLE THREAT WASTES 21 11.0 SUMMARY OF THE SELECTED REMEDY 22 11.1 Rationale for Selected Remedy 22 11.2 Description ofthe Selected Remedy ; 23 11.3 Description of Contingency Remedy 25 12.0 STATUTORY DETERMINATIONS 25 12.1 Protection of Human Health and the Environment 25 12.2 Comphance with ARARs 26 12.3 Cost Effectiveness 26 12.4 Utilization of Permanent Solutions and Altemative Treatment Technologies (or Resource Recovery Technologies) to the Maximum Extent Practicable . . . 26 12.5 Preference for Treatment as a Principle Element 27 12.6 Five-Year Review Requirements 27 13.0 DOCUMENTATION OF SIGNIFICANT CHANGES 27 APPENDICES A Figures B Tables C Responsiveness Summary D Administrative Record Index E VIDPNR Letter of Concurrence 500013 LO INTRODUCTION Ll Site Name, Location, and Description The Virgin Island Chemical Superfiind Site ("the Site") includes a former chemical facihty and properties located at Plot 13Q (approximately 3.5 acres) of Estate Bethlehem Middle Works in the south-central portion of St. Croix in the U.S. Virgin Islands (see Figure 1). Site access is via Route 66, which traverses the island east and west and abuts the south-southwest boundary ofthe Site. Plot 13Q is bordered to the north and east by an intermittent stream, the River Gut, which originates north ofthe Site and drains to the Caribbean Sea. The River Gut joins the Bethlehem Gut approximately 800 feet southeast ofthe Site. They are collectively then called the Fairplain Gut. The groundwater underlying the Site flows predominantly to the south-southeast. Land use surrounding the Site is mostly industrial and commercial. A water service company and an undeveloped lot exist immediately to the west and northwest ofthe Site. A concrete batch plant and two automobile repair shops are located east-northeast ofthe Site, on the opposite side ofthe River Gut. Two paving companies are located north-northwest ofthe Site across the River Gut. The Henry Rohlsen Airport (formerly known as the Alexander Hamilton Airport) is situated about 1,500 feet south ofthe Site and a prison lies 0.25 mile to the northwest. Two residential properties are located about 0.33 mile north and 0.75 mile northwest ofthe Site. Plot 13Q is owned by CHS Holding Corporation and is currently unoccupied and overgrown with heavy vegetation. A chain-link fence was installed in Spring 2000 along the property line to secure the area from unauthorized access. Over half of the property was covered by buildings and/or process equipment from past pharmaceutical manufacturing and blending operations. Certain ofthe potentially responsible parties demolished the buildings in the Spring of 2002. There are no remaining stmctures except a concrete pad that housed the buildings. Two storm drains are located on-Site. The Central Storm Drain runs beneath the paved area between the former laboratory and maintenance buildings. The Southem Storm Drain, where observed, is a concrete-lined depression along the southem wall ofthe former maintenance building and the edge ofthe reactor area. Both storm drains discharge to the River Gut. L2 Site History and Removal Action From 1968 to 1982, the Site was used for a variety of pharmaceutical manufacturing and blending operations under a number of different corporate entities. In general, toluene, pyridine, and quinidine (chemicals used by many ofthe occupants) have been historically spilled or otherwise released in significant volumes at the Site. In October 1982, EPA was notified ofthe facility's impending closure and off-Site removal of waste materials. Between 1984 and 1991, several investigations were conducted at the Site by EPA and a former tenant. Island Chemical Company, which was later acquired by Berlex Page -1- 500014 Laboratories Inc. (Berlex). This investigative work identified six areas of potential environmental concem (see Figure 2): (1) Laboratory and Warehouse Building (2) Aboveground Storage Tank (AST) Area (3) Former Process Pit (FPP) Area (4) Loading Dock/Former Laboratory Pit Area (5) Soil Beneath Concrete Pad Near ASTs (northem comer ofthe Site), and (6) Concrete Storage Pad (north ofthe laboratory and warehouse buildings). During the initial assessment stages ofthe Site by regulatory agencies, both EPA and Berlex conducted several response activities. These activities included soil excavation with on-Site treatment (e.g., drying trays) or off-Site disposal, dmm removals, and off-Site disposal of AST contents. Between September 1989 and October 1991, EPA conducted a removal action at the Site. At that time, the laboratory/warehouse building was found to contain approximately 400 drums (some extremely deteriorated), leaking cylinders ofchlorine and hydrogen chloride, and over 800 containers of laboratory reagents that included sodium metal, potassium cyanide, and ethyl ether. EPA removed 354 drums containing 14,720 gallons of various chemicals and 8,061 pounds of lab pack chemicals from the laboratory/warehouse building. On June 17, 1996, the Site was placed on the National Priorities List. On September 29,1994, EPA entered into an Adminisfrative Order on Consent (AOC), Index No. II CERCLA-94-0401, with Berlex and Island Chemical Company. Pierrel S.p.A, a subsidiary of Pharmacia Corporation and also a former tenant at the Site, was added as a Respondent to this AOC in April 1999. The AOC required the performance of a Remedial Investigation and Feasibility Study (RI/FS) at the Site. The primary objectives ofthe RI were to: I) collect the data needed to characterize the nature and extent of contamination and adequately support human health and ecological baseline risk assessments and 2) provide a basis on which a subsequent, cost-effective, remedial action plan would be recommended. The following specific data requirements were addressed: • Background concentrations of inorganic contaminants in surface soil through sampling and analysis; • Nature and extent of potential surface and subsurface soil impacts on the Site through sampling and analysis; • Nature and extent of potential groundwater impacts through monitoring well installation and sampling and analysis; • Site-specific geologic and hydrogeologic conditions through lithologic evaluation, water level measurements, etc.; and Page -2- 5 0 0 0 1 5 • Nature and extent of potential soil/sediment contamination in the Gut System (i.e., River, Bethlehem, and Fairplain Guts) through sampling and analysis. All six areas of potential concem were investigated during the initial assessment and the subsequent RI. Based on the data collected, only the AST and FPP areas were determined to require remediation. 2.0 HIGHLIGHTS OF COMMUNITY PARTICIPATION Public participation in the remedy selection process is required by CERCLA Sections 113 and . 117, 42 U.S.C. Sections 9613 and 9617, and 40 CFR Section 300.430(f)(3) ofthe NCP. These sections require that, before adoption of any plan for remedial action to be imdertaken by EPA, the State, or an individual (e.g., potentially responsible party), the lead agency shall: 1. Publish a notice and make the Proposed Plan available to the public, and 2. Provide a reasonable opportunity for submission of written and oral comments and an opportunity for a public meeting at or near the Site regarding the Proposed Plan and any proposed findings relating to cleanup standards. The lead agency shall keep a franscript of the meeting and make such transcript available to the public. The information made available to the public under item 1, above, shall provide a reasonable explanation ofthe Proposed Plan and altemative proposals considered. Additionally, notice ofthe final remedial action plan set forth in the ROD must be published, and the plan must be made available to the public before commencing any remedial action. Such a final plan must be accompanied by a discussion of any significant changes to the preferred remedy presented in the Proposed Plan along with the reasons for the changes. A response (Responsiveness Summary) to each ofthe significant comments, criticisms, and new data submitted in written or oral presentations during the public comment period must be included with the ROD. A summary of community involvement activities at the Site follows: November 1994 - EPA visited the Site and spoke to representatives or owners ofthe businesses and restaurants adjacent to the Site about upcoming sampling activities. January 1995 - EPA delivered a fact sheet door-to-door to affected businesses and nearby residents. The fact sheet explained the nature ofthe contamination and the need for the RI. February 15,1995 - EPA held a public meeting at the Department of Education Curriculum Center to present the RI work plan and to answer questions from the community. Page-3- 5 0 0 0 1 6 August 1995 - EPA completed a Community Relations Plan for the Site, which documented community concems expressed during the November 1994 visits and the Febmary 1995 pubic meeting. September 1997 - EPA prepared and distributed another fact sheet describing completed and ongoing remedial investigation activities. June 27,2001 - EPA released the RI and FS reports and the Proposed Plan for pubhc comment. These documents were made available to the public in the EPA Docket Room in Region II, New York and the information repository at the University ofthe Virgin Islands, St. Croix Campus Library, Kingshill, St. Croix. A notice announcing the public comment period and a public meeting, along with the availability ofthe RI and FS reports and Proposed Plan, was published on June 27, 2001. The public comment period originally was scheduled from June 27 through July 27, 2001. In response to public request for additional time, EPA extended the pubhc comment period an additional 15 days to August 11, 2001. July 12,2001 - EPA and VIDPNR hosted a public meeting to present the conclusions ofthe RI/FS, fiirther elaborate on the reasons for recommending the Preferred Altemative, and to receive public comments. The meeting was held at 7:00 p.m. at the Department of Education Curriculum Center on Centerline Road in Kingshill, St. Croix. Representatives from EPA presented the Proposed Plan, which discussed the following five altematives: • Altemative 1: No Further Action • Altemative 2: Monitored Natural Attenuation (MNA) with Institutional Controls • Altemative 3: Soil Vapor Extraction/Air Sparging (SVE/AS) for the AST area, MNA for the FPP area, and Institutional Confrols • Altemative 4: SVE/AS for the-AST area, Groundwater Exfraction and Treatment for the FPP area, and Institutional Confrols • Altemative 5: Groundwater Extraction and Treatment for the AST area, MNA for the FPP area, and Institutional Controls Altemative 3 was presented as EPA's Preferred Altemative. In addition, EPA proposed to retain Altemative 4 as a contingency remedy that would be implemented in the event that the analyses of fiiture groundwater monitoring data indicate that active remediation ofthe contaminated groundwater is appropriate. A portion ofthe meeting was dedicated to answering questions and accepting formal oral comments from the public. Community acceptance ofthe Selected Remedy is discussed in Section 9.0, Summary of Comparative Analysis of Altematives, of this Decision Summary. EPA's response to comments received during the public comment period is included in the Responsiveness Summary, which is part of this ROD, and is designated as Appendix C. Page-4- 500017 3.0 SCOPE AND ROLE OF RESPONSE ACTION This is the first and only operable unit at the Site. The Selected Remedy addresses soil and groundwater contamination in the AST area and groundwater contamination in the FPP area at the Virgin Island Chemical Superfund Site. The Selected Remedy will use a soil vapor extraction/air sparging system to freat groundwater, saturated soil, and unsaturated soil at the AST area and MNA to address groundwater in the FPP area. The Department of Planning and Natural Resources will utilize institutional confrols (in the form of existing well permitting laws) to limit the pumping of groundwater at the Site to prevent interference with the selected remedy and to also prevent human exposure to contaminated groundwater until MCLs are achieved. The Selected Remedy is necessary to protect human health and the environment. 4.0 SUMMARY OF SITE CHARACTERISTICS RI/FS activities were conducted at the Site, with EPA and VIDPNR oversight, from 1994 to 2000. The primary objectives ofthe RI were to: 1) collect the data needed to characterize the nature and extent of contamination and adequately support human health and ecological baseline risk assessments and 2) provide a basis on which a subsequent, cost-effective, remedial action plan would be recommended. The RI field investigation was completed in four phases from 1995 through 1998. Six areas of potential environmental concem were investigated (see Figure 2): (1) Laboratory and Warehouse Building (2) Aboveground Storage Tank (AST) Area (3) Former Process Pit (FPP) Area (4) Loading Dock/Former Laboratory Pit Area (5) Soil Beneath Concrete Pad Near ASTs (northem comer ofthe Site) (6) Concrete Storage Pad (north ofthe laboratory and warehouse buildings) The following Site-specific data were collected as part ofthese investigations: • Background concenfrations of constituents in surface soils • Nature and extent of potential surface and subsurface soil impacts on Site • Nature and extent of potential groundwater impacts on Site/ofF Site • Site-specific geologic and hydrogeologic conditions • Nature and extent of potential soil/sediment impacts in the Gut system (i.e.. River, Bethlehem, and Fair Plains Guts). Page-5- 5 0 0 0 1 8 The FS was initiated subsequent to completion ofthe RI, which included the collection of supplemental RI data and the performance of an SVE/AS pilot study in the AST and FPP areas in 2000. The results ofthe RI investigation are summarized below. The results ofthe SVE/AS pilot study, which was conducted as part ofthe FS, are fiirther discussed in Section 8.0. 4.1 Geology and Hydrogeology Geology • * . . . . . The Site geology generally consists of approximately 90 feet of fill and alluvium overlying the clayey marl ofthe Kingshill Formation (see Figures 2 and 3). • Fill material [thickness varies from 0 to approximately 10 feet below ground surface (bgs)]- Consists of reworked alluvium material, as described below. • Alluvium (to approximately 90 feet bgs) - Consists of brown and grey clay-rich sediments with lesser and varying amounts of silt and fine sand. Enfrained within the clay-rich matrix to approximately 30 to 40 feet bgs are more permeable sand and gravel lenses. These lenses are localized and not uniform or continuous across the Site. Kingshill Formation (below approx. 90 feet bgs) - Consists of white to light brown and grey, stiff clay with lesser amounts of sand. Hydrogeology The water table depth fluctuates from approximately 10 to 30 feet bgs according to precipitation, which generally varies according to an aimual cycle. Multiple rounds of groundwater level measurements were taken during the RI to characterize groundwater flow during both the wet and dry periods. Based upon the results ofthese measurements, it was determined that two distinct water-bearing zones exist within the alluvium. The "shallow" alluvium zone corresponds to the interval between 0 to approximately 50 feet bgs, and the "deep" alluvium.zone refers to the interval between approximately 50 to 100 feet bgs. The characteristics ofthese zones are illustrated on the groundwater elevation iso-contour maps (see Figures 4 to 7) and hydrographs (see Figures 8 and 9) included in Appendix A. Figures 4 through 7 contain interpreted groundwater elevation contours in the shallow and deep alluvium during high (i.e., March 6, 2000) and low (i.e., October 21,1998) water table conditions. The predominant groimdwater flow direction within both the shallow and deep alluvium is to the south-southeast, with a localized easterly flow component also apparent in the shallow alluvium proximal to monitoring well MW-10 during high water table conditions. Horizontal gradients in the shallow and deep alluvium range from approximately 0.002 to 0.014 feet per foot (ft/ft) and from 0.003 to 0.014 ft/ft, respectively^ The vertical gradients between the shallow and deep Page-6- 5 0 0 0 1 9 alluvium are consistently downward and range from -0.005 to -0.11 ft/ft. The hydrauhc conductivities for the shallow and deep alluvium ranged from 0.90 to 18.14 feet per day (ft/d) and from 2.73 to 5.65 ft/d, respectively. Figures 8 and 9 contain the results of continuous water level measurements from two shallow/deep well pairs (MW-6/MW-8 in the AST area, MW-2/MW-7 in the FPP area), respectively, along with corresponding precipitation data for a period of approximately 3 weeks. In both cases, the hydrograph for the deep well exhibited a response (i.e., a corresponding change in water level) to off-site pumping, whereas the shallow well exhibited a steady decline and no response to off-site pumping. This information supports the conclusion that an aquitard exists between the shallow and deep alluvium, which prevents direct hydraulic communication between theses two zones. This conclusion is fiirther supported by the distribution of groundwater contaminants, as fiirther discussed in Section 4.3. 4.2 Soil Surface Soil The analytical results from surface soil samples were compared to EPA's SSLs, risk-based screening levels derived from other EPA guidance documents, and Site background concentrations (for metals only). Arsenic was detected above the risk-based screening level of 3.83 parts per million (ppm) (non-detected to 8.8 ppm); iron was detected above twice the Site background concentration of 31,933 ppm (18,100 ppm to 63,400 ppm); and manganese was detected above the risk-based level of 1,600 ppm (311 ppm to 2,100 ppm) in several samples. Based upon further evaluation ofthe data as part ofthe risk assessment (see Section 6.0), no contaminants of significant concem were identified in the surface soil. Subsurface Soil The analytical results from subsurface soil samples were compared to EPA's SSLs for protection of groundwater and to Site background concenfrations (for metals only). Based on these comparisons and the groundwater data collected during the RI, metals and semi-volatile organic compounds (SVOCs) were not considered to be a significant concem. The predominant contaminants determined to have impacted subsurface soils in the AST area were ethylbenzene (7 parts per billion (ppb) to 320,000 ppb) and xylene (2 ppb to 2,000,000 ppb). The SSLs for ethylbenzene and xylene are 6,500 ppb and 90,000 ppb, respectively. The impacted subsurface soils generally encompass an on-Site area between Tanks 3 and 10 (see Figure 10). The zone of impact was estimated to be approximately 7,800 square feet (sf) in area and to extend from two feet bgs to the water table interface (approximately 25 feet bgs). While concenfrations of chloroform were not detected above the SSL of 600 ppb (maximum concentration of chloroform was 410 ppb), this chemical was included as a contaminant of potential concem (COPC) based upon its detection in groundwater. The subsurface soils within a 400-square-foot area, from 20 to 25 feet bgs, near monitoring well MW-2 (i.e., the location where Page-7- 500020 highest concentrations of chloroform were detected in groundwater; see Figure 13), were conservatively assumed to be impacted with chloroform. 4.3 Groundwater The following volatile organic compounds (VOCs) were detected above the federal Maximum Contaminant Levels (MCLs) in groundwater: ethylbenzene, xylene, and chloroform. Groundwater quality in the AST area was determined to be impacted by ethylbenzene (700 ppb to 23,000 ppb) and xylene (27,000 ppb to 110,000 ppb). The MCLs for ethylbenzene and xylene are 700 ppb and 10,000 ppb, respectively. Concenfration iso-contour maps illustrating the 1998 extent ofthe ethylbenzene and xylene contamination exceeding MCLs in groundwater are included as Figures 11 and 12, respectively. In 1998, the area and depth of groundwater impact above MCLs were estimated to be approximately 14,000 sf and 40 to 50 feet bgs, respectively, based upon the results of groundwater samples collected from shallow monitoring wells MW-1, MW-6 and MW-10, deep monitoring well MW-8, and multiple geoprobe and temporary well sampling locations. The most recent results from groundwater sampling completed during the period of March to May 2000 indicate that the groundwater plume is not expanding. Ethylbenzene and xylene were not detected in any ofthe existing off-Site production wells. Groundwater quality in the FPP area was determined to be impacted by chloroform. The MCL for chloroform is 100 ppb. A concenfration iso-contour map illusfrating the 1998 extent of chloroform contamination exceeding MCLs in groundwater is included as Figure 13. In 1998, the area and depth of impact above the MCL was estimated to be approximately 3,000 sf and 40 to 50 feet bgs, respectively, based upon the results of groundwater samples collected from shallow monitoring wells MW-2 and MW-11, deep monitoring well MW-7, and multiple geoprobe and temporary well sampling locations (96 ppb to 3,800 ppb). The most recent results from groundwater sampling completed during the period of March to May 2000 indicate that chloroform concenfrations (38 ppb to 76 ppb) have decreased below the MCL, excluding the localized area of temporary well FPP-VMP-ID (25 -137 ppb; located 10 feet from MW-2). Chloroform was not detected in any off-Site production wells. Methylene chloride was also notably detected in groundwater at both the AST and FPP areas. However, methylene chloride was also detected in field, trip, and laboratory blanks and at concentrations that can be attributed to laboratory contamination rather than actual Site conditions. To be conservative, this chemical was included as a COPC. 4.4 Gut System Several metals were detected at the reference location (RG-2), uspsfream of Plot 13Q, in the River Gut. The distribution ofthese metals was generally variable throughout the Gut System. However, a slight increase in the concenfration of certain metals was noted at several locations downsfream ofthe facility and at one location in the Bethlehem Gut. These elevated concenfrations in the River Gut are likely the result ofthe depositional nature of the locations. No metals were detected above EPA SSLs and, thus, they are not of concem. Page-8- 500021 4.5 Fate and Transport The existing data obtained during the RI/FS support the following conclusions: 1) An active source of ethylbenze and xylene contamination exists in the unsaturated zone soils at the AST area, which will continue to impact the underlying groundwater quality at concenfrations exceeding MCLs. However, the existing groimdwater data indicate that ethylbenzene and xylene plumes exceeding MCLs have reached steady state as a result of natural attenuation processes (e.g., biodegradation, adsorption, dilution) and, hence, are not expanding or migrating beyond their current position. The groundwater plumes exceeding MCLs in this area generally coincide, extend just north ofthe Site property boundary, and have not impacted off-Site production wells. The current impact to groundwater quality will persist so long as the active source remains present. 2) An active source of chloroform contamination was not identified in the FPP area. Existing groundwater data indicate that the chloroform plume is confracting as a result of natural attenuation processes, with current groundwater quality in this area predominantly conforming with MCLs. The groundwater plume exceeding MCLs is within the Plot 13Q property boundary and has not impacted off-Site production wells. 5.0 CURRENT AND POTENTIAL FUTURE LAND USE The Revised Final Human Health Risk Assessment (2000) considered both current and potential future land use scenarios. The Site and the surrounding area have been generally developed for various commercial/ industrial uses, and it is reasonable to assume that such uses will continue into the extended fiiture. The exposure pathways of ingestion, inhalation, and dermal absorption via contact with the COPCs in groundwater, soils, and sediments were identified for evaluation. Potential human receptor populations were evaluated for each pathway and either mled out or included in the risk assessment. This evaluation identified the following possible exposure pathways: 5.1 Current Land Use • Residential (child/adult) exposure to groundwater via six off-Site wells was evaluated. This pathway was deemed incomplete as no COPCs were identified for the groundwater from these off-Site wells in the immediate vicinity ofthe Site. • Trespasser (pre-adolescent/adult) exposure to COPCs in the surface soil/sediment collected from the Site and the stream system (Gut System) was evaluated for three pathways (incidental ingestion, dermal contact, and inhalation of particulates). Pre- adolescent children were assumed to be those between 7 and 12 years of age. 5.2 Future Land Use • Industrial/Commercial (adult) exposures on-Site to COPCs in groundwater, surface soil, and sediment were evaluated for three pathways (ingestion, inhalation of VOCs (groundwater) and particulates (soil and sediment), and dermal contact). Page-9- 5 0 0 0 2 2 • Constmction worker (adult) exposures on-Site to COPCs in surface soil, subsurface soil (up to 12 feet bgs), and soil/sediment in the Gut System were evaluated for three pathways (incidental ingestion, dermal contact, and inhalation of particulates). Exposure to groundwater was not evaluated for this receptor since groundwater at the Site is generally encountered at depths between 18 and 20 feet bgs. Since constmction activities are not anticipated to occur at such depths, exposure to groundwater was not considered. In addition to evaluating the potential for risk associated with direct contact with contaminants in subsurface soil, the same data also were compared to EPA's SSLs to detennine if concenfrations could adversely impact groundwater through migration (leaching). • Off-Site residential (child/adult) exposures to COPCs in groundwater were evaluated for three pathways (ingestion, dermal contact, and inhalation of particulates or VOC vapors). For this scenario, it was assumed that on-Site concenfrations could be present in an off- Site well for the entire exposure duration. In reality, no COPCs were detected in the off- Site wells or in the wells at the edge ofthe Site nor are they expected to reach these areas in the future, as discussed in Sections 4.1 and 4.3. Therefore, frie exposure assumptions used in this scenario are exfremely conservative. 6.0 SUMMARY OF SITE RISKS Based upon the results ofthe RI, a baseline risk assessment was conducted to estimate the risks associated with current and future Site conditions. A baseline risk assessment is an analysis ofthe potential adverse human health and ecological effects caused by hazardous substance releases from a Site in the absence of any actions to control or mitigate these under current and fiature land uses. The results ofthe baseline risk assessment are discussed below and summarized on Tables 1 through 10. 6.1 Human Health Risk An evaluation was made of all potential exposure routes which cause exposure to chemicals of potential concem at the Site for people living or working iri the area. The estimated carcinogenic risks and noncarcinogenic hazards were compared to EPA guidelines and generally-accepted target risk levels. Carcinogenic risks falling within the target range of 1 X 10'* to 1 X 10"^ and noncarcinogenic hazards less than 1 were considered to be below the statutory threshold. Under a fiiture land use scenario, the cumulative carcinogenic risk estimates for exposure to groundwater for the industrial/commercial worker (9 X 10^), the adult resident (8 X 10"*) and the child resident (4 X 10"*) exceed EPA's target risk range. These exposure scenarios assumed that the on-Site groundwater would be used as a potable water source for drinking and bathing. Inhalation of volatilized chloroform accounts for most ofthe cumulative risk for this medium. Although the maximum detected concenfrations of ethylbenzene and xylene exceeded their respective MCLs in the AST area, theresults of the Human Health Risk Assessment showed that Page-10- 500023 exposure to these two COPCs alone over time did not present unacceptable risks or hazards to human health based upon their levels of detection throughout the entire Site. For the evaluation of noncancer human health hazards, potential fiiture industrial/commercial and residential groundwater use exceeded EPA's target hazard index (HI) of 1. For the industrial/commercial worker exposure and both residential scenarios, chloroform was the major contributor. Both adult and child residential His exceeded 1 (255 and 600, respectively), as did the industrial/commercial worker (330). Ingestion and inhalation of chloroform contributed to virtually all ofthe noncancer hazard for the industrial/commercial worker and residential groundwater use scenario. Ingestion of iron and manganese also contributed less significantly to the hazard estimates. All contaminants in the subsurface soil were below levels of concem, and were not carried into the human health risk assessment. On-Site surface soil and soil/sediment in the Gut System did not demonsfrate carcinogenic risks for the adult industrial/commercial worker, adult and pre- adolescent trespassers and constmction workers above EPA's target risk range. Noncancer hazards were near or below EPA's HI of 1.0. For the constmction worker scenario, the total HI was 1.2, although no individual chemical exceeded the HI of 1.0. Arsenic, iron and manganese were included in the Human Health Risk Assessment. However, all risks and hazards associated with exposure to these chemicals are within EPA's acceptable levels and by themselves are not considered to be a health concem. They do, however contribute to the overall risk at the Site. In summary, chloroform in the groundwater is the main risk and hazard driver for the industrial/commercial worker and the adult and child resident for the future groundwater use scenario, with methylene chloride and arsenic contributing to the risk as well. Manganese and iron also contributed to the estimated non-cancer risk; however, these compounds are naturally occurring in groundwater and do not have MCLs. Ethylbenzene and xylene did not significantly contribute to the calculated risks, as described above. However, ethylbenzene and xylene exceeded their respective MCLs in groundwater in the AST area and, therefore are considered contaminants of concem. 6.2 Environmental Concerns A Screening Ecological Risk Assessment (SERA) focused on the drainage channels adjacent to and downsfream ofthe Site, including the River Gut (which serves as the northeastem and southeastem Site boundary), Bethlehem Gut, and Fairplain Gut. The SERA was developed using data obtained through a surface soil/sediment sampling program conducted within the three drainage channels. In general, aluminum exposure may potentially impact herbivorous, insectivorous, and piscivorous wildlife foraging in the River, Bethlehem and Fairplain Guts. Aluminum, chromium, vanadium and zinc, identified for plants, measured adjacent to or downsfream ofthe Site were found at similar or lower concentrations to those measured at the upsfream reference location (RG-2). This finding suggests that the contaminants of potential ecological concem have been transported from upgradient sources. Historical (1986) and current (1997) data for soil collected Page-11- 500024 from the Central and Southem Storm Drains suggest that several metals (e.g., aluminum, manganese, and zinc) may have been historically discharged to downsfream areas ofthe River Gut (near sample location RG-13). The potential contribution of aluminum has decreased over the years, as evidenced by the substantial reduction in concenfrations measured in 1997, as compared to 1986. In addition, the aluminum concenfrations measured in soil from the storm drains collected in 1997 were similar to those measured in soil collected from the River Gut upsfream ofthe drain discharge points. Therefore, a current on-Site source of aluminum to the River Gut is unlikely. The Bethlehem Gut, which contained the second highest concenfration of aluminum, also is a potential source of exposure in the Fairplain Gut. A bauxite plant is located in close proximity to the Site and serves as a likely source ofthe aluminum concenfrations detected. 7.0 REMEDIAL ACTION OBJECTIVES The remedy outlined in this ROD is intended to be the final remedial action for the Site. Remedial action objectives (RAOs) are medium-specific (e.g., soil, groundwater, etc.) goals for protecting human health and the environment. The RAOs for the Virgin Island Chemical Superftmd Site are to: • Mitigate the toxicity, mobility, and/or volume of VOCs (ethylbenzene and xylene) in soils in the AST area so as to minimize continued leaching to groundwater; • Mitigate the toxicity, mobility, and/or volume of VOCs (ethylbenzene and xylene) in groundwater in the AST area and downgradient so as to achieve MCLs and protect potential future groundwater users; • Mitigate the toxicity, mobility, and/or volume of chloroform in groundwater in the FPP area and dovragradient so as to achieve MCLs and protect fiiture potential groundwater users; and • Restrict on-Site groundwater use to non-potable purposes until the water quality is restored to MCLs. The Applicable or Relevant and Appropriate Requirements (ARARs) and other To-Be-Considered criteria (TBCs) for soil and groundwater remediation at the Virgin Islands Chemical Site are summarized in Table 13. The groundwater cleanup goals are based upon the primary MCLs for drinking water, as established by federal regulations. There are no promulgated federal or territory cleanup standards for soils. In addition, the results ofthe baseline risk assessment did not identify any unacceptable human health risks associated with direct exposure to the contaminated soils at the Site. Therefore, Site-specific cleanup goals for Site soil contaminants were developed as TBCs using the EPA Soil Screening Level (SSL) methodology for the migration to groundwater pathway. Page-12- 500025 Additional ARARs and/or TBC, specific to remedial freatment system design and operation, will be dictated by the applicable federal and territorial regulations (e.g., for surface water and air discharges) as referenced in Table 13. 8.0 DESCRIPTION OF ALTERNATIVES Based on the results ofthe RI, EPA evaluated five remedial altematives that would address soil and groundwater contamination at the Virgin Island Chemical Superfund Site. As part of evaluating altematives, a soil vapor exfraction/air sparging pilot study was performed in Spring 2000 at both the AST and FPP areas to better assess the effectiveness of SVE/AS freatment in these areas. The results ofthe pilot test supported the following conclusions: SVE/AS would be an effective Combined technology for removing ethylbenzene and xylene from the AST source area soils and groundwater. AS freatment would also enhance the conditions for aerobic biodegradation ofthese contaminants. • SVE/AS would not be effective for freatment ofthe FPP area, based upon the low air permeability of soils and the low chloroform concenfrations remaining in the soils and groundwater in this area. The analytical results of groundwater samples collected prior to, during, and after SVE/AS testing fiirther indicated that chloroform concenfrations in groundwater have decreased since 1998 to below the MCL as a result of natural attenuation, excluding a localized area near temporary monitoring well FPP-VMP-ID. Following completion ofthe pilot study, five remedial altematives were developed for evaluation. Four altematives involved active cleanup measures. One altemative evaluated MNA. Two altematives evaluated SVE/AS, combined with MNA in one case and groundwater exfraction and treatment in the other case. Groundwater extraction and freatment with MNA was evaluated as the remaining altemative. All ofthese active cleanup altematives included institutional confrols. As required by CERCLA, a No Further Action altemative was evaluated as a basis for comparison with the other active cleanup methods. The FS Altematives have been modified to reflect institutional confrols that are appropriate to current Site conditions and implementation responsibilities. The following section describes the remedial altematives evaluated in the FS for the Site. The Selected Altemative is Altemative 3 (i.e.. Soil Vapor Extraction/Air Sparging for the AST area, MNA for the FPP area, and Institutional Confrols). The Contingency Altemative for groundwater is a combination of Altemative 4 and Altemative 5 (i.e.. Soil Vapor Exfraction/Air Sparging for the AST Area, Groundwater Exfraction and Treatment for the AST and FPP Areas, and Institutional Confrols). Note that the capital cost presented in this section of the ROD includes expenses related to the labor, equipment, and material costs of constmction. Operations and Maintenance (O&M) cost refers to the cost over time of operating labor, maintenance, materials, energy, disposal, and adminisfrative activities. Present-worth provides an analysis ofthe current value of all costs. Page-13- 5 0 0 0 2 6 Present-worth cost is calculated based on a predetermined interest rate and the time period over which an altemative will be completed. 8.1 Alternative 1: No Further Action Under the No Further Action alternative, no new response actions would be initiated at the Site. The security fence installed in Spring 2000 would remain and be maintained, but the existing SVE/AS system installed for the pilot study in the Spring of 2000 would be rendered non- operational. The potential risks associated with the contamination would not be minimized by this action. • Incurred capital costs of existing fence: $45,000 Estimated present-worth O&M costs: $12,000 Total estimated present-worth cost: $57,000 (based upon 30 years of maintenance) 8.2 Alternative 2: MNA with Institutional Controls Altemative 2 would include MNA for COPCs in groundwater in the AST area and FPP area. Under this altemative, groundwater conditions would be monitored over an assumed period of 15 years using existing wells at the Site, plus additional monitoring wells would be installed at the AST and FPP areas. The following parameters would be monitored: ethylbenzene and xylene isomers (AST area only), chloroform and dichloromethane (FPP area only), dissolved oxygen, reduction/oxidation (redox) potential, total organic carbon, ferrous iron, sulfate, sulfide, and methane. The monitoring frequency is assumed to consist of quarterly sampling for Year 1, semi-annual sampling for Years 2 and 3, and annual sampling thereafter to Year 15. The Department of Planning and Natural Resources in consultation with EPA, will utihze institutional confrols (in the form of existing well permitting laws and regulations) to limit the pumping of groundwater at the Site to prevent interference with the selected remedy and to also prevent human exposure to contaminated groundwater until MCLs are achieved. Estimated capital costs: $116,560 Estimated present-worth O&M costs: $545,530 Total estimated present-worth cost: $662,090 Page -14- 500027 8.3 Alternative 3: SVE/AS for the AST Area, MNA for the FPP Area, and Institutional Controls In addition to the institutional confrols identified in Altemative 2, this altemative includes expansion and use ofthe existing SVE/AS system to freat groundwater, saturated soil, and unsaturated soil at the AST area. For the AST area, Altemative 3 includes using the existing air sparging system for volatilizing VOCs in shallow groundwater and the soil vapor extraction system to capture sparged vapors from the groundwater and to remove VOCs in the soils above the water table. Additional afr sparging/soil vapor extraction wells would be installed during implementation ofthe remedy to remediate contaminated groundwater and soil in the AST area. This altemative includes periodic monitoring ofthe SVE/AS system. Altemative 3 assumes: 1) one year of SVE/AS operation to achieve the SSLs and groundwater MCLs and 2) three years of verification groundwater monitoring after shutdown ofthe SVE/AS system in the AST area to assure that MCLs are achieved in groundwater. For the FPP area, MNA would be implemented for low-level residual VOC contamination in groundwater. Altemative 3 includes the same sampling scheme for groundwater monitoring as stated in Altemative 2 for an assumed period of 15 years. • Incurred capital costs: $ 565,000 • Estimated additional capital costs: $ 285,760 • Estimated present-worth O&M costs: $ 553,500 • Total estimated present-worth cost: $1,404,260 8.4 Alternative 4: SVE/AS for the AST Area, Groundwater Extraction and Treatment for the FPP Area, and Institutional Controls In addition to the institutional confrols identified in Altemative 2, this altemative includes: • SVE/AS to treat groundwater, saturated soil, and unsaturated soil at the AST area, and • A groundwater extraction and freatment system to hydraulically confrol and freat impacted groundwater at the FPP area. The SVE/AS portion ofthe remedy in the AST area would be the same as described in Altemative 3. At the FPP area, the groundwater extraction system would be comprised of two exfraction wells located approximately 70 feet apart. Each well would be equipped with a submersible pump. The primary exfraction well would be located in the area where the highest concenfrations of chloroform in groundwater were historically encountered. The secondary extraction well would Page-15- 500028 be located downgradient ofthe first well. The combined capture zone from both wells would encompass the FPP area and the historic extent ofthe chloroform plume. The treatment system would consist of a storage/equalization tank, from which groundwater would be pumped to a low profile air stripper for removal of chloroform. Treated water would be discharged via pipeline to the River Gut. It is estimated that 5 years would be required for operation ofthe groundwater freatment and exfraction system to meet MCLs. Altemative 4 includes the following monitoring scheme: • Pre- and post-air stripper water sampling to evaluate removal efficiency in the air stripper and compliance with surface water discharge limits; • Periodic air flow monitoring to ensure sufficient air flow from the blower for mass fransfer in the stripper; Monitoring of differential pressure across the air stripper, in addition to periodic visual inspection ofthe trays to evaluate whether fouling or other impediments to air flow have occurred; • Calculation of mass emissions from the air stripper by using the measured concenfrations of chloroform in the influent water and treated water and the flow rate from the storage tank to the stripper. • Assessment ofthe cone of depression and extent of capture zone induced by the exfraction wells by measuring water levels at new and existing groundwater monitoring wells. Altemative 4 includes the same sampling scheme for groundwater monitoring described in Altemative 2. It was assumed that monitoring in the FPP area would continue through the operation ofthe extraction system (i.e., until the attainment of MCLs), plus two years of post- shutdown monitoring. • Incurred capital costs: $ 565,000 Estimated additional capital costs: $ 654,240 Estimated present-worth O&M costs: $ 877,330 Total estimated present-worth cost: $2,096,570 8.5 Alternative 5: Groundwater Extraction and Treatment for the AST Area, MNA for tbe FPP Area, and Institutional Controls In addition to the institutional confrols identified in Altemative 2, this altemative includes: Page -16- 5 0 0 0 2 9 • MNA for impacted groundwater in the FPP area, and a groundwater exfraction and treatment system to capture and treat impacted groundwater at the AST area. At the FPP area, the MNA portion ofthe remedy would be the same as described in Altemative 2. At the AST area, the groundwater exfraction system would consist of two exfraction wells located within the zone of highest xylene and ethylbenzene impacts. The expected combined capture zones ofthese wells would encompass the entire AST area and the extent ofthe xylene and ethylbenzene plumes. The treatment system would be comprised ofthe same components and be subject to the same monitoring scheme as described in Altemative 4. Treated water would be discharged to the River Gut at a location northeast ofthe AST area. Altemative 5 includes the same sampling scheme for groundwater monitoring as identified in Altemative 2. In the FPP area, the assumed duration of monitoring would be 15 years. In the AST area, the assumed duration of monitoring would be seven years (i.e., five years during extraction system operation and two years of post-shutdown monitoring). • Incurred capital costs: $ 565,000 • Estimated additional capital costs: $ 556,480 • Estimated present-worth O&M costs: $1,030,370 • Total estimated present-worth cost: $2,151,850 9.0 SUMMARY OF COMPARATIVE ANALYSIS OF ALTERNATIVES Section 300.430(e)(9) ofthe NCP requires that EPA evaluate and compare the remedial cleanup altematives based on the nine criteria listed below. The first two criteria, (1) overall protection of human health and the environment and (2) compliance with applicable or relevant and appropriate requirements (ARARs), are threshold criteria that must be met for the Selected Remedy. The Selected Remedy must then represent the best balance ofthe remaining primary balancing and modifying criteria. 9.1 NCP Evaluation and Comparison Criteria 9.1.1 Threshold Criteria (1) Overall protection of human health and the environment addresses whether or not a remedy provides adequate protection and describes how risks posed through each exposure pathway (based on a reasonable maximum exposure scenario) are eliminated, reduced, or confrolled through freatment, engineering methods, or institutional confrols. (2) Compliance with applicable or relevant and appropriate requirements (ARARs) addresses whether or not a remedy would meet all ofthe applicable or relevant and Page-17- 500030 appropriate requirements of other federal and state environmental statutes and regulations or provide grounds for invoking a waiver. 9.1.2 Primary Balancing Criteria (3) Long-term effectiveness and permanence refer to the ability of a remedy to maintain reliable protection of human health and the environment over time, once cleanup goals have been met. It also addresses the magnitude and effectiveness ofthe measures that may be required to manage the risk posed by treatment residuals and/or unfreated wastes. (4) Reduction of toxicity, mobility, and volume through treatment is the anticipated performance ofthe freatment technologies, with respect to these parameters, that a remedy may employ. (5) Short-term effectiveness addresses the period of time needed to achieve protection and any adverse impacts on human health and the environment that may be posed during the constmction and implementation period until cleanup goals are achieved. (6) Implementability is the technical feasibility (e.g., the difficulty ofthe altemative to constmct and operate) and adminisfrative ease (e.g., the amount of coordination with other government agencies) of a remedy, including the availability of necessary materials and services. (7) Cost includes the estimated capital, operation and maintenance, and net present-worth costs. 9.1.3 Modifying Criteria (8) Territorial acceptance indicates whether, based on its review ofthe RI/FS reports and the Proposed Plan, the Territory (VIDPNR) concurs with, opposes, or has no comment on the preferred remedy at the present time. (9) Community acceptance refers to the public's general response to the altematives described in the Proposed Plan and the RI/FS reports. 9.2 Evaluation of the Alternatives Against the NCP Criteria This section summarizes the evaluation ofthe remedial altematives against the nine NCP criteria. The following subsections are a brief summary ofthe evaluation and comparison ofthe altematives against each criteria. Additional details ofthe evaluation ofthe altematives are presented in the FS. Page-18- 5 0 0 0 3 1 9.2.1 Overall Protection of Human Health and the Environment The No Further Action altemative does not address Site risks. All ofthe remaining altematives include a monitoring component to evaluate the protectiveness of the remedy. Although natural attenuation would still occur under the No Further Action altemative, there would be no verification or measure ofthe extent to which these processes are occurring. Altemative 3 would be more effective than MNA alone (Altemative 2) in overall protection of human health, since the inclusion of SVE/AS would remove mass from the AST area more quickly and reduce the amount of time to achieve MCLs and SSLs. Similarly, Altemative 3 would be more effective than Altemative 5 in three ways: (1) SVE would rapidly remove and reduce the contaminant source in the unsaturated zone, whereas groundwater exfraction alone would not address the unsaturated zone; (2) AS is expected to be more effective at remediating contaminated groundwater than conventional groundwater extraction and freatment based upon the localized nature of contaminant distribution, higher silt/clay content ofthe Site soils, and poor yield ofthe shallow aquifer. AS would also better facilitate aerobic biodegradation processes via introduction of air; and (3) SVE/AS would be more readily implemented considering that a system is already in place from the pilot study. With respect to Altemative 4, the existing groundwater data indicate that cleanup via groundwater exfraction and freatment in the FPP area would occur no more rapidly than via natural attenuation (included as a component in Altematives 1, 2, 3, and 5). The groundwater data from Spring 2000 indicate that only one temporary monitoring point exhibits chloroform concenfrations above its MCL. These findings support the conclusion that natural attenuation is adequately protective without the need for any active exfraction system. 9.2.2 Compliance with ARARs The No Further Action altemative does not include a monitoring component to verify compliance with chemical-specific ARARs for groundwater or soil. Altematives 1 (No Further Action) and 2 would not achieve compliance with chemical-specific ARARs in the AST area within a time frame that is comparable to that offered by other active remedial altematives based upon the presence of a residual source. All other altematives can be implemented to achieve and verify compliance with ARARs within a reasonable time frame. 9.2.3 Long-Term Effectiveness and Permanence Altematives 1 and 2 will not provide long-term protection against the risks posed by contaminated groundwater and soils in the AST area. Also, Altemative 1 does not provide a monitoring component to verify the long-term effectiveness of natural attenuation. Altemative 2 will allow Site contaminants to remain in the AST area for a greater period of time than Altematives 3,4 and 5. However, off-Site risks to human health and the envfronment are not expected with any Page-19- 500032 altemative. A permanent remedy will be achieved more quickly by Altematives 3 and 4, since contaminant mass will be removed more quickly from the AST area soil and groundwater, rather than by reliance on solely natural biological and physical processes under Altemative 2 or by groundwater freatment alone under Altemative 5. Altematives 3,4 and 5 are expected to perform similarly in the FPP area over the long-term, based upon the low concenfrations of chloroform remaining in soil and groundwater. 9.2.4 Reduction of Toxicity, Mobility, and Volume through Treatment Altematives 1 and 2 do not include remedies that involve active treatment in the AST or FPP areas. Therefore, these altematives would not actively reduce contaminant toxicity, mobility, or volume. Passive reduction would occur in both areas as a result of natural attenuation processes. For Altematives 3 and 5, active control and removal of mass would occur via SVE/AS or groundwater exfraction in the AST area, but would not occur in the FPP area. Altemative 4 would control and remove contaminant mass at both the FPP and AST areas using SVE/AS treatment and groundwater exfraction and freatment, respectively. However, the relative reduction achieved in the FPP area by pump and freat Altemative 4 would be comparable to that offered by natural attenuation under Altematives 1,2, 3 and 5, based upon the low concenfrations and limited mass of contamination present m the FPP area. Altematives 3 and 4 would also provide secondary reduction of toxicity, mobility, and volume through treatment by enhancing natural biodegradation processes that will reduce ethylbenzene and xylene mass in the AST area. The oxygen delivered to groundwater via air sparging will likely augment aerobic biodegradation ofthese contaminants. 9.2.5 Short-Term Effectiveness The relative short-term effectiveness provided by Altematives 1 and 2 is comparable and greater than that provided by Altematives 3,4 and 5, because Altematives 1 and 2 do not involve the completion of intmsive remedial constmction work within areas containing contaminated groundwater or soils. Altematives 3,4 and 5 include the constmction of an active remediation system in the AST and/or FPP areas. A limited amount of intmsive constmction work (i.e., new SVE/AS wells, groundwater exfraction wells, new monitoring wells/points) will be required for these altematives, within areas containing contaminated groundwater and/or soils, to complete remedial system installation. This work can be completed using conventional constmction equipment and techniques and standard measures to ensure worker health and safety. The relative short-term effectiveness achieved by Altemative 3 is greater than that achieved by Altematives 4 and 5, because a pilot SVE/AS system is already in-place and would only require minor modifications for full-scale implementation. The relative short-term effectiveness provided by Altematives 4 and 5 is comparable, since both require the installation of groundwater exfraction and freatment systems. Page -20- 500033 9.2.6 Implementability In general, all five altematives are implementable. Altemative 1 is the simplest to implement, followed in order of ease by Altematives 2, 3, 5, and 4, considering that an operational SVE/AS system for Altematives 3 and 4 already exists at the Site. Materials, services, and equipment associated with the implementation of each remedial altemative are generally available on the U.S. mainland and on larger islands, such as Puerto Rico. Certain units, such as the low-profile air stripper (i.e., Altematives 4 and 5), and associated spare parts are somewhat less widely available in the Virgin Islands, and would need to be manufactured and shipped from the U.S. mainland, necessitating a longer lead time. Also, Altematives 3, 5, and 4 (in that order) are increasingly more intensive in terms of operation and maintenance than Altematives 1 and 2. 9.2.7 Cost Costs for each remedial altemative increase in the following order: Altemative 1, Altemative 2, Altemative 3, Altemative 4, and Altemative 5. However, most ofthe capital costs for the SVE/AS system associated with Altematives 3 and 4 have aheady been incurred as a result ofthe pilot SVE/AS system. 9.2.8 Territorial Acceptance VIDPNR has been consulted throughout this process and concurs with the Selected Remedy, Altemative 3, and the Contingency Remedy, a combination of Altematives 4 and 5 for groundwater only. 9.2.9 Community Acceptance Public comment on the RI, FS, and Proposed Plan was solicited during a formal pubhc comment period originally designated from June 27 to July 27,2001. In response to public request for additional time, EPA extended the public comment period an additional 15 days tp August 11, 2001. Comments generally favored the Preferred Altemative. Appendix C contains a summary of community responses to the Selected Remedy. 10.0 PRINCIPLE THREAT WASTES The NCP establishes an expectation that EPA will use freatment to address the principle threats posed by a Site wherever practicable (NCP Section 300.430(a)(l)(iii)(A)). Identifying principle threat wastes combines concepts of both hazard and risk. In general, principle threat wastes are those source materials considered to be highly toxic or highly mobile that generally cannot be contained in a reliable manner or would present a significant risk to human health or the environment should exposure occur. Conversely, non-principle threat wastes are those source materials that generally can be reliably contained and that would present only a low risk in the event of exposure. The manner in which principle threats are addressed generally will determine whether the statutory preference for treatment as a principle element is satisfied. Page-21- 500034 The source materials identified at the Site include contaminated soils and groundwater in the AST area. The predominant contaminants of potential concem are ethylbenzene, xylene, and chloroform. These source materials constitute principle threat wastes; therefore, the statutory preference for treatment is applicable to the AST area. In the FPP area, groundwater is impacted by chloroform. However, recent groundwater sampling results indicate that the chloroform concenfration has decreased since 1998 to below its MCL as a result of natural attenuation, excluding a localized area near temporary monitoring well FPP- VMP-ID. In Spring 2000, a soil vapor extraction/air sparging pilot study was performed at both the AST and FPP areas to better assess the effectiveness of SVE/AS freatment in these areas. Results of the pilot study supported these conclusions: • SVE/AS would be an effective technology for removing ethylbenzene and xylene from the AST source area soils and groundwater. AS freatment would also enhance the conditions for aerobic biodegradation ofthese contaminants. SVE/AS would not be effective for freatment ofthe FPP area, based upon the low afr permeability of soils and the low chloroform concenfrations remaining in the soils and groundwater in this area. In addition, recent groundwater samphng (November 2001) in the AST area has shown that concenfration of toluene, ethylbenzene and xylenes are below the MCLs. Thus, SVE/AS is a reliable remedy to accomplish active source confrol and contaminant mass removal in the AST area. Based upon the low concentrations and limited mass of contamination in the FPP area, natural attenuation is expected to continue to reduce chloroform levels. 11.0 SUMMARY OF THE SELECTED REMEDY Based upon consideration of CERCLA requirements, the detailed analysis of altematives, and public comments, EPA has determined that Altemative 3 (SVE/AS for the AST Area, MNA for the FPP Area, and Institutional Confrols) is the appropriate remedy for the Virgin Island Chemical Superfund Site. EPA has also selected a contingent remedy in the AST and FPP areas which includes a groimdwater exfraction and freatment remedy to assure the MCLs for groundwater are achieved in a reasonable time frame. 11.1 Rationale for Selected Remedy Altemative 3 either meets or exceeds benefits associated with the selecting criteria when compared to the other altematives. The Selected Remedy will reduce risk to human health and the environment through the following: • As required, Altemative 3 meets the threshold cleanup evaluation criteria (overall protection of human health and the environment and comphance with ARARs). Page-22- 500035 Altemative 3 provides very good long-term effectiveness and permanence. Altemative 3 actively controls the source materials and removes contaminant mass in the AST area. Altemative 3 mitigates the human health risks (defined by the risk assessment). Altemative 3 is readily implementable. An operational SVE/AS system for Altemative 3 aheady exists at the Site. Altemative 3 offers a cost-effective solution that meets the cleanup goals for the Site. The Selected Remedy achieves the appropriate balance considering Site-specific conditions and criteria identified in CERCLA and the NCP. The contingency remedy (Altematives 4 and 5) also achieves these criteria. 11.2 Description of the Selected Remedy The principle components ofthe Selected Remedy (Altemative 3) are as follows: SVE/AS for the AST Area • The existing SVE/AS system will be expanded to actively freat the entire volume of: 1) contaminated groundwater exceeding MCLs and 2) contaminated soils exceeding SSLs. Air sparging will be used to strip VOCs from groundwater, and soil vapor exfraction will be used to recover sparged VOC vapors and to remove VOCs from the unsaturated zone soils. • SVE/AS system performance monitoring will be required throughout the duration ofthe system operation and maintenance to verify and monitor freatment system performance and to assess remedial progress, as approved by EPA. • SVE/AS system operation will continue to operate until the EPA's SSLs in soils and groundwater MCLs are achieved. It is anticipated that SSLs and MCLs will be achieved in less than five years. • Air discharge criteria and compliance monitoring will be in accordance with federal and territorial requirements. • Achievement of soil cleanup goals will be verified by collecting confirmatory soil samples across the impacted area. Sampling will be performed using an appropriate grid system, with samples collected at appropriate depth intervals to the water table at each grid node within the contaminated area. Page -23- 5 0 0 0 3 6 Long-term groundwater monitoring and reporting will be initially performed on a quarterly basis. Groundwater samples will be collected for VOCs analysis, and field measurements will be taken for water quality parameters (i.e., dissolved oxygen, conductivity, temperature, pH, and oxidation reduction potential) at MW-1, MW-6, MW- 8, MW-10, and at least three additional monitoring wells to be installed at locations approved by EPA. Water level measurements will be taken at all existing monitoring wells/points. The frequency of long-term monitoring will be subjected to annual review and may be modified, as approved by EPA. Long-term groundwater monitoring will continue until the groundwater quality achieves MCLs. MNA for the FPP Area • Long-term groundwater monitoring and reporting will be initially performed on a quarterly basis. Groundwater samples will be collected for VOCs analysis, and field measurements will be taken for water quality parameters at MW-2, MW-7, MW-11, MW- 13, and at least three additional, existing and/or new monitoring wells approved by EPA. In addition, samples will be collected for analysis of intrinsic biodegradation parameters (e.g., total organic carbon, nifrate, sulfate, ferrous iron, hydrogen sulfide, methane) at MW-2, MW-11, and at least two other well locations approved by EPA. Water level measurements will be taken at all existing monitoring wells/points. The frequency of long-term monitoring will be subjected to annual review and may be modified, as approved by EPA. Long-term groundwater monitoring will continue until the groundwater quality conforms with MCLs. • The environmental monitoring results from the FPP area will be used to confirm that the VOC plume is attenuating and that its leading edge is not advancing downgradient. Downgradient monitoring wells, as identified above, will be used to frack the VOC plume exceeding MCLs. The monitoring results will also be compared against feasibility study estimates regarding natural attenuation rates, with the results of updated frend analyses included as part of quarterly remedial progress reports. • Groundwater exfraction and freatment has been retained as a contingency remedy for this and the AST area, as described in Section 11.3, which will be implemented in the future, if warranted based upon monitoring results. The decision to implement the contingency remedy will be based upon evidence (e.g. statistical analysis, modeling) that the VOCT plume is attenuating at rates that are significantly less than feasibility study predictions and that are less than cleanup rates that could otherwise be achieved by the contingency remedy. Institutional Confrols The Department of Planning and Natural Resources in consultation with EPA, will utilize institutional confrols (in the form of existing well permitting laws and regulations) to limit the pumping of groundwater at the Site to prevent interference with the selected remedy Page -24- 500037 and to also prevent human exposure to contaminated groundwater until MCLs are achieved. 11.3 Description of Contingency Remedy In addition to the Selected Remedy, EPA has retained groundwater exfraction and freatment as a contingency remedy for groundwater at the AST and FPP areas. The contingency remedy will be implemented in the event that the VOC plume is attenuating at rates that are significantly less than feasibility study predictions and that are less than cleanup rates that could otherwise be achieved by the contingency remedy. The total capital cost ofthe contingency groundwater remedy for the AST and FPP areas is $1,067,840. The contingency remedy for the AST Area and FPP Area groundwater includes: • Installation of one or more groundwater extraction wells to achieve hydraulic confrol of groundwater exceeding MCLs and to actively remove VOCs from the aquifer. • Above-ground treatment of groundwater using air stripping to reduce VOC concenfrations below the VIDPNR criteria permitted for subsequent surface water discharge to the River Gut. • Completion of freatment system performance and compliance monitoring and long-term groundwater monitoring, as generally described in Section 11.2, until MCLs are achieved. 12.0 STATUTORY DETERMINATIONS Under CERCLA Section 121, EPA must select a remedy that is protective of human health and the environment, that complies with ARARs, is cost effective, and uses permanent solutions and altemative freatment technologies or resource recovery technologies to frie maximum extent practicable. In addition, CERCLA includes a preference for remedies that include freatment as a principle element, which permanently and significantly reduces the volume, toxicity, or mobihty of hazardous substances. 12.1 Protection of Human Health and tbe Environment The Selected Remedy will protect human health and the environment through the use of an SVE/AS system which will remove ethylbenzene and xylene from the AST source area soils and groundwater to achieve MCLs and SSLs. AS freatment will also enhance conditions for aerobic biodegradation ofthese contaminants. Natural attenuation will continue to be implemented in the FPP area for low-level residual VOC contamination in groundwater. Additionally, institutional controls will be implemented at the Site to reduce the potential for human exposure to contaminants. These confrols will restrict land and/or groundwater use until the SSLs and MCLs are achieved. Page -25- 500038 In addition to source control via SVE/AS, a groundwater exfraction and freatment system to capture and freat impacted groundwater at the AST area was considered m the FS process. Ofthe two treatment options, SVE/AS freatment was considered more effective for these reasons: (1) SVE would rapidly remove and reduce the contaminant source in the unsaturated zone, whereas groundwater exfraction alone would not address the unsaturated zone; (2) AS is expected to be more effective at removing contaminants from groundwater than conventional groundwater extraction and freatment based upon the localized nature of contaminant distribution, higher silt/clay content ofthe Site soils, and poor yield ofthe shallow aquifer. AS woiild also better facilitate aerobic biodegradation processes via infroduction of air; and (3) SVE/AS would be more readily implemented considering that a system is already in place from the pilot study. 12.2 Compliance with ARARs The Selected Remedy will comply with all ARARs for the Site; no waivers will be necessary. The Site groundwater quality will be restored to federal MCLs for drinking water (40 CFR Part 141), and the impacted subsurface soils will be restored to EPA SSLs (which are TBCs) for protection of groundwater quality. The SVE/AS system will operate in accordance with national emissions standards for hazardous air pollutants (NESHAPS; 40 CFR Part 161) and territorial afr pollution confrol requirements (VIC, Title 12, Chapter 9). Well installation and abandonment will be performed in accordance with Territorial requirements (VIC Title 12, Chapter 5). 12.3 Cost Effectiveness The Selected Remedy is cost-effective and represents a reasonable value for the money to be spent. In making this determination, the following definition was used: "A remedy shall be cost- effective if its costs are proportional to its overall effectiveness" [NCP Section 300.430(f)(ii)(D)]. This was accomplished by evaluating the "overall effectiveness" of those altematives that satisfied the threshold criteria (i.e., were both protective of human health and the environment and ARAR-compliant). Overall effectiveness was evaluated by assessing three ofthe five balancing criteria in combination (i.e., long-term effectiveness and permanence; reduction of toxicity, mobility, and volume through treatment; and short-term effectiveness). Overall effectiveness was then compared to costs to determine cost-effectiveness. The estimated present worth cost ofthe Selected Remedy is $1,404,260. A significant portion ofthe capital costs for the SVE/AS system associated with the remedy have aheady been incurred as a result ofthe pilot SVE/AS system. 12.4 Utilization of Permanent Solutions and Alternative Treatment Technologies (or Resource Recovery Technologies) to the Maximum Extent Practicable The Selected Remedy utilizes permanent solutions and freatment technologies to the maximum extent practicable. In the AST area, the existing SVE/AS system will be used to actively freat and remove contaminant mass from AST area soil and groimdwater. SVE/AS provides is a pennanent remedy, which will be achieved more quickly than other altematives relying on natural biological and/or physical processes alone. In the FPP area, MNA will be implemented to achieve reduction in chloroform levels in groundwater comparable to that offered by an active exfraction system. Based upon the low concentrations of chloroform remaining in soil and groundwater, natural Page-26- 5 0 0 0 3 9 attenuation is expected to perform similarly in the FPP area over the long-term. Together, SVE/AS and MNA provide the highest effectiveness at the least cost. Of those altematives that are protective of human health and the environment and comply with ARARs, EPA has determined that the Selected Remedy for the Site provides the best balance in terms of long-term effectiveness and permanence, treatment, implementability, cost, and territorial and community acceptance. 12.5 Preference for Treatment as a Principle Element An SVE/AS pilot study was performed in Spring 2000 at both the AST and FPP areas to better assess the effectiveness of SVE/AS freatment in these areas. The results ofthe pilot test supported the conclusions that: (1) SVE/AS would be an effective technology for removing ethylbenzene and xylene from the AST source area soils and groundwater, (2) AS freatment would also enhance the conditions for aerobic biodegradation ofthese contaminants, and (3) SVE/AS would not be effective for freatment ofthe FPP area, based upon the low afr permeability of soils and the low chloroform concentrations remaining in the soils and groundwater in this area. The Selected Remedy satisfies the statutory preference for freatment by using the operational SVE/AS system that already exists at the Site to treat groundwater, saturated soil, and unsaturated soil at the AST source area. Additionally, MNA will be implemented in the FPP area for low- level residual VOC contamination in groundwater, supported by recent data which indicate that natural attenuation is adequately protective without the need for active treatment. The Selected Remedy is both technically practicable and cost effective as a result of implementation ofthe pilot system. 12.6 Five-Year Review Requirements Because contaminated soils and groundwater may remain on-Site above levels that allow for unlimited use and unrestricted exposure for approximately 5 years, the Selected Remedy will be reviewed no less often than once every five years consistent with Section 121 of CERCLA and Section 300.430(f)(4)(ii) ofthe NCP. The 5-year review includes a review ofthe groundwater monitoring data and an evaluation as to how well the Selected Remedy is achieving the RAOs and ARARs that it was designed to meet. 13.0 DOCUMENTATION OF SIGNIFICANT CHANGES The Proposed Plan for soil and groundwater contamination in the AST and FPP areas at the Virgin Island Chemical Superfund Site was released for public comment in June 2001. The Proposed Plan identified Altemative 3, Soil Vapor Exfraction/Air Sparging (SVE/AS) with MNA and Institutional Confrols, as the Preferred Altemative. Altemative 4 was also identified as the Contingency Remedy at that time. Comments were received during the public comment period. No significant changes were made to the Preferred Altemative with the exception of including a contingent remedy for groundwater in the AST area in the event that the SVE/AS remedy fails to Page-27- 500040 meet performance standards. The contingent remedy shall be groundwater exfraction and freatment in the AST and FPP areas to assure that MCLs for groundwater are achieved in a reasonable time frame. Page -28- 500041 APPENDIX A FIGURES 500042 REFERENCE 1.) MAP TAKEN FROM U.S.G.S. 7.5 MINU-fE QUADRANGLE OF CHRIS-nANSTED. VIRGIN ISLANDS. 2000 scole 2000 feet 003-6016 AM AS SHOWN DATE: 11/07/00 US01-029 DR SUBTIIU: 03 SITE LOCATION MAP Golder Associates VIRGIN ISLAND CHEMICAL SITE nouRE 1 FIGURE 1 500043 TW-S >l I V 'T' '7' m 111 [T1 frl M m mxsl l?l 1=^ •=• fsi Tsl Tsi Tt! rii M Tal " ° ^ , * • L-J ej llJ IJ 111 Id 111 t l I!) ItJ IU W W W W l:'J w w ej w "// / / I LEGEND I MW-t2 C -* « n s I 1 ( — 1 ( 1 <*> «f: ^•. • TJ iouXM GRa«c«awT ooRREcnoNM. n c u r r ] . ' N i I LEGEND I I BUIUJINO STREAM ' ROAO ™ TREE IME APPROX. LOCATICM OF CFFS1E WELLS SHALLOW HOMTmNO WEU. LOCATION ONSITE PRODUCTION WELL LOCATION DEEP MCMTtlRINO WEU. LOCATION • n — — GROUNDWATER CONTOUR (FEET MSL) 7.79 GROUNDWATER OEVATION (FEET MSL) REFERENCE 1.) DRAWINO TAKEN FROM RGURE 4 - 9 QF RJ. REPORT ENTITLED *DEEP GRdUNDWATER ELEVATION CONTOURS OCTOBER 21, 1888*, DATED 02/17/DO AND WATER LEVEL MEASUREMENTS TAKEN ON 1 0 / t l / « 8 BY McLAREN/HART, Ma ISO scale ISO feet •- t • " " " 003-60ia M m AM " • " • So-" IW. • « « AS SHOWN • • " OTflB/OO •"•- Msm-mr • l u n e 03 Golder Assodates DEEP GROUNDWAtER CONTOUR MAP -10/21/98 VIRGIN ISLAND CHEMICAL SITE r 500049 FIGURE 7 0.5 Hydrographs for wells In AST Area •MW-8 (Deep) + MW-6 (Shallow) —a—Rainfall 0.18 0.00 1/22/98 1/24/98 1/26/98 1/28/98 1/30/98 2/1/98 2/3/98 2/5/98 2/7/98 2/9/98 2/11/98 Date 18 No.: 003-6016 I BY: DSL I K B ^ M ^ OSL SAS SCALE AS SHOWN DATE 07/27/00 FILE No.: Hydrographs.XLS 01RECT0RY-. Golder\FS\Hydrogeo Golder Associates HYDROGRAPHS FOR SHALLOW AND DEEP WELLS IN AST AREA VIRGIN ISLAND CHEMICAL SITE FIGURE 8 Hydrographs for wells in FPP Area 1/22/98 1/24/98 1/26/98 1/28/98 1/30/98 2/1/98 Date •MW-7 (Deep) •• MW-2 (Shallow) • Rainfall 0.18 2/3/98 2/5/98 2/7/98 2/9/98 2/11/98 JOB No.: OR BY: 003-6016 OSL DSL SAS SCALE AS SHOWN DATE; 07/27/00 FIL£ No.; Hydrographs.XLS DIRECTORY. Golder\FS\Hydrogeo Golder Associates HYDROGRAPHS FOR SHALLOW AND DEEP WELLS IN FPP AREA VIRGIN ISLAND CHEMICAL SITE FIGURE 9 « MW--IO SBAST-10 SBAST-6 tf-8 SBAST- i CO ^ 11 f < ^ i UJ z ",SBisT-3 ' " ' 0 f ~ i r " i r - l r—) r-\ r-^ r I . I . I l . l 1,1 1,1 l . l I I J ! I J I I J I I J I I T I I I I I l ' l i ' l i " i l ' l l ' l l ' l 1 l . l i_J i - J i_J i._J i _ j I ,SBB-6 M w - i / r n q - i SBAST-9 SBAST-4 SBE- SBB-16 •SBB-15 J_ NOTES MW-13 O LEGEND I.) SOIL BORING LOCAHONS ARE APPR0MMA1E.\ \ 2.) SOIL BORINGS SHOWN WITHM SHAOCO AREA ' EXHIBITED OEIECnONS OF EtmUEMZENC ANO XYLENE ABOVE MGW SSLS (DAF-10) REFERENCE I.) DRAWmO BASED ON nCURE 4-11 OF THE RJ. REPORT EHPTIED TSnMATtD AREAL EXTENT OF IMPACTEO SOIL - AST AREA* M1E0 2/17/00. PROVIDED DT MelAREN/HART. MC. ^ - PRODUCTUN WEa LOCATION Iff SHALLOW MOMIDRINC WEU LOCATION O DEEP MONITORINO WEU LOCATION • SOIL BORING SAMPLE LOCATION ( ~1 EXISTING ABOVEGROUND STORAGE TANK LOCATION C I I J FORMER ABOVEGROUND STORAGE TANK LOCATION APPRONMAIE AREA OF IMPACTEO SOIL ABOVE SSU 40 •cc1« 003-6016 MJS AS SHOWN 11/07/00 USOI-022 03 Golder Assodafes ESTIMATED AREAL EXTENT OF IMPACTED SOIL - AST AREA VIRGIN ISLAND CHEMICAL SITE 500052 FIGURE 10 TW-5^ ,TW-4 ,TW-2 • w m a M - l »-• M - e ••-IO r - t eavp-M « m H ( i i t t i ) u - u l>.«-M.T U-71 a - n »««« n - j s coHconmiMM (ppb) TOtUtNC - « 0 IU nuDIC - t9,M9 TOUItIC - « » IU C M l K N I t W - I M f n u M t - u , m raumc - 0.1 UJ tlHOBtHIOe - 1» imx>« - Tt numit - 1 u cnnucNztHC - 0 3 i « nuNC - > « nUKNC - 1 u IIHIUtNZOC - 1 U x n o i c - » « B M i u S n n t w " - 10 u m o K - 19 s u i n j i o m - i " ni-*> IW-J" IW-«* IW-»» OCFTH (n h f ) t i - n i i - » n - i » M - M lO-JO COMCtMIMIWll (ppt) nnuoit - s u nHYUCXtCNt - •.»•» f nUNC - l<.«M f rauitw - J w (nnuiCNHNC - 9 u i m m - 9 u rouJtHt - » u miMC - 9 u m u m - 9 u CnmBtNZCNC - 9 u n a m - 9 u raUKNC - 9 u cnniBtNZoit - ] J i r n m t - 9 « DQIES: J csniuTto coHctNnunoH MWIYTC m l DC7CCTC0 ABOVt RtPORIWC UUIT CSTIMAItO CONCENIRAIIOH coNcCNiRAnoH cxcccos net (rrniKHZCNt - 700 pph, nUNt - 10.000 ppk) coHctNnunoNS reou KUPORART ocas *nc scnccNim RcsuiTS rnou ONSIC CC (stPicuaw « « ; ) M.I msuiTs w c rnou uMtcH/APim. I M S wvcsncAnoN CXCtPT SCREOIMC RCSUITS FItOO TCWOIUfn' m u s (SCPTEMSCR •>«;) LEGEND PRODUCTION W E a LOCATION SHAaOW MONITORING W E a LOCATION DEEP MONITORING WEU LOCATION GEOPROBE GROUNDWATER SAMPLE LOCATWN TEMPORARY W E a LOCATION —1V>— ETHTLBENZENE CONTOUR (ppb) I I EWSTINO ABOVEGROUND STORAGE TANK LOCATION NOTES 1.) FOR COMPARISON, CONCENTRATIONS FROM IHE MAY 2000 SAMPLING EVENT ARE REPORTED IN PARENTHESES NEXT TO W E a ID. A a UNITS ARE ppb. REFERENCE 1.) DRAWINO BASED ON nCURE 4 - 1 3 OF THE R.L REPORT ENDTUD "ESTIMATED AREAL EXTENT OF ETHYLBENZENE-IMPACTED SHAaOW GROUNDWATER - AST AREA* DATED J / 1 7 / 0 0 . PROVIOEO BY McLAREN/HART, INC. 30 •cole 30 003-6016 MJS AS SHOWN 11/07/00 USOI-024 03 Golder Assodates ESTIMATED AREAL EXTENT OF ETHYLBENZENE-IMPACTED SHALLOW GROUNDWATER IN 1998 • AST AREA VIRGIN ISLAND CHEMICAL SITE 500053 FIGURE 11 TW-5^ ,TW-4 Ifr- MW-10 .TW-2 ,TW-3 1—1 1 . 1 II! < - j l.i Pi ' — > 1 • > 1 » ^ — ' 1 > p m ^ P - 2 •7 MMHTCHANCC euuMc v a m x t> m - i w - « •»-• w r - i o F - l e i f f v - M « T O ( n » , t ) u - u iT.4-n.r t J - M u - n u m a i i N a - n coNcormiiOH (ppn) nHUDC - 4M UJ cnnutNZDa - i t , t * nuMc - m t M rauitic - eoa UJ m u o i c - 0.1 Ul t i m i K H I O C - IT n u m - Tt i m u t m - 1 u x n n i c - » « reuicNc - 1 u ( w n K H i o c - 1 tt x n i n t - » H O N i m o D c ' - 10 u iniDIC - 13 s n n t n IW-I« i w - r i » - j » IW-4» T»-V KPTM (11 bfl) l t - » I t - I t I t - J t M-J. 10-M nxucNc - 9 u nrniBCMztw . t,»»» 1 n u w - >».««• f TOUICW - 9 U cnouoncNt - 9 « n u M - 9 u mucHC - 9 u cmucHztNC - r u J mSML - 9 « mucHC - 9 u t n m w M w e - 9 u n u K - 9 u ^TOUKIIt - 9 U A M T U C N Z I M - 1 J n u M t - 9 u IgatS: I u t ( s m u i c o coNCCNiiiAnoN 4MLVTC HOT OEICCICO ABOVt RtPOBnNO U l i l c s n u i i o coMCCNriuiioN coHccNmAnoN cxcccos u a (cnonscNzcNC - roo ppt. KTUNC - lo.ooo ppk) coHcCHnunoHS rnou i t u r o i u i n ' WCLLS ARC SCRCCNMG RtsuLis mow oHsire cc (SCPICMBDI i t i j ) AU. RCSULTS ARC ntou UARCH/APRH. i t t t tmsiiGAnoH CXCCPI SCRCCNIHO RCSULtS rROH ICURORART WtllS (SCPICUSCR I t l T ) LEGEND c -f X CD / — - T k I PROOUCIION w e a L O C A T I O N SHAUOW MONITORING W E U LOCAHON DEEP MONITORINO WELL LOCATION GEOPROBE GROUNDWATER SAMPLE LOCATION TEMPORARY W E U LOCATION XYLENE CONTOUR (ppb) EXISTING ABOVEGROUND STORAGE TANK LOCATION FORMER ABOVEGROUND STORAGE TANK LOCATION NOTES I.) FOR COMPARISON, CONCENTOAHONS fHOM THE MAY 2000 SAMPLING EVENT ARE REPORTED IN PARENTHESES NEXT TO WEU 10. ALL UNITS ARE ppb. REFERENCE 1.) DRAWING BASED ON PCURE 4 - 1 2 OF TOE R.L REPORT ENTTOEO tSDMATED AREAL EXTENT OF XYLENE-IMPACTED SHALLOW GROUNDWATER - AST AREA' DATED 2 / 1 7 / 0 0 , PROVIDED BY McLAREN/HART. INC. 30 ftcole 003-6016 MJS AS SHOim 11/07/00 OS01-023 03 Golder Associates ESTIMATED AREAL EXTENT OF XYLENE-IMPACTED SHALLOW GROUNDWATER IN 1998 - AST AREA VIRGIN ISLAND CHEMICAL SITE 500054 FIGURE 12 ItLKX B cmv-T OWP-t e»pp-t OUT-10 O r w - l l eupp-ij CWPP-U OlW-14 CHIT-IS CKIT-H OlWP-lT e»FT-ii e n r - n o n r - t i COPV-U cwn>-j4 e»pp-i9 c u p p - n 04PP-J7 e » p p - u e » p p - j t « CIIPP-30 C»PP-Jf e»pp-M . c u r r - u * m p p - j 4 CVPP-M oroR-i • w - l W - J mr-T inc-il VW-ll W»-IJ ^ W - 1 4 P-I M»-I9 OCIM 10-19 »-» M-JT.. U - U I I - l e M - J t f l - 3 0 JI-J4 l - I O J7-30 I T - J l t - l l I J - l t 11-19 l l - J T t i - n 14-M t - I O 14-Jt n - ) i 91-34 34-37 11-17 13-29 31-34 31-39 17-30 » - l t l t . l - l U 11.9-29.9 94-74 30-40 137-1« 30-40 I24-IJ4 i M m o m 0 « - t t c t u m n M i m NO t i t •4 74 79 »fr NO J . j r t RO 3 4 M 7 MD i.toe 93 3 94 t.n4 t l 4 M NO I.UI t t3 NO I t 31 i.tea NO « 3J ND NO NO 4 l t SIENOTt 1 CWP J . (AppROji nn ri.) •'• "I I 'co«««t( CCNCRAroR / BUUIMO ¥ •WtMCM l'A^ United Stales Code VIC - Virgin Islands C^ode 500069 Table IT Summary of Analytes Detected in Soli above Screening Levels Virgin Island Chemical SKe, St. Croix, U.S. Virgin Islands Area of Site Medium Parameter Screening Level Sample ID Sample Date Sample Interval Concentration (n bis) VOC Constltuehts lln ua/Kal AST Area Subsurface Soil Ethylbenzene 13,000= Xylenes (totaO 190,000* SBB-1 SBB-2 S8B.4 S88.4 SBB-4 S8B-11 S88-17 SBB-17 Sa^ST•2 SBB-1 SBB-4 SB6-4 S8B-11 SBB-17 SBB-17 Jan-85 May-86 May-ge May-86 May-86 li«ay-86 May-96 May.96 Jun-97 Jan-SS May-96 May-96 May-86 May-96 May-96 6-8 22-24 10-12 12-14 20-22 20-22 14-16 20-22 8-10 6-8 12-14 20-22 20-22 14-16 20-22 57,000 32,000 150,000 100,000 170,000 58,000 DJ 320,000 270,000 34,000 DEJ 310,000 E 630,000 980,000 320,000 D 2.000,000 EJ 1,600,000 EJ SVOC CcnsBtuents lln UQ/XQI Former Laboratory PtArea Suifaes Soil Pentachlorophanol^ 30= Storm Drains Surface Soil Isophorone' 500= Inorganic ComDounds (In mofltol S8F-3 SOSSO-2 Jan-85 Oct-87 River Gut (Fairplains) Surface Soil Arsenic' 1.64' ASTArea Subsurlaoe Soi Cyanide' 40= FPG-2 Sep-87 0-1 1,800 J 2500 ASTArea Fonner Drum Area Former Laboratory Pit Area Storm Drains Surface Soil Surface Soil Surface Soil Surface Soil Iron' Manganese' Iron' Iron' Iron' Arsenic' 31933' i,«oo' 31833' 31933' 31833' 1.64' SB8-1 SBE-1 SBB-1 SBD-4 S8F-3 SDCSD-2 SCCSO-2 SOCSO-3 Jan-85 Jan-85 Jan-85 Jan-85 Jan-85 Oet-97 Oc»-87 Oet-87 0-1 0-2 0-1 0-1 0-1 0-1 0-1 0-1 32,100 'J 32,200'J 1,860 37,300-J 63,400-J 58,800 8.8 3.7 Z 8 J Farmer Drum Area Subsurface Soil Cadmium* SB8-1 SB8-1 SBE-1 SB640-1 Jan-85 Jan-85 Jan-85 Jun-87 6-8 24-26 20-22 10-12 60.2 N*J 47.3 N-J 51.7 10.1 • 'Site-specific bacKground level ^SB>A RBC: Risk-based saeening cortoentration =USEPA SSL- Based on migration to groundwater pathway. No SSL has been established for total xylenes, so the most conservative value for an isomer (o-xylene) has been used for screening purposes. 'Chemical does not constitute signHkant risk based on she risk assessment (McLaren-Hart 2000). 'Arsenic, iron and manganese were induded in the Human Health Risk Assessment However, all rials and hazards assodated with exposure to these chemicals are vMin ^ A ' s acceptable levels and are not considered to be a heaRh concern. D - Analyte quantitatad at a dIutxNt. E - Exceeded calbratian range of instrument J • Estimated value. N - Spile recovery not wihin control UmMiu na - data not available * - Duplicate analysis not VMthin control imits. • • Not applicable ft bis - feet below land surface 500070 O.AOin-6OlCVaCU»llVI'n0i4gni1KOD T d t e J d l Golder Associates P a g e l o T I Table 15. Summary of Analytes Detected In Groundwater above Screening Levels Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands Area of SHe Parameter Screening Level Well ID Sample Date Concentration VOC Constituent5 lln uoILl FPP Area Chloroform 100- ASTArea EthyH>enzene 700' Xylenes(total) 10,000* MW-2 MW-2 MW-2 MW-2 MW-2 MW-2 ^m-^ MW-1 MW-1 MW-1 MW-1 MW-1 MW-1 MW-6 MW-6 MW.« MW-6 MW-6 MW-6 MW-6 MW-1 MW-1 MW-1 MW-I MW-1 MW-1 MW-6 MW-6 MW-6 MW-6 MW-6 MW-6 MW-6 Jun-96 Jan-9e Mar.88 Oct-98 Oct-98 Mar-00 Fel>-95 Jan-98 Mar-88 Mar-00 Jun-01 Aufl-OI Nov-01 Jun-96 Jan-98 Mar-S8 Mar-00 Jun-01 Aug-01 Nov-01 Jan-98 Mar-88 Mar-00 Jun-01 AuB-01 Nov-01 Jun-96 Jan-98 Mar-88 Mar-00 Jun-01 Aug-01 Nov-01 470 1500J 2400 150 580 37 750 20,000 18,000 19,600 28.000 3,500 f70 23,000 22,000 20,000 12.400 26,000 12,000 « 86,000 80,000 89,000 130,000 24,000 (SO 27,000 110,000 98,000 60,700 150,000 83,000 ta Inorganic Comoounds (In uo/LI Fonner O u m Areas Upgradient of Site ASTArea Leacf Lead= Antimon/ 15' 15' e' MW-5 MW-5 MW-5 MW-5 MW-10 MW-10 Feb-95 May-95 Jan-g8 Mar-98 Jan-98 Mar-88 17 20.3 S ».7U 1.1 U 7 J U 50.7 MW-6 Jan-98 ' Sol! Vapor Extraction and Air Sparging system operated in the AST Area t>eginning June, 2(X)1. Wells MW-1 and MW-6 monitor effectiveness of system. 6.2 B Data in bold italics does not exceed screening levels and is included to show recent data trends. 'Treatment Technk^e Action Level (intended fOr applicabon to tap water concentratnns) ¥ederalMCL *Chem\ca\ does not constitute significant risk t>ased on site risk assessment (McLaren-Hart, 2000). 6 • Result is t>etween instrument detection limit and Contract Required Detection Limit J - Estimated value. S • Determined by Method of Standard Addttions. U - Analyte not detected The minimum quantitation limit is listed. 500071 a^ao}.eolevxuxs.v^ljMelmROD Trtiieudi Colder Associates Page 1 of 1 GROUNDWATER SAMPLING RESULTS AST AREA SOIL VAPOR EXTRACTION/AIR SPARGING SYSTEM MONITORING WELLS VIRGIN ISLAND CHEMICAL SITE, ST. CROIX, U.S. VIRGIN ISLANDS Volatile Organics Ethylbenzene Toluene Total Xylenes Total TEX MCL' 700 1000 10000 MW-1 Baseline 6/6/2001 28000 320 130000 158320 3rd Quarter 8/6/2001 3500 72 24000 27500 U 4th Quarter 11/14/2001 170 10 850 1020 U MW-6 1 Baseline 6/6/2001 26000 1300 150000 176000 U 3rd Quarter 8/6/2001 12000 390 83000 95000 U 4th Quarter 11/14/2001 6 1 63 69 ^^^ l! Volatile Organics Ethylbenzene Toluene Total Xylenes Total TEX MCL' 700 IOOO 10000 AST-VMP-ID Baseline 6/6/2001 180 2 550 732 3rd Quarter 8/6/2001 30 7 1900 1900 U U 4th Quarter 11/14/2001 2 2 9 2 U U AST-VMP-2D 1 Baseline 6/6/2001 620 2 2100 2722 3rd Quarter 8/6/2001 680 13 3100 3780 U 4th Quarter 11/14/2001 2 0.5 18 20 II Ul o o o -J to Volatile Organics Ethylbenzene Toluene Total Xylenes Total TEX MCL' 700 1000 10000 AST-VMP-3D Baseline 6/6/2001 170 5 270 445 3rd Quarter 8/6/2001 34 1 160 194 J U J 4th Quarter 11/14/2001 120 4 500 620 U AST-VMP-4D 1 Baseline 6/6/2001 0.5 0.5 0.5 0 U U U 3rd Quarter 8/6/2001 0.5 0.2 0.5 0 U U U _ ^ 4th Quarter 11/14/2001 0.5 0.5 1 0 U u u 1 'MCL - Federal Maximum Contaminant Levels (40 CFR Part 141) Notes: Units are (ig/L Total Xylenes were calculated by the laboratoty. Qualifiers were applied to the results by the laboratory or by Golder Associates following data evaluation. U = non-detect J == estimated 0:Pra|eclsAX)3401S/6oklerlPMr ROD Tebles.xl*/SVE AS Colder Associates Page 1 of 1 APPENDIX C RESPONSIVENESS SUMMARY 500073 RESPONSIVENESS SUMMARY The Proposed Plan for the Virgin Island Chemical Superfund Site (the "Site") was released for public comment on June 27, 2001. The public comment period was scheduled from Jime 27, 2001 through July 27,2001. In response to public request, it was extended 15 days to August 11, 2001. During the public comment period, EPA held one public meeting to discuss the Proposed Plan and receive comments on the Selected Remedy. In addition, EPA received three written comment on the Proposed Plan during the comment period. This document summarizes the questions and concems received during the pubhc comment period. These concems have been grouped into several categories for ease of discussion. EPA's response to each comment follows in itahcs. Residences/Businesses in Site Vicinity 1. One commenter wanted to know if the two residential communities referred to in the Proposed Plan as being north and northwest ofthe Site are the communities of Bethlehem and Profit. Estate Bethlehem and Estate Profit are the two residential communities referred to in the Proposed Plan. 2. Several people mentioned that a sheep farm is located next to the Site. They reported that sheep and goats grazed from the Site prior to it being fenced and asked if EPA had approached the farm's owners. EPA did not contact the farm owners. However, at EPA's request, the parties performing the RI/FS did secure the Site area with a fence in April 2000. 3. A resident was concemed that a water service company is located next to the Site. EPA is aware ofthe water service company's well (Carina Well) and its activities. The Carina well was installed during the fourth phase ofthe Rlfor the Site, within the past two years. The Water Service Company (Carina) was required ta apply far territory permits to drill the well and to pump the well, respectively, bath of which were received and approved by the Virgin islands Department of Planning and Natural Resources (DPNR). The Carina well is only permitted to pump water far nan-patable use. In addition, the company must sample the water on a regular basis far drinking water parameters as part of its permit to verify that the water meets drinking water standards. EPA conducted an independent check on the Carina well ta verify sampling results obtained by Carina. The data show that the groundwater results are below MCLs. The Carina well is upgradient ofthe Site. The hydrographs provided as Figures 8 and 9 ofthe ROD further indicate that the contaminated shallow zone at the Site is not influenced by Carina well pumping. C-1 5 0 0 0 7 4 Health Risks from Site Exposure 4. Several commenters asked whether EPA would investigate reports of heightened incidents of ilhiesses such as cancer in the local community to determine if there is a potential link to past exposure to Site contaminants. EPA explained that the Agency for Toxic Substances and Disease Registry (ATSDR) can perform a public health assessment to determine whether any relationship exists between current illnesses in the community and historical exposures to the Site. EPA offered ta provide concemed residents with a contact name at ATSDR to call and request this service. EPA also repeated that the Site does not pose any unacceptable risks under the current use exposures at bath an-Site and off-Site locations. The contamination at both the Former Process Pit (FPP) area and the Aboveground Storage Tank (AST) area exist below the ground surface, within the unsaturated subsurface soils and groundwater, and it has remained predominantly on the Site. Within the groundwater itself, the contamination is limited to the upper aquifer, which is not in direct communication with the deeper aquifer. Also, the groundwater flows away from residential communities in the Site vicinity. Lastly, groundwater at the Site is nat used for drinking purposes. Currently, the Site is unoccupied and fenced. 5. Another person suggested that EPA conduct a study of persons who consumed sheep from the farm next to the Site to determine the existence of any adverse health effects. This was not identified as a potentially significant exposure by ATSDR in their Public Health Assessment, therefore ATSDR has determined that such a study is not warranted. 6. One person wanted to know the specific health effects of exposure to chloroform, ethylbenzene and xylene. Short-term effects from exposure ta chlaroform via inhalation include central nervous system effects, such as dizziness, fatigue, and headaches. Long- term exposure to chloroform via inhalation ar ingestion may result in liver or kidney damage. Dermal contact with large amounts of chloroform may result in skin rashes. EPA has identified chloroform as a probable human carcinogen, based on the results of animal studies. Exposure to ethylbenzene may result in central nervous system effects such as dizziness, throat and eye irritation, and liver ar kidney effects. Short-term and long-term exposure to high levels of xylenes may cause central nervous system effects such as headaches, lack of muscle coordination, dizziness, confusion, and impairment of balance. Also, eye, nose, and throat irritation, skin rashes, and liver or kidney damage are associated with exposure to xylenes. C-2 500075 7. Another commenter wanted to know if benzene and xylene are cancer causing or carcinogenic compoimds. EPA has identified benzene as a known human carcinogen. Xylenes and ethylbenzene are not carcinogenic. 8. One resident wanted to know about the odor ofthe three contaminants of concem at the Site. EPA described ethylbenzene and xylene as having a gasoline smell, and chloroform as having a sweet, organic smell. 9. One conmienter asked if EPA could calculate the health risks associated with exposure to the Virgin Island Chemical facility when it was still operational. EPA has no way of calculating that type of risk at this time. Information which is necessary to conduct this type of risk assessment, such as records which provide chemical usage and concentrations during the time of facility operation, is not available. 10. One commenter was concemed about the effect of volatile organic compounds (VOCs) on communities downwind ofthe Site over time. Downwind populations are not at risk. Exposure to chemicals downwind of a Site would occur from inhalation of airborne surface soils at the Site. Because ofthe chemical properties associated with volatile organic chemicals, they are nat likely ta remain in surface sails aver time; they will either migrate ta the groundwater ar volatilize to air shortly after they have been introduced to the surface soil. This phenomenon occurs until the contaminants in the surface sail are for the most part gone. Therefore, any airborne surface soils from the Site would not contain the volatile organic chemicals associated with Site activities, because the surface soils no longer contain VOCs.. 11. A commenter asked what EPA means by acceptable levels of risk. EPA evaluates exposures based on the potential risk of developing cancer and the potential far noncancer health hazards. Ihe likelihood of an individual developing cancer, is expressed as a probability. Current Superfund guidelines for acceptable levels of risk are an individual lifetime excess cancer risk in the range of 10^ to 10^, corresponding ta a one-in-ten-thousand to a one-in-a-million excess cancer risk. In other wards, a 1(T* cancer risk means one additional cancer may be seen in a population of 10,000 people as a result of exposure to Site contaminants. For noncancer health effects, a hazard index (HI) is calculated. An HI represents the sum ofthe individual exposure levels compared ta their corresponding reference doses. Whenever a noncancer HI is at the "threshold level" (measured as an HI less than 1), noncancer health effects are not expected to occur. 12. A commenter wanted to know where she could take her well water for annual testing. C-3 5 0 0 0 7 6 // is the responsibility of private homeowners ta test their well water. The Virgin Islands Department of Planning and Natural Resources (DPNR) is available to provide a list of qualified laboratories for this purpose, but the homeowner must make the arrangements and assume the sampling and analytical costs. Sampling of private residential wells would only be performed by EPA if future groundwater monitoring results indicate that the contamination is spreading in the direction of such wells. 13. Another commenter asked how she could obtain a copy ofthe public health evaluation completed for the Site by ATSDR. Persons interested in receiving a copy of this document can call Mr. Arthur Black, ATSDR regional representative. His phone number is (212) 637-4307. A copy ofthe report is also available in the Repository. 14. Inmates from the Golden Grove Adult Correctional Facility in Kingshill, St. Croix submitted a petition expressing concem about health problems within the inmate population. The petition cited several symptoms and illnesses that the iimiates believe can be attributed to Site contamination, and requested a remedy to address their concems. EPA has determined that the contamination at the Site, which is predominantly located within the Site property boundary and below the ground surface, does not pose a significant off-Site health risk. EPA's remedy will reduce an-Site risk ta acceptable levels. Groundwater samples were collected from selected production wells near the Site during the RI, which confirmed that the production wells have not been impacted by Site contaminants. It is further noted that groundwater flows south-southeast fi'om the Site, whereas the Golden Grave Adult Correctional Facility is located northwest (i.e., upgradient) ofthe Site. Nature/Extent of Site Contamination 15. Several commenter asked whether the groimdwater contamination extends beyond the Site boundaries. Groundwater contamination is isolated predominantly within the fence line ofthe property. A small portion of groundwater contamination extends beyond the fence line. Furthermore, the existing data indicates that groundwater contamination is not migrating beyond its current boundary. The SVE/AS system is expected to fully treat the contaminated groundwater in the AST area, and MNA has been and is expected to continue to address the FPP area groundwater.. 16. One commenter read that a gut is present on the Site property and contaminants have entered the gut and reached the sea. C-4 500077 EPA has taken sediment samples from the River Gut, which originates north ofthe Site and drains to the Caribbean Sea. The River Gut joins the Bethlehem Gut approximately 800 feet southeast ofthe Site. They are collectively then called the Fairplain Gut. In consultation with the Department of Interior, National Oceanic and Atmospheric Administration, sediment samples were taken from at least 25 locations from the facility along the River Gut to the ocean. The results showed minimal to no impact from the Site. 17. One commenter asked for an explanation ofthe RI finding that arsenic was detected above its risk-based level in surface soil. The arsenic levels detected at the Site are naturally occurring, even though these levels are above the risk-based level for arsenic. Arsenic is a naturally occurring metal. The risk-based level for arsenic for exposure under a commercial/industrial scenario is 3.8 parts per million. The concentrations of arsenic detected in the sails at the Site range from 0.8 parts per million to 8.8 parts per million. These concentrations are within the range of naturally occurring arsenic associated with sails ofthe type found at the Site. 18. A commenter wanted to know if toluene, which was detected in earlier investigations at the Site, is currently a potential contaminant of concem. EPA did nat detect toluene above the MCL in groundwater, therefore, toluene was not included as a contaminant of concern. 19. One commenter asked about the effect of rain on benzene and xylene in the AST area, and a commenter wanted to know whether samples were taken during rainy and dry seasons. A four-phase investigation was completed at the Site, which included multiple groundwater sampling events during different seasons to characterize the effects ofthe annual precipitation cycle an Site groundwater elevations and contaminant concentrations. Enhanced vertical contaminant transport from the unsaturated zone to groundwater can occur during rain events. Likewise, recharge of rain water ta the aquifer can result in the dilution of contaminant concentrations in groundwater. Hence, bath cases cause groundwater contaminant concentrations to fluctuate over time. However, locations subjected to signiflcant impact by ethylbenzene and xylene within the aquifer would not loose detectable evidence of such impacts after each rain event, as these chemicals tend to adsorb to the soils and then leach off more slowly into the groundwater over time (i.e., tailing effect). 20. One commenter asked ifEPA had conducted fish tissue sampling. EPA did not detect elevated levels of contaminants in sediments in the most recent sampling event. Therefore, EPA did not conduct fish tissue sampling. C-5 500078 21. A commenter wanted to know what happened to the drums which were taken from the Site during previous removal activities conducted by EPA and Berlex. EPA and Berlex transported the drums off-Site ta a permitted hazardous waste disposal facility to the U.S. mainland for treatment and disposal. 22. The Committee on Planning & Environmental Protection (CPEP) ofthe 24* Legislature of the Virgin Islands would like to know how confident EPA is regarding its conclusion that chloroform or any other contaminant of concem does not appear to be migrating off-Site. The existing Site data from the Farmer Process Pit area indicate that off-Site groundwater quality, downgradient of this area, has nat been impacted by Site contaminants above MCLs. The most recent groundwater data further indicate that the current impact ta an- Site groundwater quality is localized to the immediate area ofthe Former Process Pit and is limited to low levels of chloroform that are generally at ar below the federal MCL for drinking water. The existing Site data from the Above-ground Storage Tank area indicate that the current impact to on-Site groundwater quality is localized to the general area between farmer tanks T-4 and T-12 and is limited to concentrations of ethylbenzene and xylene that exceed MCLs. The existing data further indicate that: 1) off-Site impact to groundwater quality above MCLs, downgradient of this area, is limited to within 50 feet ofthe west property line that abuts this area and 2) the contaminant plume exceeding MCLs is nat expanding. Based an all the data collected, EPA is confident that the contaminants of concerns are not migrating. Community Involvement in Superfund Process 23. Several commenters felt that EPA does not give the community adequate notice of opportunities for public participation, such as public hearings. They suggested that EPA run the same public notice in the newspaper over several days and that EPA use radio and television to a greater extent, particularly Spanish stations. EPA submitted a script in English ta various local radio stations to broadcast for several days prior ta the public meeting. EPA also has developed a mailing list of more than 100 people who attended the last public meeting (1995).. From that list, EPA mailed over 100 fliers about the public meeting during the couple of weeks preceding the public meeting. However, these materials were not translated into Spanish. EPA will consider Spanish translation in the future. 24. One commenter questioned whether the public comment period designated from June 27 to July 27,2001 was sufficient for the public to research and respond to the Proposed Plan. According to Superfund law, EPA must provide at least a 30-day public comment period, which was announced in the St. Croix Daily News and the St. Croix Avis on June 27, C-6 5 0 0 0 7 9 2001. In addition, an information repository has been maintained for the Site at the St. Croix Campus Library located in the University ofthe Virgin Islands. If the public submits a request for additional time, EPA will always grant an extension of time. A request for an extension was made and EPA agreed ta extend the public comment period far an additional 15 days during the public meeting. The public comment period closed on August 11,2001. 25. One commenter wanted to know if residents ofthe Profit and Bethlehem communities and inmates ofthe Golden Grove Correctional Facility were informed in advance of potential health consequences associated with airbome dust released during drum removal and soil excavation activities at the Site. Likewise, EPA should now notify nearby communities of upcoming remedial activities so that they can protect themselves from any potential contaminant releases. Based on the levels of chemicals detected in the soils, exposure ta airbome dust would nat have been a concem for downwind communities during the drum removal and sail excavation activities. Nevertheless, the public was notified of this removal by publication in the Daily News on January 15, 1990. EPA makes every effort ta inform the public before initiating an action through press releases, fact sheets and public meetings, to name a few. During the Removal Action, EPA also issued several press releases on the status ofthe removal action. EPA will continue to issue press releases during the remedial action. Further, any potential for releases will be controlled using appropriate health and safety procedures in accordance with an approved Health and Safety Plan which will be available ta the public. Length of EPA Investigation 26. Several commenters wanted to know why it took seven years for EPA to investigate the Site and then once the Site was placed on the National Priorities List, another seven years to get to this point. A farmer tenant. Island Chemical Company (acquired later by Berlex, one ofthe Potential Responsible Parties) performed a removal action in the early-1980s. Several investigations were conducted by EPA and the former tenant between 1984 and 1991, with an additional, more comprehensive removal action completed by EPA from 1989 to 1991 ta address the immediate threats ta human health and the environment at the Site. EPA entered into an Administrative Order on Consent with Berlex and Island Chemical Company in 1994 and subsequently added the Site to the NPL in 1996. The remedial investigation (RI) ofthe Site was completed in four phases from 1995 to 1998, which fully characterized the Site and addressed all potential human health and environmental concerns. The feasibility study (FS) was completed from 1999 to 2000, which included the performance of a comprehensive sail vapor extraction/air sparging (SVE/AS) pilot study C-1 500080 at the AST and FPP areas. TheRI and FS reports were finalized in 2001 following technical review and comment an the draft reports by EPA and DPNR. 27. One commenter asked if the "delay" had any affect on the contaminants that EPA initially found at the Site. For this particular Site, EPA has found that the concentration levels ofthe contaminants continue ta decrease aver time and predominantly remain limited to discrete areas within the Site boundary, despite the fact the initial releases likely occurred mare than 20 years ago. For example, groundwater sampling events from last year indicated that chloroform concentrations had decreased below the MCL. 28. CPEP is concemed about the length of time it took to characterize the nature and extent of contamination at the Site. The committee wanted to know whether any samples were collected to determine what contaminants were left at the Site and their corresponding concentrations after the 1989 removal action. CPEP notes that the Proposed Plan does not indicate whether the data used to characterize Site risks were collected recently or when concentrations were higher. CPEP believes that the length of time as well as the recency of the data used to drive the risk assessment may have significantly altered the risk characterization, as well as the selected preferred remedy. The Site conditions existing after the 1989-1991 removal action were characterized in the remedial investigation from 1994 to 1998. The risk assessment considered the Site data collected during the remedial investigation, as well as conservative exposure scenarios corresponding ta bath current and future land use. The remedial investigation report, which included the risk assessment, was reviewed and approved by EPA in consultation with DPNR. The cleanup goals far the Site soils and groundwater are based upon EPA's soil screening level methodology and federal MCLs for drinking water, respectively. Hence, the cleanup goals are independent ofthe contaminant concentrations detected at the Site during the remedial investigation. Potentially Responsible Parties 29. One commenter contacted the U.S. Attorney's Office to inquire about prosecution ofthe parties who are potentially responsible for the Site contamination. The caller was told that the statute of limitations had run out at the Site. She wanted to know why EPA had not informed the U.S. Attomey's OfiBce of potential criminal activity at the Site in a timely fashion. Several community members shared their view that the people ofthe Virgin Islands should be compensated for their loss of natural resources. EPA has na evidence at this time ta suggest that a criminal prosecution is warranted. EPA has worked closely with the Virgin Islands Department of Planning and Natural Resources (VIDPNR) ta keep the local agency informed about the Site. Two ofthe C-8 5 0 0 0 8 1 potentially responsible parties, Berlex and Pierrel S.p.A. (a subsidiary of Pharmacia), are taking an active rale in the Site cleanup. Natural Resources damages are the responsibility ofthe trustee agencies, which include The National Oceanic and Atmospheric Administration, Department of Interior and the Virgin Island Government. The Trustees have been actively involved with EPA's activities aver the last several years. 30. A commenter wanted to know why EPA waited until the year 2000 to erect a fence around the Site. This person also believes EPA should have posted warning signs at the Site to discourage individuals from consuming animals that graze on herbs or "bush tea" that grow in the area. The fence was installed by the PRPs after many failed attempts to have the property owner, CHS Holding Corporation, install it The PRPs requested the consent of CHS Holding Corporation to put up the fence, which taak some time to obtain. The fence was installed by the PRPs in 1999. Cleanup Goals of Selected Remedy 31. One resident questioned whether EPA could ever restore the Site property to its original state. EPA selects a remedy in accordance with the nine criteria outlined by the National Oil and Hazardous Substances Pollution Contingency Plan (NCP), including cost, implementability, and effectiveness. Superfund law requires EPA to clean up a Site to acceptable levels of risk, and cleanup goals are established based on the reasonably anticipated land use. The Virgin Island Chemical Site was an industrial property; EPA's cleanup will allow the property ta be used industrially. The groundwater at the Site will be remediated ta drinking water standards, which do nat distinguish between residential and nonresidential scenarios. 32. CPEP requested more information on the exact decision criteria (quantitative or qualitative) which will be used by EPA to determine whether to implement the contingency remedy, which consists of groundwater exfraction and freatment at locations where monitored natural attenuation is proposed under the Selected Remedy. The CPEP's concem surrounded the contingency remedy and the design ofthe fiiture groundwater monitoring program that could yield data necessary to trigger implementation ofthe contingency remedy. The CPEP indicated that is was currently unclear from the documentation provided whether the monitoring design will be statistically based and sufficiently protective to detect the criteria for determining whether the implementation of the plan is necessary to protect human health and environment. More specifically, the committee wanted to know what would be or is the acceptable decision error rate (i.e., .01, .05, 0.1 or greater) for failing to decide to implement the contingency remedy if the data indicates that it should be implemented. C-9 5 0 0 0 8 2 Current EPA Monitored Natural Attenuation (MNA) policy and protocol do not require that statistics be used to decide when a contingency remedy should be implemented, nor do they require that EPA specify an acceptable decision error rate. The decision ta implement the contingency remedy will be based upon: 1) evidence (i.e., definitive data from groundwater sampling) that the leading edge ofthe VOC plume exceeding MCLs is advancing ar 2) evidence (i.e., definitive data, statistical analysis, modeling) that the VOC plume is attenuating at rates that are significantly less than feasibility study predictions and that are clearly less than cleanup rates that could otherwise be achieved by the contingency remedy. For administrative purposes, the Site property boundary will be designated as the reference point, as it is generally the leading edge ofthe VOC plume exceeding MCLs. MW-11 and at least one other new monitoring well location approved by EPA immediately downgradient of the property boundary line will serve as sentinel, ar "trigger, " wells to test the first decision criterion. If the groundwater sample results from quarterly monitoring exceed MCLs, as detected in one round of sampling and confirmed by a subsequent verification round of sampling, at any sentinel well (i.e., ar any well downgradient thereof), then the contingency remedy will be implemented. The second decision criterion will be evaluated on a regular basis during preparation of quarterly remedial progress reports based upon the results of data evaluation/interpretation, statistical analysis, numerical modeling, and other standard methods/protocols described in the EPA MNA guidance and other directives. The public will be kept informed of its clean-up progress and would be advised of a decision to implement the contingency remedy. Other Superfund Sites in St Croix 33. One commenter wanted to know ifEPA currently has other Superfimd Sites in St. Croix. The Virgin Island Chemical Site is the only federal Superfund Site in St Croix listed on the NPL. EPA is aware of two other, the Hess and St Croix Alumina Sites, which are facilities handled under the Resource Conservation and Recovery Act (RCRA). Superfund generally focuses more on inactive, abandoned hazardous waste facilities. 34. The commenter also asked whether EPA would take confrol ofthese RCRA facilities if the facilities were to close down. EPA explained that oil and gasoline are generally not covered under Superfund, which is governed by the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), as amended. RCRA facilities contain treatment, storage and disposal units which, when they cease ta be used far that purpose, must be closed in accordance with certain RCRA requirements. Sa even though a RCRA facility may become inactive, it would nat necessarily became a Superfund Site. It is passible that an abandoned RCRA facility could be addressed by EPA or owner/operators under CERCLA. However, EPA C-10 500083 would only become involved with the facility if Superfund assistance was requested. Also, a hazardous waste Site must be added to the National Priorities List before EPA can use federal funds for long-term remedial action. C-11 500084 #1 LAGOON STREET COMPLEX FREDEUIKSIED, ST. C B O K . U.S.V.1. 00840 Caroline Kwan Remedial Project Manager United States Environmental Protection Agency 290 Broadway, 20"" Floor New York, NY 10007-1866 Dear Ms. Kwan: On behalf of Senator Alicia "Chucky" Hansen, I would like to submit the following comments regarding the EPA's proposed plan to clean up the Virgin Islands Chemical Superfimd site. Although the "EPA was notified in October of 1982 ofthe facility's impending closure and off-site removal of waste materials" and although "between 1984 and 1991 several investigations were conducted at the Site by EPA", it took until January 31 and February 1,1989 for the EPA to remove "400 drums (some exfremely deteriorated) leaking cylinders ofchlorine and hydrogen chloride, and over 800 containers of laboratory reagents that included sodium metal, potassium cyanide and ethyl ether". The EPA also removed "354 drums containing 14,720 gallons of various chemicals and 8,061 pounds of lab pack chemicals from the laboratory/warehouse building". It is deplorable that it took from 1982 until 1989, seven years, for the EPA to remove the drums. Furthermore, the EPA did not have the courtesy to inform or warn the adjacent prison known as Golden Grove Correctional Facility or the Profit and Bethlehem residential communities ofthe potential health consequences ofthe dust made airbome by the removal of the drums. The area ofthe facility was not even fenced until the year 2000, eighteen years after EPA was first notified ofthe facility's closure and sixteen years after the EPA first conducted its investigation. Up until the year 2000, sheep and goats would graze from the facilities' grounds and our St. Croix residents consumed those animals. I believe the EPA was too slow (sixteen years) in conducting its investigation and clean- up and that is unacceptable. I believe the EPA should have notified the prosecutorial agencies about the dumped hazardous waste materials. 500085 I believe the EPA should have immediately fenced the area and put warning signs of DO NOT ENTER so that unsuspecting individuals do not consume the animals that graze or the herbs or "bush tea" that grow in the area. I believe the EPA should have given better notice to the community and utilize the airwaves to give notice about the public meeting. I believe the EPA shoulti have notified the public regarding the airbome contaminants created by the previous soil excavation and should now notify the adjacent communities so that they can protect themselves from any potential contaminants produced by the remediation plan. I believe the people ofthe Virgin Islands should be compensated for their loss of natural resources. I believe a comprehensive health study should be made on the people ofthe Virgin Islands to determine whether or not the Island Chemical site has impacted on the community negatively. Cordially, Amelia B. Joseph, Esq. on behalf of Senator Alicia "Cbucky" Hansen 500086 500087 INMATE POPULATION GOL0EN GROVE ADULT CORRFrTrnNTAT PAI-TT rrv RURAL ROUTE #1 ^"RRECTIONAL FACILITY KINGSHILL ST. CROIX 00851 PETTTTON GREETINGS: WE THE UNDERSIGNED OF THE INMATE POPULATION HERE AT THE GOLDEN GROVE ADULT CORRECTIONAL FACILITY ARE ADDRESSING A PETITION DUE TO A CARCINOGENIC RISK OF TOXICITY OF GROUND CONTAMINATION THAT IS AFFECTING PRISONER HEALTH FOR THE LAST (2) TWO DECADES. THIS CONTAMINATION IS RESPONSIBLE FOR SKIN DISCOLORATION AND RASH, HAIR COLORATION, SEVERE LOST OF APPETITE, ULCERS OF THE STOMACH. KIDNEY DILAPIDATION DUE TO ADVERSE HEALTH EFFECTS ASSOCIATED WITH THE SOIL IRRIGATION OF THE WATER WE ACCOMODATE. IN REGARD TO THESE SYMPTOMS THAT IS DETERJOATING AND DIMINISHING OUR HEALTH DUE TO THE DISPOSITION WE AS INMATE HERE IN THIS INSTITUTION ARE UP AGAINST, WE STRONGLY FEEL THIS ADVERSE FORMALITY ACCOUNTS FOR THE CUMULATIVE RISK OF BEING EXPOSE TO THE CARCINOGENIC RISK OF CANCER IN THE NEAR FUTURE. WE THE UNDERSIGNED OF THE INMATE POPULATION PRAY FOR AN ADOVOCATE OF SUPPORT FROM ANY ENTITY, FEDERAL AGENCY, GOVERNMENTAL AGENCY AND ANY FORM OF RESOURCE THAT CAN ASSESS AN ALTRERNATIVE FOR AN EFFECTIVE REMEDY OF OUR CONCERNS WE ARE UP AGAINST. RESPECTFULLY SUMITTED ./?^2rf iuUx:USXAf\xj \X(\Mib I w w ^ Q g j ^ . 36.M^A'i;6 ba-n.yv/g^ ( . V " ^ Friday, August 10,2001 Caroline Kwan, Remedial Project Manager United States Environmental Protection Agency 290 Broadway, 20* Floor New York, NY 10007-1866 Dear Ms. Kwan, As Chairman ofthe Committee on Planning & Environmental Protection (CPEP) ofthe 24* Legislature of Virgin Islands, and on behalf of the people ofthe Territory, I am providing the following comments on the Proposed Plan for the Virgin Islands Chemical Superfund Site (the Site) dated June 2001.. My first concem surrounds the contingency remedy and the design ofthe future groundwater monitoring program that could yield data necessary to trigger implementation ofthe contingency remedy. It is currently unclear from the documentation provided whether the monitoring design will be statistically based and sufficiently protective to detect the criteria for determining whether the implementation ofthe plan is necessary to protect human health and environment. More specifically, what would be or is the acceptable decision error rate (i.e., .01,.05, 0.1 or greater) for failing to decide to implement the contingency remedy when in fact data indicates that it should be implemented. Furthermore, the six words ofthe fifth paragraph states "...data indicates that it is needed", however, while this implies that quantitative criteria has been developed or will be developed for taking action, it is unclear whether in fact these criteria are quantitative and if so, what are the decision criteria. Secondly, we are also concemed with the length of time it took to characterize the site and wonder whether any samples were collected to determine what contaminants were left at the site and their corresponding cpncenfrations after the removal action in January and February of 1989. This document also does not indicate whether the data used to characterize site risks were data collected recently or when concentrations were higher. The length of time involved as well as the balance of data used to drive the risk assessment (i.e., recent versus old) may have significantly altered the risk characterization, as well as the selected preferred remedy. Finally, on page six in the "Groundwater" section, what level of confidence is associated with the conclusion that chloroform does not appear to be migrating offsite and for that matter, any other contaminant of concem. 500088 We are pleased for the opportunity to provide some input on the proposed remedy and look forward to the issuance of a Record of Decision that, to the extent possible, takes all Virgin Islanders concems into serious consideration. Cordially, Donald "Ducks" Cole, Chairman Committee on Planning and Environmental Protection 24* Legislature ofthe Virgin Islands 500089 APPENDIX D ADMINISTRATIVE RECORD INDEX 500090 ISLAND CHEMICAL SITE ADMINISTRATIVE RECORD FILE INDEX OF DOCUMENTS 1.0 SITE IDEl^IFICATION 1.1 Background - RCRA and Other Infonnation P. 100001 - Report: RCRA Enforcement. Interim Report- No 100085 Analysis Data. Berlex Laboratories, St. Croix, VI. prepared by Ms. Carol Price, Environmental Scientist, Berlex Laboratories (ICC), prepared for U.S. EPA, March 13, 1986. P. 100086 - Letter to Mr. Charles Dolan, U.S. EPA, Emergency 100271 and Remedial Response Division, Region II, from Alan L. Klyes, Ph.D., Enviro-Sciences, Inc., re: Island Chemical Company, U.S. Virgin Islands, April 17, 1986. (Attachment: Project Summary (with Attachments A - N) for Island Chemical Company, Inc., (Berlex) St. Croix, Virgin Islands). 1.2 Notification/Site Inspection Reports P. 100272 - Report: Final Draft Site Inspection Report, VI 100572 Chemical, St. Croix, U.S. Virgin Islands, Volume 1 of 2, prepared by Halliburton NUS Environmental Corporation Superfund Division, prepared for Environmental Services Division, U.S. EPA, September 4, 1991. P. ,100573 - Report: Final Draft Site Inspection Report. VI 100847 Chemical, St. Croix, U.S. Virgin Islands, Volume 2 of 2. prepared by Halliburton NUS Environmental Corporation, prepared for Environmental Services Division, U.S. EPA, September 4, 1991. (NOTE: Pages 100835 through 100847 are CONFIDENTIAL. These pages can be located at the U.S. EPA, Superfund Records Center, 290 Broadway, 18th Floor, N.Y., N.Y., 10007-1866.) 500091 2.0 REMOVAL RESPONSE 2 .5 Action Memorandum P. 200001 - Memorandum to Mr. William J. Muszynski, P.E., 200042 Acting Regional Administrator, U.S. EPA, Region II, from Mr. Douglas R. Kodama, On-Scene Coordinator, Response and Prevention Branch, U.S. EPA, Region II, re: Preliminary Assessment, Removal Site Evaluation, and Funding Authorization Request for a CERCLA Removal Action at the Virgin Island Chemical Company, Inc..Site, St. Croix, U.S. Virgin Islands, Action Memorandum, August 8, 1989. 3.0 REMEDIAL INVESTIGATION 3.2 Sampling and Analysis Data/Chain of Custody Forms P. 3 00001 - Letter to Ms. Sherrel Henry, Remedial Project 300124 Manager, U.S. EPA, Region II, from Mr. Jason M. Schindler, Associate Geologist, Harding Lawson Associates, re: Non-CLP Results of Potable Water Sampling, Island Chemical Company, St. Croix, U.S. Virgin Islands, January 3, 1995. (Attachment: Non-CLP laboratory data package. Report of Laboratory Analysis, prepared by Pace Inc., Environmental Laboratories). P. 300125 - Memorandum to Mr. Jason Schindler, Harding Lawson 300227 Associates (HLA), Philadelphia, from Mr. Mike Phillips, HLA, Denver, re: Island Chemical Company Data Review, January 10, 1995. (Attachment: 1. HLA Data Quality Assurance Review Summary, Volatile Organic Compounds Analysis, Case Number: 94195, Project Number: 29872 10-wl, Island Chemical Company, reviewed January 3, 1995; 2. HLA Data Quality Assurance Review Summary, Semivolatile Organic Compounds Analysis, Case Number: 94195, Project Number: 29872 10.1, Island Chemical Company, reviewed January 4, 1995; 3. HLA Data Quality Assurance Review Summary, Metals Analysis, Case Number: 94195, Project Number: 29872 10.1, Island Chemical Company, reviewed January 5, 1995; 4. HLA Data Quality Assurance 500092 Review Summary, Semivolatile Organic Compounds Analysis, Case Number: 94195, Project Number: 29872 10.1, Island Chemical Company, reviewed January 5, 1995; 5. HLA Data Quality Assurance Review Summary, Organochlorine Pesticides and Polychhlorinated Biphenyls Analysis, Case Number: 94195, Project Number 29872 10.1, Island Chemical Company, reviewed January 5, 1995; and 6. HLA Data Quality Assurance Review Summary, Semi- volatile Organic Compounds Analysis, Case Number: 94195, Project Number: 29872 10.1, Island Chemical Company, reviewed January 9, 1995). P. 300228 - Letter to Mr. Jonathan Rude, U.S. EPA Contract 300228 Laboratory Program, from Ms. Pamela J. Philip, Work Assignment Manager, CDM Federal Programs Corporation, re: Completed CLP Paperwork for Case Number 23153, February 9, 1995. P. 300229 - Letter to Ms. Sherrel D. Taylor-Domville, U.S. 300233 EPA, Region II, from Mr. Bharat Patel, C.P.G., Associate Hydrogeologist, and Mr. Jason M. Schindler, Associate Geologist, Harding Lawson Associates, re: Results of February 14 and 15, 1995 Quality Assurance Field Audit, Island Chemical Company Site, Remedial Investigation, St. Croix, U.S. Virgin Islands, March 1, 1995. P. 300234 - Table 4-2 (Draft): Soil Sample Analytical Results 300241 - Volatile Organic Compounds, Virgin Island Chemical Company, January 31, 1995. (Attachment: Table 4-8 (Draft): Groundwater Sample Analytical Results - Volatile Organic Compounds, Virgin Island Chemical Company, May 11, 1995. P. 300242 - Letter to Ms. Kathy Kinsella, RSCC, Lockheed, from 300253 Ms. Pamela Philip, Work Assignment Manager, CDM Federal Programs Corporation, re: Completed CLP Paperwork and Sampling Trip Report for Case Number 23237, February 28, 1995. (Attachment: Report: Sampling Trip Report. Virgin Islands Chemical Site. St. Croix. U.S. Virgin Islands, prepared by CDM Federal Programs Corporation, prepared for U.S. EPA, Region II, February 28, 1995) . 500093 3 00254 - Letter to Mr. Jonathan Rude, U.S. EPA, Contract 300256 Laboratory Program, from Ms. Pamela Philip, Work Assignment Manager, CDM Federal Program Corporation, re: Completed CLP Paperwork for Case Number 23237, February 28, 1995. (Attachment: U.S. EPA, Inorganic Traffic Report & Chain of Custody Report (for Inorganic CLP Analysis), February 15, 1995). 300257 - Letter to Ms. Sherrel Taylor-Domville, U.S. EPA, 300688 Region II, Emergency and Remedial Response Division (ERRD), from Mr. Jason Schindler, Associate Geologist, Harding Lawson Associates, re: Results of Soil and Initial Groundwater Sampling, Island Chemical Company, St. Croix, U.S. Virgin Islands, April 7, 1995. (Attachment: 1. Letter to Mr. Steve Bruckner, Harding Lawson & Associates, from Ms. Elaine Wild, QA Officer, Pace Inc. Environmental Laboratories, re: the attached pyridine analysis supporting raw data for Report Groups #95010, 95020 and 95022, April 5, 1995; 2. Raw pyridine data for Report Groups #95010, 95020, 95022. 300689 - Data Package: Harding Lawson & Associates (HLA) 300851 Data Quality Assurance Review Suitmiary, Semi- volatile Organic Compound Analysis, April 12, 1995. 3 00852 - Letter to Ms. Sherrel D. Taylor-Domville, U.S. 300854 EPA, Region II, from Mr. Matthew Gordan, for Mr. Bharat Patel, C.P.G., Managing Associate Hydrogeologist, and Mr. Jason M. Schindler, Associate Geologist, Harding Lawson Associates, re: Results of Second Quality Assurance Field Audit, Island Chemical Company Site, Remedial Investigation, St. Croix, U.S. Virgin Islands, June 7, 1995. - 300855 - Letter to Ms. Sherrel Henry, Work Assignment 300858 Manager, U.S. EPA, Region II, from Ms. Pamela Philip, Work Assignment Manager, CDM Federal Programs Corporation, re: Draft Assessment of PRP Data Validation Activities, Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, July 14, 1995. (Attachment Report: Draft Data Assessment of PRP Data Validation Activities, Virgin Island 500094 chemical Site, St. Crcix, U.S. Virgin Islands, prepared by CDM Federal Programs Corporation). 300859 - Letter to Ms. Sherrel Henry, U.S. EPA, Region II, 300861 from Mr. John S. Virgie, P.G., Senior Geologist, and Mr. Edward A. Nemecek, R.G,, C.P.G., Principal Hydrogeologist, Harding Lawson Associates, re: Soil Sampling Program - AST Area, Phase II Remedial Investigation, Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, June 28, 1996. (Attachment: Figure 1, Surface Soil Sample, Soil Boring Locations, AST Area, Island Chemical Co., St. Croix, U.S. Virgin Islands, prepared by Harding Lawson Associates, June 14, 1996), 300862 - Letter to Ms. Caroline Kwan, Remedial Project 300936 Manager, U.S. EPA, Region II, from Mr. Perry Katz, Principal Environmental Scientist, McLaren Hart, Inc., re: VICHEM Site, St. Croix, U.S. Virgin Islands, November 1997 Monthly Progress Report, December 15, 1997. (Attachments: (1) Report: Attachment, November 1997 Monthly Progress Report, List of Tables; (2) Table 1, Virgin Island Chemical Site, Soil Boring Sampling Results, Volatile Organic Compounds; (3) Table 2, Virgin Island Chemical Site, Soil Boring Sampling Results, Semivolatile Organic Compounds; (4) Table 3, Virgin Island Chemical Site, Soil Boring Sampling Results, Metals; (5) Table 4, Virgin Island Chemical Site, Gut and Storm Drain Surface Soil Sampling Results, Semivolatile Organic Compounds; (6) Table 5, Virgin Island Chemical Site, Gut and Storm Drain Surface Soil Sampling Results, Metals; (7) Table 6, Virgin Island Chemical Site, Gut and Storm Drain Surface Soil Sampling Results, Physicochemical Parameters; (8) .Table 7, Virgin Island Chemical Site, (Jut and Storm Drain Surface Soil Sampling Results, Grain Size Analysis; (9) Table 8, Virgin Island Chemical Site, Fairplain Gut/Manning Bay Sediment Sampling Results, Semivolatile Organic Compounds; (10) Table 9, Virgin Island Chemical Site, Fairplain Gut/Manning Bay Sediment Sampling Results, Metals; (11) Table 10, Virgin Island Chemical Site, Fairplain Gut/Manning Bay Sediment Sampling . . Results, Physicochemical Parameters; (12) Table 500095 11, Virgin Island Chemical Site, Fairplain Gut/Manning Bay Sediment Sampling Results, Grain Size Analysis; (13) Table 12, Virgin Island Chemical Site, Soil Boring Sampling Results, Biological Parameters; (14) Table 13, Virgin Island Chemical Site, Soil Boring Sampling Results, Physicochemical Parameters; (15) Table 14, Virgin Island Chemical Site, Preliminary Soil Boring Sampling Results, Process Pit Area, Volatile Organic Compounds and (16) Table 15, Virgin Island Chemical Site, Preliminary Soil Boring Sampling Results, Lab Pit Area, Volatile Organic Compounds. 3.3 Work Plan P. 300937 - Report: Island Chemical Company, Inc., Remedial 301284 Investigation St. Croix, U.S. Virgin Islands, Draft Work Plan. Volume I of II, Work Plan and Appendices A through C. prepared by Harding Lawson Associates, prepared for Island Chemical Company, Inc., March 17, 1994. P. 301285 - Report: Island Chemical Company. Inc., Remedial 301764 Investigation St. Croix, U.S. Virgin Islands, Draft Work Plan, Volume II of II, Work Plan and Appendices D through O. prepared by Harding Lawson Associates, prepared for Island Chemical Company, Inc., March 17, 1994. P. 301765 - Report: Draft Remedial Investigation Work Plan. 302136 Island Chemical Company, Inc., St. Croix. U.S. Virgin Islands, prepared by Harding Lawson Associates, prepared for Island Chemical Company, Inc., August 5, 1994. P. 302137 - Letter to Ms. Sherrel Henry, U.S. EPA, Region II, 302141 from Mr. Edward A. Nemecek, R.G., C.P.G., Principal Hydrogeologist, Harding Lawson Associates, re: Revised Draft Remedial Investigation Work Plan Schedule, Island Chemical Company, Inc., St. Croix, U.S. Virgin Islands, September 14, 1994. (Attachments: (1) Distribution List, Island Chemical Company, Inc., St. Croix, U.S. Virgin Islands, September 19, 1994; (2) Outline for Island Chemical Company 500096 Inc. Remedial Investigation Report, September 19, 1994; (3) Figure 8-1: Work Plan Implementation Schedule, Island Chemical Company, St. Croix, U.S. Virgin Islands, September 19, 1994). P. 302142 - Letter to Ms. Sherrel Taylor-Domville, U.S. EPA, 302160 Region II, Emergency and Remedial Response Division, U.S. EPA, Region II, from Mr. Jason M. Schindler, P.G,, Associate Geologist, Harding Lawson Associates, re: Draft Phase II Work Plan, Remedial Investigation, VICHEM Site, St. Croix, U.S. Virgin Islands, November 21, 1995. (Attachment: Report: Draft Phase II Remedial Investigation Work Plan, Virgin Island Chemical Site, Remedial Investigation, St. Croix. U.S. Virgin Islands, prepared by Harding Lawson Associates, Engineering and Environmental Services, prepared for Island Chemical Company, November 21, 1995). P. 302161 - Letter to Ms. Caroline Kwan, Remedial Project 302188 Manager, U.S. EPA, Region II, from Ms. Lori G. Singer, Sills Cummis Zuckerman Radin Tischman Epstein & Gross, re: Vichem Site/St. Croix, Virgin Islands, November 6, 1996. (Attachments: (1) Letter to Wilfredo Geigel, Esq., from Ms. Lori G. Singer, Sills Cummis Zuckerman Radin Tischman Epstein & Gross, re: CHS Holding Co., Inc., October 14, 1996; (2) Letter to Lori Singer, Esq., Sills Cummis Zuckerman Radin Tischman Epstein & Gross, from Wilfredo A. Geigel, Esq., re: Berlex V. CHS, October 17, 1996; (3) Report: Draft Remedial Investigation Work Plan Addendum - Phase III. Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, prepared by Harding Lawson Associates, Engineering and Environmental Services, prepared for Island Chemical Company, November 7, 1996). P. 302189 - Report: Draft Remedial Investigation Work Plan 302231 Addendum - Phase III, Virgin Island Chemical Site. St. Croix, U.S. Virgin Islands, prepared by Harding Lawson Associates, Engineering and Environmental Services, prepared for Island Chemical Company, January 20, 1997. 500097 F. 302232 - Memorandum to Ms. Caroline Kwan, Remedial Project 302291 Manager, U.S. EPA, Region II, from Mr. John S. Virgie, Senior Geologist, Harding Lawson Associates, Engineering and Environmental Services and Mr. Edward A. Nemecek, Principal Hydrogeologist, Regional Geosciences Manager, Harding Lawson Associates, Engineering and Environmental Services, re: Draft Remedial Investigation Work Plan Addendum - Phase III, Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, June 20, 1997•(Attachment: Report: Draft Remedial Investigation Work Plan Addendum - Phase III. Virgin Island Chemical Site, St. Croix. U.S. Virgin Islands, prepared by Harding Lawson Associates, Engineering and Environmental Services, prepared for Island Chemical Company, June 20, 1997). P. 302292 - Memorandum to Ms. Caroline Kwan, Remedial Project 302355 Manager, U.S. EPA, Region II, from Mr. John S. Virgie, Senior Geologist, Harding Lawson Associates, Engineering and Environmental Services, re: Revised Draft Remedial Investigation Work Plan - Phase III, Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, July 25, 1997. (Attachment: Report: Draft Remedial Investigation Work Plan Addendum - Phase III. Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, prepared by Harding Lawson Associates, Engineering and Environmental Services, prepared for Island Chemical Company, July 25, 1997). P. 302355A - Letter to Ms. Caroline Kwan, U.S. EPA, Region II, 3023550 from Mr. Perry Katz, Principal Environmental Scientist and Ms. Norma Eichlin, Senior Engineer, McLaren Hart, Inc., re: Island Chemical Site, St. Croix, U. S. Virgin Islands, Supplemental Remedial Investigation (Phase IV RI), August 12, 1998. P. 302355P - Letter to Ms.Caroline Kwan, U.S. EPA, Region II, 302355Q from Mr. Perry Katz, Principal Environmental Scientist and Ms. Norma Eichlin, Senior Engineer, McLaren Hart, Inc., re: Island Chemical Site, St. Croix, U. S. Virgin Islands, Clarifications to Supplemental Remedial Investigation dated August 12, 1998, August 24, 1996. r '"' 8 500098 3 02355R- Letter to Ms. Caro]ine Kwan, Remedial Project 302355DD Manager, U.S. EPA, Region II, from Mr. Perry Katz, Principal Environmental Scientist and Ms. Norma Eichlin, Senior Engineer, McLaren Hart, Inc., re: Island Chemical Site, St. Croix, U.S. Virgin Islands, Field Modifications During Supplemental Remedial Investigation (Phase IV RI) , November 20, 1998. (NOTE; Pages 302355AA through 302355DD are . CONFIDENTIAL. These pages can be located at the U.S. EPA, Superfund Records Center, 290 Broadway, IS"* Floor, N.Y., N.Y., 10007-1866.) 3.4 Remedial Investigation Reports P. 302356 - Report: Compendium of Well Water Data Collected at 302357 the Virgin Island Chemical Co. bv the U.S. EPA (1986 - 1990)• undated.• P. 302358 - Report: Draft Technical Memorandum Pathways 302367 Analysis Report and Phase I Baseline Risk Assessment Summary, Virgin Island Chemical Site. St. Croix, U.S. Virgin Islands, prepared by Harding Lawson Associates, prepared for Island Chemical Company, Inc., August 14, 1995. 302368 - Letter to Ms. Sherrel D. Taylor-Domville, U.S. 302368 EPA, Region II, from Mr. Jason M, Schindler, Associate Geologist, and Mr. Edward A. Nemecek, R.G., C.P.G., Principal Hydrogeologist, Harding Lawson Associates, re: Draft Data Summary Report, Remedial Investigation, Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, August-15, 1995. 302369 - Report: Draft Data Summary Report, Virgin Island 302886 Chemical Site, St. Croix, U.S. Virgin Islands. U.S. EPA Index No. II CERCLA-94-04 01. Volume I of II. prepared by Harding Lawson Associates, prepared for Island Chemical Company, August 15, 1995. 302887 - Report: Draft Data Summary Report, Virgin Island 303349 Chemical Site. St. Croix, U.S. Virgin Islands. U.S. EPA Index No. II CERCLA-94-0401. Volume II of 500099 II. prepared by Harding Lawson Associates, prepared for Island Chemical Company, August 15, 1995. 303350 - Letter to Ms. Alison Devine, U.S. EPA, Region II, 303358 from Mr. Robert D. Goltz, P.E., ARCS II Program Manager, CDM Federal Programs Corporation, re: Technical Review of Draft Supplemental Data Summary Report, Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, October 8, 1996. (Attachment: Report: Technical Review of the Draft Supplemental Data Summary Report, Virgin Island Chemical Site, prepared by CDM Federal Programs Corporation, prepared for U.S. EPA, Region II, October 8, 1996). 303359 - Report: Revised Final Remedial Investigation 303676 Report, Volume 1 and Remedial Investigation Addendum. Virgin Island Chemical Site, St. Croix. U. S. Virgin Islands, prepared by Golder Associates Inc., prepared for Berlex Laboratories, Inc. and Pharmacia & Upjohn, October 2000. 303677 - Report: Final Remedial Investigation Report. 304262 Virgin Island Chemical Site, St. Croix, Virgin Islands. Volume II, Appendices A-G, I-K. prepared by McLaren/Hart, Inc., prepared for Berlex Laboratories, Inc. and Pharmacia & Upjohn, February 2000. 304263 - Report: Final Remedial Investigation Report. 304841 Virgin Island Chemical Site, St. Croix, Virgin Islands, Volume III, Appendix H, prepared by McLaren/Hart, Inc., prepared for Berlex Laboratories, Inc. and Pharmacia & Upjohn, February 2000. 304 842 - Report: Draft Soil Vapor Extraction/Air Sparging 305249 (SVE/AS) Pilot Study Report. Virgin Island Chemical Site. St. Croix. U. S. Virgin Islands. prepared by Golder Associates Inc., prepared for Berlex Laboratories, Inc. and Pharmacia & Upjohn, October 2000. ^° 500100 3.5 Correspondence P. 3 05250 - Letter to Mr. Edward A. Nemecek, Principal 3 05254 Hydrogeologist, from Ms. Carole Petersen, Chief, New York/Caribbean Superfund Branch II, U.S. EPA, Region II, re: Comments on the Draft Phase II Remedial Investigation Work Plan, Island Chemical Site, St. Croix, U.S. Virgin Islands, undated. P. 305255 - Letter to Mr. James Oland, Supervisor, Caribbean 305255 Field Office, U.S. Fish and Wildlife Service, from Mr. Robert Hargrove, Chief, Environmental Impacts Branch, U.S. EPA, re: initiating consultation with the U.S. Fish and Wildlife Service to determine whether there are any federal endangered/ threatened Species or critical habitats present on or in the vicinity of the Island Chemical Company National Priorities List site, located in the Christiansted Jurisdiction, St. Croix, U.S. Virgin Islands, June 30, 1995. P. 305256 - Letter to Ms. Sherrel Henry, Remedial Project 305259 Manager, U.S. EPA, Region II, from Ms. Diane Wehner, NOAA Coastal Resource Coordinator, U.S. Dept. Of Commerce, re: review of Draft Data Summary Report for the Virgin Island Chemical Site, September 7, 1995. P. 305260 - Memorandum to Ms, Sherrel D. Henry, Remedial 305261 Project Manager, U.S. EPA, Region II, from Ms. Shari Stevens, Environmental Scientist, U.S. EPA, Region II, re: Technical Review of the Draft Data Summary Report for the Virgin Island Chemical Site, September 8, 1995. P. 305262 - Letter to Ms. Sherrel Henry, Work Assignment 305268 Manager, U.S. EPA, Region II, re: Technical Review of PRP Data Summary Report for the Virgin Island Chemical Site, September 18, 1995. P. 305269 - Letter to Ms. Sherrel Taylor-Domville, U.S. EPA, 305270 Region II, from Mr. Jason M. Schindler, P.G., Associate Geologist, and Mr. Edward A. Nemecek, R.G., C.P.G., Regional Geosciences Manager, Harding Lawson Associates, re: Supplemental Work . . Plan, Remedial Investigation, Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, October 20, 1995. 500101 500102 F. 305271 - Letter to Ms. Alison Devine, U.S. EPA, Region II, 305277 from Mr. Robert D. Goltz, P.E., ARCS II Program Manager, CDM Federal Programs Corporation, re: Technical Review of Draft Phase II Work Plan, Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, December 11, 1995. (Attachment: Report: Technical Review of the Draft Phase II Work Plan. Virgin Island Chemical Site. St. Croix, U.S. Virgin Islands, prepared by CDM Federal Programs Corporation; prepared for, U.S. EPA, Region II, December 11, 1995. P. 305278 - Letter to Ms, Sherrel Henry, Remedial Project 305281 Manager, U.S. EPA, Region II, from Ms. Diane E. Wehner, NOAA Coastal Resource Coordinator, U.S. Dept. of Commerce, re: review of the Draft Phase II Remedial Investigation (RI) Work Plan for the Island Chemical Company, Inc. Site, December 14, 1995. (Attachments: 1. Site Location Map, and 2. Figure 13 - Gut Soil Sampling Program). P. 305282 - Letter to Mr. Edward A. Nemecek, Principal 305286 Hydrogeologist Co., from Ms. Carole Petersen, Chief, N.Y./Caribbean Superfund Branch II, U.S. EPA, Region II, re: Comments on the Draft Phase II Remedial Investigation Work Plan, Island Chemical Site, St. Croix, U.S. Virgin Islands, January 31, 1996, P. 305287 - Letter to Ms. Sherrel Taylor-Domville, U.S. EPA, 305303 Region II, from Mr. Jason M. Schindler, P.G., Associate Geologist, and Mr. Edward A. Nemecek, R.G., Principal Hydrogeologist, Harding Lawson Associates, re: Response to Comments, Draft Phase II Remedial Investigation Work Plan, Island Chemical Company, St. Croix, U.S. Virgin Islands, February 23, 1996. (Attachments: (1) Letter to Carol Berns, Esq., U.S. EPA, Region II,. from Lori G. Singer, Esq., Sills, Cummis, Zuckerman, Radin, Tischman, Epstein, & Gross, re: Plot Q of Estate Bethlehem Middle Works off of Melvin Evans Highway (Route 66) in St. Croix, U.S. Virgin Islands (Vichem Site), Supplemental Work Plan Issues, December 11, 1995; (2) Letter to Docket Coordinator, Headquarters, U.S. EPA, CERCLA Docket Office, from Lori G. Singer, Esq., Sills, Cummis, Zuckerman, Radin, Tischman, Epstein, & Gross, re: NPL, Proposed Rule No. 16, Tuesday, January 18, 1994 ("Proposed Rule"), Island Chemical Corp./Virgin Islands Chemical Corp., St. Croix, Virgin Islands, March 21, 1994; (3) Letter to 500103 Docket Coordinator, Headquarters, U.S. EPA, CERCLA Docket Office, from Teri L. Copeland, M.S., Principal Toxicoiogist, Harding Lawson Associates, re: NPL, Proposed Rule No. 16, 11894 Island Chemical Corp./Virgin Islands Chemical Corp., St. Croix, Virgin Islands, March 21, 1994). P. 3 05304 - Letter to Ms. Sherrel Taylor-Domville, U.S. EPA, 305305 Region II, from Mr. Jason M. Schindler, P.G., Associate Geologist, and Mr, Edward A. Nemecek, R,G., C.P.G., Principal Hydrogeologist, Regional Geosciences Manager, Harding Lawson Associates, re: Proposed Site Activities, Phase II Remedial Investigation Work Plan, Island Chemical Company, St. Croix, U.S. Virgin Islands, April 12, 1996. P. 305306 - Letter to Mr. Jason Schindler, P.G,, Associate 305306 Geologist, Harding Lawson Associates, from Ms. Sherrel D. Henry, Project Manager, U. S. EPA, Region II, re: Proposed Site Activities Phase II Remedial Investigation Work Plan, Island Chemical Site, St. Croix, U.S. Virgin Islands, April 17, 1996. P. 305307 - Letter to Mr. Jason Schindler, P.G., Associate 305307 . Geologist, Harding Lawson Associates, from Ms. Sherrel D; Heniry, Project Manager, U. S, EPA, Region II, re: Proposed Site Activities Phase II Remedial Investigation Work Plan, Island Chemical Site, St. Croix, U.S. Virgin Islands, April 18, 1996. P. 305308 - Letter to Mr. Jason Schindler, P.G., Associate 305309 Geologist, Harding Lawson Associates, re: Comments on Proposed Site Activities, Phase II Remedial Investigation Work Plan, Island Chemical Site, St. Croix, U.S. Virgin Islands, May 2, 1996. P. 305310 - Letter to Ms. Sherrel D. Henry, U.S. EPA, Region 305312 II, from Mr. John S. Virgie, P.G., Senior Geologist, and Mr. Edward A. Nemecek, R.G., C.P.G., Principal Hydrogeologist, Regional Geosciences Manager, Harding Lawson Associates, re: Additional Requested Information, Prop>osed Site Activities, Phase II Remedial Investigation Work Plan, Island Chemical Company, St. Croix, U.S. Virgin Islands, May 15, 1996. (Attachment: Figure 1, Proposed Surface Soil and Soil Boring Locations, Island Chemical Company, St. Croix, U.S. Virgin Islands, prepared by Harding Lawson Associates, May 14, 199€), 500104 P, 305313 - Letter to Mr. Austin Moorehead, Director, Division 305313 of Environmental Protection, Department of Planning and Natural Resources, Government of the Virgin Islands of the United States, from Ms. Sherrel D. Henry, Remedial Project Manager, U.S. EPA, Region II, re: request to discuss the status of the Site, May 16, 1996. P. 305314 - Letter to Lori G. Singer, Esq., Sills Cummis 3 05314 Zuckerman Radin Tischman Epstein & Gross, from Mr. Melvin Hauptman, Leader, Sediments/Caribbean Team, Emergency Remedial and Response Division, re: Approval of McLaren/Hart Inc. for Implementation of the RI/FS at the Island Chemical Site, St. Croix, USVI, August 8, 1997. P. 3 05315 - Memorandum to Ms. Caroline Kwan, Remedial Project 305315 Manager, Sediments/Caribbean Team, from Ms. Grace Musumeci, Chief, Environmental Review Section, re: Virgin Islands Chemical Site, St. Croix, USVI, Compliance with the National Historic Preservation Act, March 31, 1999. P. 305316 - Letter to Ms. Caroline Kwan, Remedial Project 305317 Manager, U.S. EPA, Region. II, from Mr. Perry Katz, Principal Environmental Scientist, McLaren Hart, Inc., re: Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, Schedule for Installation of Site Fence, January 26, 2000, P. 305318 - Letter to Mr. Perry Katz, Principal Environmental 305319 Scientist, McLaren Hart, Inc., from Ms. Caroline Kwan, Project Manager, Sediments/Caribbean Team, U.S. EPA, Region II, re: Virgin Island Chemical Site, St. Croix, United States Virgin Islands, January 27, 2000. P. 305320 - Report: Weekly Progress Report - 2/15/00 Through 305320 2/21/00, Implementation of Pilot-Scale Study. Virgin Island Chemical Site. St. Croix, U.S. Virgin Islands, facsimile date February 24, 2000. P. 305321 - Letter (w/attachments) to Ms. Caroline Kwan, 305330 Remedial Project Manager, U.S. EPA, Region II, from Mr. Perry Katz, Managing Environmental Scientist and'Ms. Norma Eichlin, Supervising Engineer, McLaren Hart, Inc., re: Virgin Island Chemical Site, St. Croix, U.S. Virgin Islands, 500105 Revisions to Calculation of Site-Specific Dilution Attenuation Factor, May 16, 2000. P. 305331 - Letter (w/attachments) to Ms. Caroline Kwan, 305345 Remedial Project Manager, U. S. EPA, Region II, from Mr. Terry E. Grimmer, M. S., R. E. A., Head of Environmental Health & Safety, Berlex Laboratories, Inc., and Mr. William G. Gierke, P. G., Corporate E&S, Environmental Remediation, Pharmacia & Upjohn, re: Notification - Replacement of Prime Contractor/Consultant, Virgin Island Chemical Site, Remedial Investigation/Feasibility Study (RI/FS), July 12, 2000. 4.0 FEASIBILITY STXJDY 4.3 Feasibility Study Reports P. 400001 - Report: Feasibility Study Report, Virgin Island 400170 Chemical Site. St. Croix, U. S. Virgin Islands, prepared by Golder Associates Inc., prepared for Berlex Laboratories, Inc. and Pharmacia & Upjohn, June 2 001, 4.4 Proposed Plans (SOP, FOP) P. 400171 - Report: Superfund Proposed Plan, Virgin Island 400182 Chemical Site, St. Croix, U. S. Virgin Islands, prepared by U.S. EPA, Region II, June 2001. 4.6 Correspondence P. 4 00183 - Letter to Mr. Perry Katz, Project Manager, McLaren 400190 Hart, from Ms. Caroline Kwan, Project Manager, Sediments/Caribbean Team, U.S. EPA, Region II, re: Comments of the Feasibility Study Technjical Memo and Draft Treatability Study Work Plan for the VI Chemical Site, St. Croix, USVI, April 22, 1999. 7.0 ENFORCEMENT 7.3 Administrative Orders P, 700001 - Letter to Lori Singer, Esq., Sills, 700037 Cummis, Zuckerman, Radin, Tischman, Epstein, & Gross, from Mr. Paul Simon, Section Chief, V*! N,Y,/Caribbean Superfund Branch, ORC, U.S. EPA, Region II, re: Virgin Island Chemical Site; I 500106 Administrative Order on Consent, Index No, II CERCLA-94-0401, October 3, 1994, (Attachment: Administrative Order on Consent for Remedial Investigation/Feasibility Study, Island Chemical Co., Inc. And Berlex Laboratories, Inc., Respondents, Index No. II CERCLA-94-0401, September 29, 1994). P. 700038 - Letter to Mr. William Whitlock, Esq., Pharmacia & 700039 Upjohn Co., from Ms. Jeanne M. Fox, Regional Administrator, U.S. EPA, Region II, re: Virgin Island Chemical Superfund Site, Administrative Order on Consent for Remedial Investigation/Feasibility Study, Index No. II, CERCLA-94-04 01, April 14, 1999. 9.0 NATURAL RESOURCE TRUSTEES 9.4 Correspondence P. 900001 - Letter to Mr. Robert Witte, U.S. EPA, Region II, 900002 from Mr. Roy E. Adams, Commissioner/SHPO, Government of the Virgin Islands of the United States, Department of Planning and Natural Resources, re: Request for Review of Proposed "Remedial Work" at the Island Chemical Site in St. Croix, USVI, May 20, 1994. 10.0 PUBLIC PARTICIPATION 10.1 Comments and Responses P. 10.0001 - Mailing List form requesting additional 10.0001 information on the Virgin Island Chemical site, completed by Mr, Keruaeth C, Haines, President, Coastal Consultants, March 27, 1995, 10.2 Community Relations Plans P, 10.0002 - Letter to Mr. Eustace Carr, from Ms. Sherrel 10.0002 Henry, Remedial Project Manager, U.S. EPA, Region II, re: Community Relations Activities at the Virgin Island Chemical Site, February 1, 1995. P, 10.0003 - Letter to Ms. Jennifer Jackson, The University of 10.0003 the Virgin Islands, St, Croix Campus, from Ms. Sherrel Henry, Remedial Project Manager, U.S, EPA, Region II, re: Community Relations Activities at the Virgin Island Chemical Site, February 1, 1995. 500107 P. 10.0004 - Letter to Mr. Jeff Lawlor, Virgin Islands Port 10.0004 Authority, from Ms. Sherrel Henry, Remedial Project Manager, U.S. EPA, Region II, re: Community Relations Activities at the Virgin Island Chemical Site, February 1, 1995. P. 10.0005 - Letter to Mr. Robert E. Simmons, Postmaster, from 10.0005 Ms. Sherrel Henry, Remedial Project Manager, U.S. EPA, Region II, re: Community Relations Activities at the Virgin Island Chemical Site, February 1, 1995. P. 10.0006 - Letter to Mr. Luis Cora, Comptroller, Virgin 10.0006 Islands Paving, Inc., from Ms. Sherrel Henry, Remedial Project Manager, U.S. EPA, Region II, re: Community Relations, Activities at the Virgin Island Chemical Site, February 1, 1995. P. 10.0007 - Letter to Ms. Natalie B. Stevens, Assistant 10.0007 Manager, Charlie's Concrete Services, from Ms. Sherrel Henry, Remedial Project Manager, U.S. EPA, Region II, re: Community Relations Activities at the Virgin Island Chemical Site, February 1, 1995. P. 10.0008 - Letter to Ms. Antoinette King, King's Automotive, 10.0008 from Ms. Sherrel Henry, Remedial Project Manager, U.S. EPA, Region II, re: Community Relations Activities at the Virgin Island Chemical Site, February 1, 1995, P. 10.0009 - Letter to Mr. Joe C. Pitts, Vice President t 10.0009 General Manager, VIAPCO, from Ms. Sherrel Henry, Remedial Project Manager, U.S. EPA, Region II, re: Community Relations Activities at the Virgin Island Chemical Site, February 1, 1995, P. 10.0010 - Letter to Ms. Karen V. Chapman, Administrative 10.0010 Specialist, University of the Virgin Islands, from Ms. Sherrel Henry, Remedial Project Manager, U.S. EPA, Region II, re: Community Relations Activities at the Virgin Island Chemical Site, February 1, 1995. P. 10.0011 - Letter to Ms. Sherrel Henry, Remedial Project 10.0020 Manager, U.S. EPA, from Ms. Pamela J. Philip, Work Assignment Manager, CDM Federal Programs Corporation, re: Island Chemical Site, St. Croix, U.S.V.I., Updated Community Relations Mailing List, April 26, 1995. (Attachment: Mailing List, Island Chemical/Virgin Island Chemical Site, April 20, 1995.) n 1 p. 10.0021 - Plan: Draft Communitv Relations Plan, Virgin 10.0063 Island Chemical, St. Croix, U.S. Virgin Islands, prepared by CDM Federal Programs Corporation, prepared for U.S. EPA, August 1995. 10.4 Piiblic Meeting P. 10.0064 - Announcement of Public Meeting to present the 10.0065 Work Plan for the Virgin Island Chemical Superfund Site, February 1995. P. 10.0066 - Sign-in Log for, U.S. EPA, Region II, Public 10.0067 Meeting for Virgin Island Chemical Superfund Site, Attendees, Wednesday, February 15, 1995. 10.6 Fact Sheets and Press Releases P. 10.0068 - Fact Sheet:: Remedial Investigation/Feasibility 10.0071 Study, Virgin Island/Island Chemical Site, Christiansted, St. Croix, U.S. Virgin Island, prepared by U.S. EPA, Region II, January 1994. P. 10.0072 - Fact Sheet: Remedial Investigation/Feasibility 10.0074 Study, Virgin Island/Island Chemical Site, Christiansted, St. Croix, U.S. Virgin Island, prepared by U.S. EPA, Region II, December 1994. P. 10.0075 - .Superfund Update: Virgin Island/Island Chemical 10.0077 Site, Christiansted, St. Croix, Virgin Island, prepared by U.S. EPA, Region II, May 1996. 11.0 TECHNICAL SOURCES AND GUIDANCE DOCUMENTS 11.3 State Guidance P. 11.0001 - Report: Virgin Islands Rules & Regulations. Air 11.0006 -Pollution Control, Title 12, Chapter 9. facsimile April 21, 1999. (Attachment: Government of the Virgin Islands of the United States Department of Planning and Natural Resources, Air Pollution Control, Application Information, General, facsimile April 21, 1999.) 500108 APPENDIX E VIDPNR LETTER ON CONCURRENCE 500109 GOVERNMENT OF THE VIRGIN ISLANDS OF THE UNITED STATES Deparunent of Planning & Naliiral Re.foiirce.'; Divi.uon of Environmental Protection RAINBOW PLAZA 45 MARS HILL FREDERIKSTED, ST. CROIX 00841 (340)773-1082 July 23, 2002 Mr. George Pavlous Director, ERRD US Environmental Protection Agency 290 Broadway New York, NY 10007-1866 R£: DPNR concurrence on tbe Virgin Islands Chemical Record of Decision Dear Mr. Pavlous: This letter provides the Virgin Islands Department of Planning and Natural Resources (DPNR) concurrence on the US Environmental Protection Agency (EPA) Record of Decision (ROD) for the Virgin Islands Chemical Superfund Site in St. Croix. Based on discussions between your staff and DPNR on July 17, 2002, the proposed change to the language on the Institutional Control section ofthe ROD is acceptable as follows: '^The Department of Planning and Natural Resources, in consultation with EPA, will utilize institutional controls (in the form of existing well permitting laws and regulations) to limit tbe pumping of groundwater at tbe Site to prevent interference with tbe selected remedy and to also prevent human exposure to contaminated groundwater until MCLs are achieve." DPNR expects to work closely with EPA during the implementation ofthe selected remedy for the Site - Altemative 3 (SVE/AS for the AST Area, MNA for the FPP Area, and Institutional Controls) and Altemative 4 (SVE/AS for the AST Area, Groundwater Extraction and Treatment for the FPP Area, and Institutional Controls) as a contingency remedy which would be implemented if MNA does not reduce groundwater contamination to MCLs in a reasonable timeframe. DPNR considers this Record ofDecision as an important step towards the eventual reclamation of a valuable Virgin Islands resource. Thank you. Sincerely, ^ 3DIJJ0 S.H0J,03yia eo:2iwd i-sn^oo Jean C. Plaskett, Esq. Commissioner A><-i i^Jo ••••IBH 'i' "^3143 II NQi53a"Vc{3"S"n 5 0 0 1 1 0 iDM ci-viunvK/ucr-waiergui • /-20- I , o-iDAiu ; viur.AiK/Utr-watergut-> 1212 ea? 4264;# 2/ 2 GOVERNMENT OFTHE VIRGIN ISLANDS OF THE UNfTRD S'TATRS ncpaniiKiii ('/ Claiming SL Nntm-al Ketounc^ Division (if F.t\viit>nmtiittil Piotfvlion RAINBOW PLAZA 45 MARS HILL FREDERIKSTED. -ST CROIX 00841 (340)773.1082 July 23, 2002 Mr, George Pavlous Director. ERRD US EnvironmentaJ Protection Agency 290 Broadway Now York. NY 10007-1866 RE: DPNR concurrence OB the Vir^gin Islands Chemical Record ofDecision Dear Mr. Pavlous: This letter js^vides the Virgin Islands Department of Planning and Natural Resources (DPNR) concurrence on the US Environment&i Protection Agency (EPA) Rec»rd ofDecision (ROD) for the Virgin Islands Chemical Superfund Site in St Croix. Based on discussions between your stuff and DPNR on July 17,2002, the proposed change to the language on tho Institutional Control section uf (he ROD is acceptable as follows: *^he Department of Planning and Natarai Rcsonrccs, In consultation with EPA, will utilize institutional controls On the form of existing well permitting laws and regulations) to Umit the pumping of groundwater at the Site to prevent interference with tbe gelected remedy and to abo prevent human exposure to contaminated groundwater until MCLs lire achieved." DPNR expects to work closely with EPA during the implementation ofthe selected remedy for the Site - Altemative 3 (SVE/AS for the AST Area. MNA for die FPP Area, and Institutional Controls) and Altemative 4 (SVE/AS for the AST Area, Groundwater Extraction and Treatment _ for the FPP Area, and Institutional Controls) as a contingency remedy which would be implemented if MNA does not reduce groundwater contamination to MCLs in a reasonable timeframe. DPNR considers diis Record of Decision as an important step towards the uvenlual reclamation of a valuable Virgin Islands resouree. Thank you. Sincerely, i ^ l ^ s n C. Plaskett, Esq. Commissioner 5 0 0 1 1 1