OFFICE MEMORANDUM To: From: Date: Subject: Project Number: r Jason Schindler HLA, Philadelphia Mike Phillips ^'^^^ HLA, Denver Januaiy 10, 1995 Island Chemical Company Data Review 29872 10.1 SDMS Document . y The completed reports for the data validation for the water samples collected November 4, 1994, as part of the Island Chemical Company Remedial Investigation are enclosed. We will retain copies of the data validation reports for this project as well as the data packages themselves. If you have any questions regarding these reports, please call me at [303) 293-6052. MPP/jr SchiOllO.mem Enclosures cc: Brian D. LaFlamme - HLA, Denver Island Chemical Company Project File Harding Lawson Associates S Engineering and Environmental Services 2400 ARCO Tower, 707 17th Street Denver, CO 80202 - (303) 292-5365 300125 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Volatile Organic Compounds Analysis Case Number : cy cf / ^ ^ Project Number: ^ f^ p>j_ / ^ / Site: : ^ v ^ n i T ^ k e ^ ^ . J r . Contractor Laboratory: g ^ ^ I a L y , . i > ^ ^ iZPi^c. A7..^U^ O J ^ K Z ^ Validator: p y y L f b QC Reviewer n.Fki'lh'f>y Validation Date: /.2./;i./7f y Review Date: / / J A r " Sample Matrix: Y/oAcv- Analytical Metho± S A h L C V y o A /^/f^ Sample Designations: - p T / / / O pn^yo f r / o j i / - T G 1 1 0 ^ J-t^h 11*^^/4- Z/^t> lA/ZSOo / Of /V S.O ^ ^ U/vsoc^3 U / y s 0 0 7 Data for the above samples are: Acceptable for use X Acceptable for use as qualified Unacceptable for use Is action required by the Project Manager? Yes ( ^ ^ / ) Comments: T A e o^a+os ^<^rc xy^lt 7.a,-teoi uj i ^j, fl^c. U S E P A C L/° X h r Na^:oH^[ Fi^ir^cft^i^ul Gc^iAcliA^ -fo^ 0^;rc^^yc V^-hc, / ^ c u U i ^ '^ voa_l,doc 10141994 1032 Form VOA 1.0 300126 DATA COMPLETENESS CHECKLIST JC Included, no problems Z. Included, problems O Not included NA Not applicable Quality Control Summary "X Case Narrative yy Surrogate Recovery Summary y MS/MSD Summary •yf^ Reagent Blank Summary y GC/MS Instrument Performance Summary Sample Data X Chain of Custody Forms /v Holding Times y Organic Analysis Data Sheets y Quantitation Reports y Reconstmcted Ion Chromatograms y Mass Spectra Printouts y A ' TIC Mass Spectra Library Searches Initial Calibration Data ^ Calibration Summary "TZ Standards Quantitation Reports y Standards Reconstructed Ion Chromatograms Continuing Calibration Data TK Calibration Summary \A^ Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms X Internal Standards Summary Instrument Performance Data yZ BFB Mass Spectra X Reconstructed Ion Chromatogram A Bra Mass Listings voa_l,(ioc 10141994 1032 Fonn VOA 1.0 300127 Reagent Blank Data •7^ Organic Analysis Data Sheets X. Quantitation Reports X Reconstmcted Ion Chromatograms y Mass Spectra FYintouts /K/v TIC Mass Spectra Library Searches Matrix Spike and Matrix Spike Duplicate Data y z Organic Analysis Data Sheets y Quantitation Reports y Reconstmcted Ion Chromatograms Laboratory Control Sample Z7 Organic Analysis Data Sheets X Quantitation Reports " ^ Reconstmcted Ion Chromatograms y Z Mass Spectra Printouts TIC Mass Spectra Library Searches M^ Comments: , . Form VOA 1.0 voa_I.doc 10141994 1032 3 300128 SPECmC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? C ^ ^ No Were custody transfers correctly and completely documented? y y ^ No Comments: Holding Times Were sample analyses perf^mgd within holding times? " Y e s ; No Comments: Instrument Tuning ^ Did the instrument performance checks meet acceptance criteria? / y X ^ No Were samples analyzed within the 12-hour period following an acceptable performance check? y y ^ / ) No Comments: „ , . Form VOA 1,0 10141994 1032 4 300129 Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration?-,-. (_Yes^ No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? _ Yes (^^/> Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes (-y^o/ Comments: Sea. o«>c 13 -^- o-Af-cty-trJ a-^ufy/cj- <^^ e>.-H-ecteA a>^<^lyfcj /c Were mass spectra providedjor the target analytes detected in the investigative^samples? ^ e s ) No Were the mass spectra of acceptable quality and analytes correctly identified? ( ^ e p No Were the quantitated results for target analytes calculated using the appropriate internal standards and were the relative retention times (RRTs) acceptable? Yes No 7 ^ Comments: r J u ^ I^T f.,,^^ . . . . ^ l,^-~DyAy£c...,r-^^^.yig^^^..^ ^ y ^ Tentatively Identified Compounds Were tentatively identified compound (TIC) seiches conducted for all sample analyses? Yes No / ^ / ? Were non-target peaks evaluated as required? Yes No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes No Comments: . /, ., ^ y ^ A/ y ic^'^. ^ly.^-'^tj.- X * " ^ - ^ X - /AJ'y^:>'^'^^^yA2-<2^ voa_l.doc 10141994 1032 Form VOA 1.0 300133 Log Books Were sample preparations properly documented and performed in accordance with method protocols? fes) No NA Were sample analyses properly documented and performed in accordance with method protocols? y ^ ^ No Comments: Form VOA 1.0 voa_l.ooc 10141994 1032 Q 300134 Calculation Checks Instalment Tuning ul H n l ^ // • / ^ Relative Abundance: /^/e- SZ> _ S £ j y - . JCK> - nc} O S ^ ^ A r r J J - ^ ^ / < ^ - ^O.S^S 10 m ^ Initial Calibration RRF: \y$-TD di o zy d-k I oi-o [\^) ryZtM^^y^<^^^^-^'^ y y y y z y ^ syy ^ / 75y- %RSD: /; i^'^y-yty,r-^ ^^-cf^ / d \;' /?^ :^ 4 Surrogate Recovery ^tio^-ycc^^ yy'/o 77.'Z y . d i\j^,yyy/^^ ^.37-y( ^ 7 / ^ voa_l.doc 10141994 1032 10 Form VOA 1.0 300135 Matrix Spike Recovery (A>Jr^yyAa.yyrt^ ^ 3 ^ ^ / ^ ^ /.,. ^ v ^ ^ ^ - - ^ - yy\^i/y'yyyy^^'ur^i^.^-i^ ly%o-~jyi[_ y y y u ' t ^ ey>-Ay.' .^-7- l'" " ', "*J/Z- y i ^ ^ (,.2^^ Sample Results T^^/^fi^ -^J-^^^^-^^/^ZC l ^ ^ ^ . O ^ / o CRQL:, „,p /l^j-Hc/ C / ? q i ^ C/ecjLA yi-^iZo^ Ft.-t. 7 '0 Detected Result: - ^ ^^; V^ y^y,-^^ TIC Result //o/ze^ voa_l.()oc I0I4I994 1032 11 Form VOA 1.0 3 0 0 1 3 6 HOLDING TIME QUALIFICATION SUMMARY FORM Sample klenlificatlon 1 PTino P T Z^l/O -pr-z^z/ Ty-? / l o v Date Siunpled u-H-9y 1 I \ y Date Analyzed //_/K-9X / iy /y /S'^Y Analysis Holding Time JO I h 10 /I Qualifier A y d / y ^ Al/ Comments: o o H w • J voa_! .doc 10141994 1032 Forni VOA 1.0 12 INITIAL CALIBRATION QUALIHCATION SUMMARY FORM Date/Time Instrument Analyte RF RSD Samples Affected Qualifier ll//v/ ? f / , ^ ^ % ^ 9 D - M . / % w o o H w 00 voa_l ,doc 10141994 1032 Form VOA 1.0 13 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time ft/y/^y ///'izA Instrument e A 7^ Analyte L^^ny./?.i.^~-i'Uer^ f" Ayytny^-)^ yy(-^a-*v.^ AA.TLy^./jydyyy /i- l^ydv-r^ A- -^T/^ZyrbiyMia^e.-- y.Zy>~!i ? -Pyy&iyrUHdyjt^ a .yM<2y ~l, 7 A)^y^f^^iyiini^- tji^/f,-MJ-'2yyyfy.i..r.^ y '^/4-'^(t^,t^ir-ny..^ RF ' .ooy ,oo^ f^ te- , 0 ^ 9 *oi3 %D 4^^.r -v^/. / A ^ . O ^ y "fr^y zi(^y ; i 7 . 7 ^ ^ ? 7.7.y Samples Affected y t ^ UO"/ j 1 1 1 1 \\y Qualifier y / i ^ y / dy r/r? x//e zrl^^ 1 zr/y f//^ Comments: 10 o o »-» vo voa_l ,doc 10141994 1032 14 Fonn VOA 1,0 BLANK SUMMARY FORM CO o o o Blank ID V6LI701 T g //OV Analyte yi.../Lyl.y..P^ nZlnAd-^ r^C^l^ylrV\r. t>U(t>irycl^ Blank Result (units) /^, A ' • ^ ' / ^.. IL Action Level / O ^JL ' / / o Ut^lL Associated Samples p T / / i o , F T } / ) 0 . yr/A-^y PT luc pr 2IIO PT /oyt / ^ Comments: ^.y^^^y^dzy.^ e j j ^ y ^ /yji^dy^; yz/y^/r-'-^ J voa_l.doc ini419'l4 1032 Form VOA 1.0 1.5 Summary and Conclusions "TAe Uflu-ltje. QirtiUhii'c. Co ^/iQty-^cAj' i^ctr<-i/^s -/^i^ Scci^„/f g^e^v^cvv^ c ^oc>, f Y / ? - S ~ a ye. a cceicA <^y6/f r o y u y c c^s J/fycf. -f titSU T k c ^ - e . l y y c sActi^c/oirJ d^ytcxfZoiyis} ^ V ^ ^ ' ^ O ) To >^ ^r<.-fo^r <^n.c/ 2 - {)'<--^a tvouc yn f^g^ '<^///•=-/ CC/,'4 t-*. f/oM lrC:Sty )'hf cA Z of Ho-f- Ke--g-'f- -^A< / ; K r rt. I/-/ f y C t^i f'C t^iQ U,. "IZ"<0 ^dc/iAlCi f-A, kc/.t/,Vg ^^g^/7o»i>rc -rcic-f o 1^ r T^ k' ^fe-foi^c, -^ ~ •^ g-f g *it> ^ 1-1 e , A ••> V i 2 ~ A e > r a H o h e ^yd'c/ <^o-f i ^ - c c j - "fly c i ^ y , y i A i ^ y i c y-r'f'c-i^.'oh . 7 " gLuc/ .? - K c-^-gL 1^ o n CL ktMyc 4 e-e t-1 a u e . , l r A i c < 7 y PCy-C-tt^-t (Al' TA-H-lr-^i^cC Qt^A 71 O V^ (rtyt f »^ I >vt ^< fu-v fot^ •f'kcjc. co~wOM.-^c 10141994 1032 16 Form VOA 1.0 300141 EPf'i SZtt'lf'L'E. HO. L.OU; COHC. UlATER V O L A T I L E ORGAMICS A N A L Y S I S DATA SHEET P T l 0 2 I fe. b hi a in & v. E T C£G 1JL£....S0UTH i...ab Code;; GULJF C a s e No L a b S a m p l e ID;: ylMSOOo L..ab F-'ile ID;: y.QoNSOS 2 5 , , 0 0 . ( m l ) Con t r a c t n c;>i-!;:> !>K.J , SDG No. D a t e R e c e i v e d s 1.1/05. D11V. t :i. ori F'a c. t o r " ,1, CAS NO L" 0 N C E N J F\ AT 1 ^. J i'-i i'. '-.u:i .••••'!..,) ; 1 0 0 - 4 1 •••••-•• ; i O O - 4 2 - 5 - /' !/i-"00—3' • u !'• o if! o •.•:.' 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C a s e No „ ;; HLA. l...ab S a m p l e I D ; : U N S 0 0 3 _ _ Lab F i l e ID; 'ZOAAZA>I P u r q e Volume:; ^L'?.!:Q9 . (ml) EF'A SAMPLE NO, P i 1 0 2 1 CtOn "•'.. i'"a.c; 't;; __ _ i"-/.r-- 1. [... „ C^TNT'- 1-I^. •> r-./I •: i—. i:; •f.jfio r'v:.',. :; _ h-UL-j M o M U 2..';;r..t.'i'...::!.. D a '1: e R e c: e n. v e (J:; i.1./0 5 / 9 4 D a t e Anal'/zed;; i.Li'.l£:Z25. D :i. 1 u•\. i. oi"i i"'a>;;'toi" v 1=0 i^iLl.fi'l be I-' "i" ]• 'C-^i 'fc:ii.ti"i d CAS NOf'lBER r'- r-l ' Y : : " I OLiND Ni'ii'l!:;: RT EST „ CONi..;, (uci/L..') \ f A\ 9 ^ 1=^ /^ n i U ^ .Ui:/M/s, 300143 Oruui5 LOW C O N C WATER VOLATILE ORGANICS ANALYSIS DATA SliEET ab Name:: ETC£G),.Ji...£ SOIJFH Lat:. Code;: GULP Case No L.al;i Sample IDs CNSOOl Lab File ID;; y.QyNS.Oi.._ r-'ii.r'qe Volume:; 2'.vi..00 (ml) r-i....f"'l Coi'i 'i;. I'ao't;: SAS No,. ;; EF-'H BANF'LE NO, PTl110 SDG N Q „ S i.fllzl:.. Date Received n LIAOAZAZ. Date Analyzed;; D :i. 1 l-l. 'l'. i o I"! i'" a c 't o i" ;; 1 . 0 \..-i--u;> Yi y'i „ l O A - 9 3 — ^ 1 0 8 - B o - : :l 0 0 - 4 2 - ; 1 3 3 0 - 2 0 - 7 4 . - Q 7 . - 3 - '71-V-O'! •••4- , 1 • • : X! !. a •••''..'•• - . . ' ' • " - . . ^ • - . * • '.i.'"" '^'.t'-y "-' "1 (.)(),'':,'1 •-<. '•-'' .1. A.'.''Y•"'''",•>:;:• •'" .i. \.\>y>C:,\.--K>y.- 7 5 - 2 5 - 2 1 0 8 - 1 0 - 1 COiir'OCt'-iD CONCEbrTRATION ( u g / L ) ••••'}.. ., 1' •••• .1/ :i. i::i y o ri 1 o o:-:' x r: a !"i e —T o 1 u e i"i e •••• (.• b.!. o I" o [j e i'i z e >' i e ••" L.'.v i"i y .1. b e i'l z e !"i e S 't. y!" e i"i e ••••Xylei"ie ( ' L o ' t a l ) — 1 ,, '.•:.'.•--'.)X bi "o;''iO'""-.:>"" i.':.h.Loi "••(./i"i .1. oi"Oi'iie ''.'.i'i a n e Hi'omofi'iO'tl':a!"ie —V :i. i"iy .1. 1...:!": .1. OV :i. c e L.-l'i .i. 01 "C;e'Li"!a.i"ie - N e t ; " i y l i : ; ' n e Cri].o) "zrie. r'lCie 'tci'z, e !"o !:)ai"ie •::i. !• i..'i...i| I )..' .;. :::•'..i. ,i. • .1. 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Ci b .i. o I' Ci. iijei"i i^ ei "i c^ FORi-'i I i...CV I ! 1 i!. : L 11 0 R «'.; Q r.;. 1 1 1 i u R 300146 010022 ii.i...CE ..OW CONC„ WATER V O L A T I L E ORGANICS A N A L Y S I S DATA SHEET TENT AT I V E L Y I DEN T I F I ED C01''iPuUl'4DS EF'A SA|-'IPi...E NO I b cl a m e s E T C£G IJ! j;;;._ SO IJ T H L a b Code;; GUL..F C a s e i'-io,.;; HLA.. !...ab Sai'nple IDs yij.SL.>02 l...aii. Fii.le IDs yoywS.'D2 F'urcje Vciluiiie;; 2 5 , . 0 0 (mil.) Con 'ii.i'ac't; T 2 1 1 0 ; SDG No „ s 941.95. D a 'li. e IV e c e ii. v e f j s l.j:/Z}ZZ2.Z. D a t e A n a 1 y z e (ii ;i A.1./.;L:4Z9 4. D i 1 u '•:.'}.. oi"i I--'a c -tcii i- s 1 „ O Numtiier iCs -found s (. U(ii/L.. j zfA^ ILI..IIKU i i " ^ i i ' i | ' " • ' I ' I •" • IkZr'] 010 300147 ILCA ...OW CONC. WATER VOLATILE ORGANIC iii. l-l a me s PJc/!Z}AA:.....3Z>AIli ab Codes GUL£ Case No ,. a b S a m p l e IDs yNS<)07 _ a b F i l e IDs Vni..liMS07R EPA SANPL..E NO- •3 ANALYSIS DATA SHEET (ii: (iMT li. 1" a c 't:: _ i'.'iAu'.i i'M'iiii „ s T B I 1 0 4 •'urtiiCi' Volv.vmen z!.!iii.;,.Op ( m l ) r.-. .-• t". ,'i fii f'lS 1-iO „ C0i'ipn!..ji-iD SDG No» s 94.1.95.. D a't e I'i; e c e ii. v e d s kXZAZ.Z.AA. Da'ii.e Ana.l.yzed s iv.i'-.;i D ii. 1 u 't. ii. (ii.!"i !'• a Ci 'k.iz r;; .il.^ 0., CONCENTRATION ( V.\C!/i,.. ) 1 0 8 - 9 0 - 7 • 10' 13-, 96- / .•;.•. • 74- .'''5- V'b- 75- 67- 7 5- 7 5 i>-'42-5 3 0 - 2 0 - • 1 2 - 8 - • • 8 7 - 3 - ..e3.,..9.... ••01~4- .. 09.-2 • •• • • 6 4 - 1 - • • 1 5 - 0 - - 3 5 - 4 - • • 3 4 - 3 - ^>-59-2 i. a(•;>•••• ( ; : . 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(ii i-^(i>me '•:. i'larie — ii. ., ii. „ ii ••" i i" il. Ci il .1. o,rci.e'L liai'i'iii' _ -(iiiai''b(i>n T e'Li"aiii i'lii.(ii.i" i(i!e — !••;I "oc'iixil ii. (iii"i.1.(iiii''onie liiiai'ici' •••• (ii ii i;i •••' ii. ,, -.'.]. •••• i.i' ii. (ii 11.1. (il I" (il iii r (il !i? e i l Ci' •••• I I' ii. (ii i'l.!. o i "(iiiivi'ii.I'len e •••i.i'ii iijrciiiKiniii'l.!.o!'"OiHe i".i'lane • •• ii. .. ii. ,, iii •• : '•'ii. (ii i'l .1. (il r(iie'ci'iai'i (ic • • B e n z e n e ; — 'L!- a n iii' • •• ii. „ ^ii,•••• i) ii. (ii il .1. (ii' r (ii p i- (ii liii e i^i ci' — i i rofiiO'T'o r'fii ••••'••;•••• i^'le'li.i'ly .i.•••• ii•••• l^'eI'l 'i.a.n(iine —i:i—lieXancM'ie _ •- i e'Li"acih .1. viic'viie'ti'iei'ie — ii. ., ii .,i;i,,ii:i^' i (ii-'Ci-aciri.l.cili"oci••i^i•la^e — ii. ,, 3—Dii. (ii i'l ii. Cii !'• (iliil e n zetici' ii. ,,4—Dii. Ci>iii.oI'-ciiiienzene •••• il. ,, iii "••• i) ii. liii 1^1.1. (il'[-" o iii oil'.:'. e i'l e i L.i ' -i ' y IAT \y r ; \u I? • M y ^T / y \ &^i5i cz . 1 . i •...' ii. ; I...I 1 y MJ* .i. i i..' 5 ;;..] R 5 ;u R M z. I y CJ 010026 300148 ILCE LOW CONC. WATER V0LATI1...E ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COl'iPOUNDS 1 Name s !;i;TC/GlJ.LJi..jSOllI>i L.ab Codes GUL,F Case i'-io„s HLA., l...aiii Sam liil le IDs UNSOO/ Lab File IDs VGUNSOZR !"'urae Volumes 2,^>,.p0 (ml) Cciin'iiract; EPA SANPLE NO. TBI104 SAS No., s _ SDG N o . : 94195. Date i-i;eceiveds IXAQAZzZZ. Date Analyzed: 11/1M2Z D ii. 1 u li ii. (il 11 !'• a (ii't o i'' s 1 » 0 -lumiiier TiliCs Youncl L.-I-K;:, i'-ii..,; ij.V'iii.rv Cni^'ii-'Qi.JND NAME li-.ii> ! m "i 7 ,Li\ •'• 'i :- i i-'"\ i iL,== L<. 300149 • f • •—• ! I .. 010027 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Semivolatile Organic Compounds Analysis Case Number : <^ 7- If. y Project Number: ^ a-p. -7^ -t^ _ / Site: y-?/a-n^y (Z/yp.i^.tOff-1 cz, 'O- Contractor Laboratory: / ^ yy^. ZJZ i A 7 o , t ^ ^1^/e-t?. >!..'- - ' w y z y yy^y IZZG^ ~:zz\yz..-. ->2^y-^ i/^hr bna_l,(ioc 10141994 1034 Form BNA 1.0 300152 SPECmC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? / ^ Y ^ No Were custody transfers corrgylv and completely documented? //Yes~) No Comments: Holding Times Were sample extractions performed within holding times? "YiT? No Were sample analyses perfoiroed within holding times? yX^/) No Comments: 'ai>ZJU-yt^^-;l.yy^^ /^(UZiJ-tZ.^r^yZ^ ^^^yi^yt:Z.r^6^^^^y/^ •JU-:^^t^.^;^yiy^^ l.(UZi^yzZ.^r^yZ^ ^^^yl^^uZt:Z.r^€.^^^^y^'y^ -..^^^ /oyi d^ u/'f/?'/, /A-^^-^^^^^'-^T^ ,^Ay.yzzz7i^ .-^f^ Instrument Tuning Did the instrument performance checks meet acceptance criteria? /fep No Were samples analyzed within the 12-hour period following an acceptable performance check? y ^ Z No Comments: biu_l.doc 10141994 1034 300153 Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibratiotii^ X v e s ) No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? ...^ X Y ^ NO Did the initial calibration meet the minimum relative response factor (RRF) criteria? ,•-• Yes^ No Comments: Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (7cD)? Yes No Did the continuing calibration meet the minimum RRF criteria? Yes No Comments: Avf baa_l.doc 10141994 1034 5 Form BNA 1.0 300154 Surrogate Recoveries Were the surrogate spike reeoyeries within acceptance limits? (J^P> No If the spike recoveries were unacceptable, were, the samples reanalyzed? Yes No ( / ^ ^ Comments: Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? ( ^ ^ ^ No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes No y ^ r^f"°, I _ Comments: . . . y i. z'^^'fr •Af A7o> azySyjtb .yy<^^^--^^^-^-y^ ^'y'iS T'' ^'^ _ _ ^ _ _ e>yy^ y^-^ ^ ^ A - y f i J Lf-T.yjyd-^^oy^yyiyyi.i.ji-) y ^ y ^ ^ y ^ * / / /^<^ s y < ^ - - y j ' 9 / Internal Standards Were the internal standard_areas and retention times within the required limits? ^'xZAy No If the internal standard requirements were not met, were the samples reanalyzed? Yes No y ' " ^ Comments: baa_l.doc 10141994 1034 6 Form BNA 1.0 300155 Blank Analyses Were the appropriate number^ blank analyses performed? y^esA No Were analytes detected in theb^lanks? y Y e s ) No If analytes were detected in the blanks, were the same analytes also detected in the associated investigative samples? ..-^-^^ / Y ^ No NA Did the sample results require qualification due to the presence of analytes in the associated blank samples? fesj) No • Comments: ta.im.t.M—hiC. tl II If s i ^ 1 7 ^ I ^ . ^ \ s ^ ^ ^ - ^ pTlAd t»yve.- % A S lA I j pTP-UO [fiyy/ul J - ^ Laboratory Control Samples Were laboratory control sample (LCS) analyses performed at the correct frequency? ( / i t s ) No NA Were the LCS recoveries within acceptable limits? ( ^ ^ No NA Comments: bQa_l.doc 10141994 1034 Fonn BNA 1.0 300156 Sample Results Were target analytes reported in the investigative samples? y ^ / ) No (l) Were mass spectra provided for the target analytes reported in the investigative samples? (tsA No Were the mass speeds of acceptable quality and analytes correcUy identified? ( / ^ / > No Were the quantitated results for target analytes calculated using the appropriate internal standards and were the relative retention times (RRTs}_acceptable? y^tsA No Comments '(} o^yzL. yuJi. cy^/^^^^^^.'^yzt y==[^- Tentatively Identified Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? yyAz%'\ No NA i^^ Were all non-target peaks evaluated as required? j^^Yep* No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? /^ep No Comments: bDa_l.doc 10141994 1034 8 Form BNA 1.0 300157 Log Books Were sample preparationsprepeBly documented and performed in accordance with method protocols? / y ^ No Were sample analyses propgri3f:4pcumented and performed in accordance with method protocols? " Y e s ) No Comments: bna_l .doc 10141994 1034 9 Fonn BNA 1.0 300158 Calculation Checks ,/y/?r Instrument Tuning i x k h f ^ ^ 7 j - y X^^^^ Relative Abundance: /^^ ^ C>^/3 ) initial Calibn„i„„ ^ ' ^ ' ^ T T ^ ^ " " ^ ^ ^ - ^ RRF: PAif =: / z y ^ ^ yo^ i %RSD: , / 3 ^ r Continuing cybXtion RRF: ^-y^y y l %D: W g a t e Recovery ^ ^ j / / ^ , . ^ ^ ^ . . . / J /o /^ - -—X /(TO r^ ^ 7 9 bna.l.doc 10141994 1034 10 Form BNA 1.0 3 0 0 1 5 9 Matrix Spike Recovery f f 7 0 0 d ^ J cP-?^X RPD: y ^o<^? <2L X >?,' / VA-^.'O ^ Fc.+ov- ^ ^ C >^ Q i- ^^''^''^ ^^^ Detected Result: f f ' T - ^ ^ T A j TICResuU PTA/IO d boa l.doc 10141994 1034 \ \ Form BNA 1.0 3 0 0 1 6 0 HOLDING TIME QUALIHCATION SUMMARY FORM Sample Identification Date Sampled Date Prepared Date Analyzed Prep. Holding Time Analysis Holding Time Qualifier P T I / ;J0H9A 11- Y ^ ? / / i - f - ^ ^ l y 7-^-9 7 y A "y^ A2A: '^Mg? /\/i}A' y^5 7 ; i o ^ 9 7 PTA-//fo^'^Y P T 1 0 ^ / 'f^'f'^Y IA) O O H o\ l-» Comments bna_l.doc I014I994 lOW 12 Fonn BNA 1.0 INITIAL CALIBRATION QUALIFICATION SUMMARY FORM Date/Time 1 Instilment Analyte RF '/y dy 7 RSD / AK ' U ^ Ay - ^ Samples Affected y^ Qualifier Comments: Ui o o l-» a\ to bna_l.doc 10141994 1034 13 FomiDNA 1.0 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instinjment Analyte RF ; ^: AM i Ay %D ^ ^ Samples Affected / Qualifier Comments: LO O O H» 0 \ CO bna_l .doc 10141994 lOM 14 Fonn BNA 1.0 BLANK SUMMARY FORM Blank ID 1 '^PL.ky Analyte uz.fi. y-yU/^4f^'7ia. Blank Result (units) ^ \ y^ti 1 y y> Action Level lOy^c, U y Associated Samples PTl 10 , pTzzjio, priori yU S-/yn-Sp 1 Comments: w o o iHlil.I .C 10141991 lO.VI 1.5 l-iinii UNA 1.0 Summary and Conclusions -folr SCKl^afft (Zit^tiy^lry CfV<3i^p ^ j I '^ S~ a irg. Ct C C C/) "fA ^ / f r Ac T •oV- JAI e. a j Cj ua,}' Ti'^e T k t - i - i - e - l U a J i / o t v k q J J ' O c/'«-V'C ^ Validation Date: / .2-/? / / ^ ^ Validator's Initials: fAK QC Reviewer's Signature: ^y^yyyy y y-yyyCyZ. QC Reviewer's Initials H P F Review Date: / / V / ^ i~ bDa_l.doc 10141994 1034 16 300165 Fonn BNA 1.0 LOW COMC. WATER SEI';iVn;...AT:i:LE ORGANICS ANA;...YST3 DATA Si-!EET i:F'A SA!"'1PLE MO. • ^1:) Mafiie;; EIC£GyLF...jBginii..._ K b Codes GULF _ Caii^e No,,;: HLA. L a b Saiiiple IDi; ytiS^iy-^ L a b F:i.:i.e ID;; SyyNS03.L S a fll i:) ]. e v Q 1 u fn e;; 9 /().. 0 (rn ].) Con X r a c t . SDG No., D a •(: e i;:! x 't r a c -i: o d ;; lJi:./,0 9 / 9 4 D a •!:. o A i'l a !i. y z o i::i;; 1 2 / <> 2,/9 A D :i. 1 t.l t :i. CJ I"I i'" a c: 'i: o r v. 1,. 0 .i. i"i .'i t.'.-^ c'!'. '.I. (;>j"j V C.I .1. i.i.ri't'^" , 0 'i. 1.1. .1 ) CONCENTRATION (i..u:!/i...) • l - ' h e n o . 1 •;•>'::. . . . . A Q — ' 7 h.i. i:jro!:-ihv>?i",o. .;. .!. .!.•••••;' . i . • - . i . \-\W--Vy..l-- / • - ; 9:L-:;:.e--7- ' •; :--;-i •••••i i - z •'.Z. ,/<'' • ' O X Vi:''1:. ^:^ i.. !;. ••••I.: r'r .i. Ci'••"C) *!j r ' O ILtai" ''':• ) • •'^' •••' i'i i.Z 'I. i"' '-.•-'.). O \"\ i.----;": O .'.. - W—;••! ;i. 1;. >" i" i -'•':'> o •••• .•; j . • •• n • •• ]••' i" o ij y . ; . a 'Vi '.<. ii o ' i ' l o X a C! i l . . CJ i' '!!'i!vj -^ i ' l a i ' i 'X-!* •Ni'-;. r'Cj^X'K'n;' oi"ie • .1. • : : / L J | . . i : \'...< i' i . j : IV.. • >!•• N :i. 'I. !"0'!:i Tiwi'i o . '.-:: , : ' • ' ; " • ' ) . ' . i... I i .1. V.J !" L . ' ! . ) M ^ . ^ ' l 1 1...1 .:. • 1 ,: 2 ,,'•'••• i ;•'•;!. c!'"!.;.';:']•• Di:>iK!"! z ' o n o •'i^'^o X a o i"1.!. C'zciiji..'. X.a'!!! !i. oi "t o ••4--Ci'N,oro--3--r'io•';.!• i v i o i i o n o l . •• 2 •••• i''10 t. i"iy .i. i "1 a p 1"! 'C ]">-':'. X O!': 0 '-\"i':^: Xa\.'.'Z\.i.o"'oc'-yc..\.opon ''.a.d ':•.or •••:;! .1 '-Y •; •:::•••• I I" '-1 C.i'i .1 O i " ' ; ) Z.. i"iOi"i O .i. ••/;!••••'../1": i. O i " ' O i ! a. iJ Z;''.'.. ZZk .i.Ol": O •••4ic;er'! a prvLhy . l o n o • 2 ., 6•••• D :i. r 1 ':•. 'c i"o i;.o!!.no!"i o ••3—N:!.'troar-iiI i n o 1 '•: '.:•-- Revievve Date , _ I r ^ . . ' 020011 300166 i L C C i...OW COr;C„ WATER SEMIV0LATI1...E ORGANICS Al^-iALYSIS DATA Sl-IEET EPA SAMr1...E NC # 11:) iHamon ';;;XC/GUl..P SQUTI^j Ca!;) Code;: GULF. Case No. '...ab G a c i p l o IDi; UIM.S003 i.-ab FLi.Io I D s S.S^'UiMSOoL.... i:i-!X.V: (.'• I e VO .i. ufne:: 9 1 0 „ 0 ( n'l 1.) i..;or'i c e n •i:.rated E x 'trac^i;. Vol.'..ime ;; : P T l 0 2 I 'Con 11" .a c •!:". 1 CAS No„;! _ SDG No,.;; 94:i.9a D a t e r ^ e c e i v e d u - l l / 0 5 , ^ ' ' 9 4 n a i . e 1;:.x'Li''actedi;; ! L ! ' / 0 9 / v 4 WaLe A n a l y z e d ! I; 1 2 / 0 2 / 9 4 '-• '-'• •' ) D:i. j.u.t;i.0!"p F ' a o t o r v. 1,. O .A.yzA.Z:: N ! ]-\P\'i .1. 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'"ie!"! avi ' v . h r e n o f'.i't "•:. I'll "a oo,'rie ! • .;. u i. J i" a I "I 'V. i'! e I'! e i-''yi-"ei"ie !.•• l.l'i;. ••.'.!. oiZY'i ;;•'v.i. p^n't i'i a.!. a ' t o -'--' 11 -'-'-• ""!-> 'i- C '-."{.1.0\"OZ:Or'l 'Z. i d iI'l o He I'l z o i. a ) A i'i 'Li"n"ai::erii'X' '•'•• !'i'"' y z - e i "1 e _ "••iiKi.s ( 2'-i:', •;;. i i y l ' ' i o x y l ) F-'rri:i"iala'i'.e D i - i " i - O r - l : y l P h t h a l a ' t e " Bei". 'A. o ( b ) F i u o r a "1 t h e r i e Wen z o i. k ) i .i,LLOi''ar'i ti'lei'ie J;.ien z o (a ) T'y reri e Ii'ideno ( i ,, 2 ,, 3-Oi:;) r'yi-f.-/.^^,e i>:i l;:ienz (a.: h ) An'U'ii'acxer'ie Ben z o i cs., i'i „ i jP'ory'i f-rio VALIDATED Reviewed 3y ^..Ty/Z Date 17./^ 7/7/ , '...' i:: I ! I 0200JC 300167 j.LCF L.OIJ; CONC, WATER SEnIVOi..:ATI!,_£ ORGANICS ANA1...YSIG DATA SNEET TENTATIVELY IDENTIFIED COMPOUNDS Ei'-'A SA!''ii--'LE:' NO « a hi \--\ a fll e s liiTC / G i JI^P.. j ; ; OU T H L.ab C o d e i : GULF C a s e N o , i.,.ab Safn|:>le ID:; UNSOOo^ L a b F i l e ID:; i:)afiip.!.e VO.I.urne 0.,0 ( f n l ) I..-ori (xer'p •r i-axe ' O .1. l.UI'ie I- ^.'..•0'J Con t r a c i : AS No p ( l.l ! 1 .;. 1'vLxf c; •!;. :i. ix; ri 'v o ,1.1.1 m e ;; ._ SDG No „ ;: 94.1.9.;::. D a t e i' Maine:: EIjC/GiJL^SQU'Ti^: ....ab Codes GULF. Case No.:: HLA i.-ab Sample ID:: UMSOOl b.ab File ID;; OVUNSOIL Safiiple voli.une:: C o n c: e ri •L I- a •!: e c; E: x 't r a c .;-!••!jec:•<:.io:^i Vo].i..;f;,e;; Z:Zy..;y:i <-. m 1 ) i.iine;: 1 0 0 0 •i':> i"iO „ . 1 . , . '-•'.< K ' . . . : . 1 . 1 CONF-'CiUND Con t r a c t (1.1 :i.) D A T A SF^iEET E P A SANP1...E N O . i R T l l l O SDG No„n 9 4 1 9 a D a t e R e c e i v e d s * l l / O a / 9 4 i^sate Eilx^trac'ixed;; l l / 0 9 / ' ^ ? 4 Da'te A n a l y z e d n 1 2 / 0 2 / 9 4 D :i, 1 Ll •(•. :i. c. |-| F" a (x 'l o y;; ;| ., Q ^ • • i ; : CONCENTRATION (uq/L) 108^-95--2^ lll^-44^-4- 108-60-l^ 1 0 6 — 4 4 ••.•I;:.. f.';'.-;...^''•v.-'" '1. O a ••••(;>/••. 9 — :;.;; ;; .-..9;:,... ;i.... 120—82--i-' 106- 47^.-8... ' • - •;; :i •',' ( • '•'•I 1" •1 ,..... . . V Q 0 9 ••••58 •/ - - " / y - - i : 1 - 1 1 - 9....9 A... 6-20^^ •••09—I- •-.'• " * C' •" y.."" M-"Opl"o -.;..'ropyl an':; I" i.'Z'no.!. '•' '•• '•---' V 2--L; n 1 o " ' o e 'ix n y l ) E 'i;.i'^io r ^:' ••" t ; l"i 1 O •'• c ; i:;i fl v;> ...i r i'! 2^-No thyl p yo^^ o 1 " •••• '•^.••-!'•';e'i:•••iy!i. p | - | e I ' l o ! i . ••••N--N:i.•ii.roso-^Di-n-F' " •••• .••I e X (Vu:: {••i .i. o j^' o e 'ix M a !"i e ••"{'••hi. 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'ixi'-cixxcici .. .1. !..: i ""^''''..V'i' (i/ii'i'X;.x>I'.e;"!y.;.••• pi'lei'iv'.l.e'c.'•.e•'• • "• I'lexac:r'i 1 c>vober^ zex;"!o —-'," ei'i ca.c; '\ .1.(j r'(j'J r'lOrIc'l ' r'l a;'i '•'. i"i)''en e ir :. tie I'a; "I 'cner'iO 1 '-'•-•- '•'y.i. oo\'\ zy.i. pXrcrial;;..'l.e --'•' M --'•'! "•'.•.''.[. oh.!. c'i i''ijX'.c''."; z X. ci i n e X.s izy-•Z•^.\•ly^. i'lcox'y'l) F''j'v.xi"ia }'.- .:. cxo'•".;;•.V'l 'ci'lc;'!".o. • l i " i C i e n o ( 1 , , 2 .. 3 -..x;c; ) i'-'vT'erie x.'j. i;>er'i z ( a „ ri.) Axi •ixl"i:"ac;er'ie kier'i ZO f, Q ., j"i,, :i. ) ]-.'cx •" v l e n e •^ r .n t ": r=^.v Z- Tcn A^AL. Reviewed By Date /2./yY/9Y yr ^yys^i 020023 300170 ILCF EF'A SAinF'LE NC LOIA! C 0 N C „ WATER SEI'IIVOLATILE ORGANICS AilALYSIS DATA SHEET TENTATIVELY I D E N T I F I E D CONFOUNDS 1 ... |. ' . . , , . . - ,1 I — t - 1 - . / (-•- I I I |... r-- {-. I i . . i " . I l(.l 1 ••!•::',111>:L' 'i !;;...l,'.....:..£,0.yh.:\'Z .^'iL:'.•.•.L.LC; ,al:j f.^odes G1:1L.F._. C a s e h!o„ Lab Sample IDu UN.S001 :...aix. Fii.le ID;: SVyNSOlL iiSamp .i.e v o 1 cifne;: 9.i50 . 0 (. fn.1.) - a c t 'v I r'l .i e c: '>. '\. ori V o .1 \xtr.e' T 1 1 1 0 Ccjn 'Ixi^'a. I..'ix;; ( u \. I SDG Ho., V. 941.£5 _ Da'ixe [•Received;;- ^AZO'y/y'-': D a t e F;!xtrac-ixecN: ^i..!./()9/94 na'Ixe Aiia.!.yzeci;; %Ay.zyZZyZz D .1. !i. n -ix :i. o r i F a c 't r, r ;; 1 „ 0 cuiiDOi" I .1. l.-c:. 't'oi.u"ici;i T „ COi'--lL ( Cl i':i / i 'i VALIDATED Reviewed By Date j £ y ^ JjJzLl/Ll7£- 020024 1 ;"••.":• I i . , „ " r " j " 300171 ILCB LOW CONC. WATER SENIVOLATILE ORGANICS ANA!._YSIS DATA SHEET EPA SAI'9--' ata Name:; ETC/GlJLFi...Sgin;K a b C o d e " GULF" Ca:;;.e i'-io., n . ;:t lx. ^::. --:^ f I'l p. X o i .D i ..ab F i l e ID SyyN302L S a m p l e volufnoii 925...0. (fnl) c'lor-i cer^i •'xi'ated Fiix'crac'ix Volcai'iei; 1 0 0 0 C(xiri 'l. rac:t;; P T 2 1 1 0 SDG No,, :; 9 4 1 9 D a t e F ^ e c e i v e d n 1.Z/.Q':Z D a 'F e 'c. X 11'" a c: 't e d n 1 .i./.y.2. Da'ixe Al".a!i.yzed ;; .1.2/02, D :i. 1 u 'ix ;i. o n F" a c; 'i: o i'';; 'i,.. 0 .n.:i e(X ix 1 c:.i'i vo.i.ufne" 1,. 0. (Cl 1) !:)!••!;; CONF'OUND ( C.'X'l...''. /')0.... _,CQ.... -j . , lo.;:.- ; 6:.::'!i. • ..-! .... •"•' ; 8 8 - 7 5 - 5 ; 1 0 5 - 6 7 - 9 - t.:\p,-—~y.'.y--ij. 1 3 1 - 1 1 - 3 - 2 0 8 - - 9 6 - 8 - 606—20—2- - i-' i' 1 e r'. c. .i. • o;L 1::. (2—Ci-i 1 c;.!-"(;>e t.ny.i. ) ';•• "•'• her' _ -2- C i-. 1 o Vo XJ hen o 1 -/;!—i'ie c i"iy .i. u i'lon c;. :. -2 ., 2 -o X vi:;. 'i. 'Z- ('}. •••'Z- i "i 1 o i''o p v"o pa'"i e .i -4•-1Me '•:. \"iy .i. J:;. 1 "iei"i o.;. - {-•I •- i'-i :i. t i-- o cxo -- D:!. -- r-. •- ''•' r o z< y 1 a fii i i"i e •.(....l-j V .-1 1 -;^:;.. 'I.i-c:.x..en zerie _ _ • .1. •;;:. 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X\'\& - f'. c; e i"i a. r. rx ix i". e i". e VALIDATED Revievved By y y / ^ Date ly/yj/^f ... ,... a ; '..- 5 ' 1... 300172 020023 Oi-M'i :i.LCC ..OW COi'-iC, WATER SEi'!IV01...ATIi-.E ORGANICS ANAi...YSIG DATA Si-iEET EPA SAl^ l.-ab Name;; ET.C£GiJ.,F....SOlJ.TH z<.b Coden GULF .„..acie i'.io., ;: F'il...i..| i.,.ab S a i i m l e IDs F.;NS0C '-•.-.S'.i.'^, :-"-,'-.-' F i l e ID: SVUi--lS02b, Cf.ir-ic:er'i•txra'lxed E x t r a c ' t Volcifne;: 1 0 0 0 C.::)n •t.'-"a.;x'i;. •::>(-'K:) ! ' - i O . ( Cl 1 ) ••T2110 SDG No., D a t e R e c e i v e d ;;- I..' a t e i::! x: 'ix i- a c: 'ix e d ;: D a t e Ar'ialyzedu Di J l.l't:;.on FZ'.Q''V.or .1. / '-..I a .• 11./0.9./9 1 2 / 0 2 / 9 . n ,*! e c 'c ;i. Oi"i . u i i i e ; ; 'i .. O i. U .!. ) s:)F! ;«:::i N U „ COi''iF'OUi-..!D L,L.!i--.!i...!::.;••; i Hp! i .) C.ii'.! ( c i q / ! . . . ) X. CK.>-i.^k;.- / - 1 3 2 - 6 4 - 9 - :i. 2 1 - 1 4 - 2 - 100—01 -; r-. -'. .... •-:•-. V.-..... .c'';i. i::..x.:'ri '.t fX."i"i.U"ar-! — 2 ,| 4—D;i.r-i i -t!-"O->XCJIcier'.c? Die'ix i"iy 1 p i'rix i'xa. la'ixe •; •'•• C: i "i 1 CJ \"o p i "Iej"i y').. — p l".izn'/1 e c i"ie!-" i'-' 1 i,.i. CJ !'• e I' IO" 1 ..-.-1 i-. '•;,, t,-.-,--.•..-'.'..'. \ .i. ex CJ-- /:;.—Tie'cr-iy... pr'ioricj.i. l-.j •-1'-.|;.. 'ix r CJ 'Z:- o Cl :i. r> i'i e!'-. y.;. a fn ;i. n CJ i.'.-.. ) 4—ivi:-cj!-i';cj':jhe!-i V.i. -'• iijliex'.y.i.e'ixriei" i-'ex x;.. c; i"i.;. or-cji;jerx z en e *—i-'on -x. a c; x'. .1. cj I'cj rj ne!"i CJ .1. K : I i 2'^'—-0(J-—O.. .i. ,!. / — ':.i.!, -- / - 1 1 7 - 8 4 - 0 - 2 0 7-• 08—9- 5 0 - 3 2 - 8 ac:.-/o-c:. l-ll'l ... i : I- .:i..^...:.vl 1 V.^ . I . . . 1 F 1 Cl CJ r a r'i 'C ri e n e B Cl 'L V' ii. :x. e n z y'J.. p n 'ix !'i a ii. a i: e ^::,,, 3 ' —D ii. fxri.i. cji-cjiuei'i z:!, ci i r : e i'^en z CJ ( a .j f'-iri 'c'."ivzi.cic-jrio bi!.-;;:. f. li -i::. ci'jy.i. ri.ix:xy,!.) F''rixi"iala'ixe .i.J ii. — n — i.J ci'ixy .i. i-':'!'ixi'ia.;. a'Ce fcien z CJ I. iiJ) \" .1. cicji-"an i x h e n e T^ f;:. ."i 'z CJ ( I'X ii F 3. Cl CJ 'z a n 'ix i'i e r'i e fcierizcjc a ) i - ' y r e r ' i e .1.1 "I ci .XJn CJ f 1 ,i X:i,, .ij —cic! } i'-'vi"eri e Dii, bcji-j z ( a ,. n ',> Zic: ixhi-aci.ix'rie B e n zcj { q ., j'i,. ii. ) t - ' e r y l e n c j i:: I • _ . , . . . . .;: I y /"' ^ h..m AE4/C R.3viewed By y— / ' / Date — U / J J ^ L U I L I iiujjiimL»u.wwnmii 300173 02003C ILCF LOW CONC WATER SENIVOLATILE ORGANICS ANALYSIS TENTATIVELY IDENTIFIED CONFOUNDS EPA SANPLE LaliJ Names ETC£Glij,P._j30lJTl:i I...ab Codes GULF Case Mo..: HLA L a b S a m p l e I D s UfciiOOl.. Laiij F i l e I D s SVUNSOL iafi'! p 1 e v o il. Ufiie;; 9 2 5 „ 0 (fn I ) Ccjn c e n t r a t e d E x t r a c t Vcjiufiie;; 1.CK>0... iii i"i .:i e Ci t ii. cjn Vcj il. cime n i,.y. (*-'• ^- ) C.Dn t r a c t <-. u .i. } DATA SF^iEET PT2110 SDG N o „ : 9 4 1 9 5 D a t e R e c e i v e d s - I.X./JZAZS.Z. D a t e liii X -lx I" a c t e d n 1 i / 0 9 / 9 •4 a.i.v'ze.ij:: D ii. 1 u 't :i. CJ n F' a ex t CJ i"; Di-l;; CJ I-!ClfI', iije r ii'iCs "fcjund ;; COilPDUi'-'D i'^lANF: ;UN!I ,*—'"-^ Pipr>s/r-g- i-- (y . uyS(A<^2^ \7yys/zyo3 Data for the above samples are: Acceptable for use / Acceptable for use as qualified Unacceptable for use Is action required by the PrQiect Manager? Yes ( N A ) Comments: •1= CLP ^ o w : i L n o 3 . o C nt^yr Vvi'-f^l^ fie e><:cCyP+/o H. o f ti,c CLP row xir^02.Oj Pc^^i- dj p v ^ ^'^^ "^° o-vo. - at^-f'iyoi^y i)e.V'y//l't^u^ c< i-icA i-ku I ll ly-i-^ ^ tDcl_l,doc 10141994 1035 Fonn MET IJJ 3 0 0 1 7 5 DATA COMPLETENESS CHECKLIST Included, no problems Included, problems 0 Not included NA Not applicable Quality Control Summary / Case Narrative y Chain of Custody Forms X Cover Page X Holding Times X Inorganic Analysis Data Sheets •y Initial and Continuing Calibration Summary X ICP and AA CRDL Check Standard Summary NA Linear Range Verification Standard Srniunary •^ Calibration and Preparation Blank Summary X ICP Interference Check Sample Summary •^ Matrix Spike Summary O Post Digestion Spike Sample Summary X Duplicate Sample Summary X Laboratory Control Sample Summary NA Method of Standard Additions Summary •^ ICP Serial Dilution Summary X Quarterly Instrument Detection Limits Summary X Annual Interelement Correction Factors Summary X Quarterly ICP Linear Range Summary X Sample Preparation Log Summary X Sample Analysis Run Log Summary Sample Raw Data X ICP Raw Data X GFAA Raw Data X Mercury Raw Data X Cyanide Raw Data Comments: ii>el_l,doc 10141994 1035 2 *^°™ ^^^ '^^ 3 0 0 1 7 6 SPECIFIC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? ( ^ ^ No Were custody transfers correctly and completely documented? ( ( ^ ^ No Comments: Holding Times Were sample preparaiionsaad^ analyses performed within holding times? ( ^ ^ No Conmients: met_l Joe 10141994 1035 3 0 0 1 7 7 Instrument Calibration Were instruments calibrated daily and each time that sample analyses were performed? ( Y ^ No Were the instruments calibrated using the minimum required numbers of blanks and standards? (Yes) No For the GFAA methods was one standard analyzed at the Contract Required Detection Limit (CRDL)? Yes C ® "^ For the applicable methods did the correlation coefficients meet the minimum requirement of 0.995? (YeT) No NA For the cyanide analyses wa§a midrange standard distilled and analyzed? ( ^ ^ No Comments: . * ThujlUir^ O n i p L o^ f o y ^ X skoxy^S {O Uj^/i \yyk:oli ^Cts "XCAL ffrxt^cAcKiycAs a y e <^y 1 o ^ ^ T^ To ^ cAi,y / o o CFout,^ >: I \y^ Initial and Continuing Calibration Verification Were the calibration standjjtsjs and blanks analyzed at the required frequencies? (Yes) No Were the standard recoveries within QC limits? Yes ( N ^ Comments: , _ _ , - _ i D-7 c ^ .i.' ,.i^ y fka i^/if'ct-l Ccclf' ^i^cKfi o tn Tk&. Vo Vzc-jyyci^y i^y aK+, ^ P h ^ 1 ^ ' \yyuj 1 2 1 . y ^ . . ~rk.t.cAo^c^ a l l i-e^r^i-fj- ^i^ct^fci. ikt.,^ VAc l^Sj- i F c n fU<^ 1 k? L ^ ^ ^ c \ c c e ^ ^ ^ i / e . S,Ac^ ri,,'ky r e c o v e r i e s Wc«^e o y y A c fi^c acce/yf'^tncz l}e.c»iyJis. i k e K^«"ri/-iX S ^ > i^<-- CWfcw-,'^^ ^/( S ^ l c ^ : u i ^ ^ f k . / h y ^ , o^A c.i.i.ydi.y ^.S^l-U kciiy. teeui aiyc^lZAicA ^\f ^AI i^a.i-QcA C T / IJiT A • roeOjdoc 10141994 1035 5 FofSiMETli) 3 0 0 1 7 9 Laboratory Control Sample Were laboratory control sampie analyses performed at the required frequency? < J ^ No Were laboratory control sample recovery results acceptable? (Yes) No Comments: ICP Interference Check Sample Were ICP interference checksamples GCS) analysed at the required frequency? (Yes) No Were the ICS recovery cnt£m met? (Yes) No Were results greater than thsTOL reported for elements not present in the ICS solution? (Yes) No Were negative results with absolute values greater than the IDL reported for elements not present in the ICS solution? ' Yes ) No Were the concentrations of metals in the investigative samples simUar to the concentrations of the ICS solution? Yes rNo' Did the sample results require qualification due to interference problems? Yes d ^ Comments: mel^l-doc 10141994 1035 ' " 6 Form MET IXi 300180 Duplicate Sample Results Were duplicate sample analyses performed at the required frequency? ( ^ s ) No Did the duplicate sample results meet acceptance criteria? ( j e s ^ No Comments: Blank Analyses Were preparation and calijjration blank analyses performed at the required frequency? ^Yes) No Were elements reported in the blanks at levels above the CRDL? Yes (^Noy Were elements reported injtie blanks at levels between the IDL and the CRDL? (Yes) No Were negative results withah^lute values greater than the IDL reported in the blanks? (Ye?) No If analytes were reported in the blanks, were the same analytes also reported for the associated investigative samples? ( Y e s ) No Did the sample results reqjjdiequalification due to the presence of analytes in the associated blank samples? ( j e T ) No Comments: TkiL /Vow, a-i/f ^ / ^ ^ c rej-M/^-/ "^^ "^ P T U / O Ct^ ' / JU^ Sc trial cCUf.A^ yes^i-i^ -Toy ^ ^ U i i ^ ^ j h^aj,hctr,iy}^^ ^i.A Kva»^^cvA«n^« Were detection limits provided for the reported target analytes, and if so, were they current and acceptable? j ^ ^ e p No Comments: lDct_ljioc 10141994 1035 10 Fonn MET IJ 300184 • HOLDING TIME QUALIHCATION SUMMARY FORM Sample Identification Analyte Date Sampled Date Prepared Date Analyzed Analysis Holding Time Qualifier F T / J / 0 r.cp't/^zze^ i i - ^ ~ ? y l l - / 7 - ? 7 /1-17-9A /yg/yG- pyiox/ MS no7 ?Tzz^i/o u^ xy PTino (^yA.Wli il^t^.^^ y n-ia^ny n-ir-"^? PTIO^^/ 71 Uio Y fTn-110 C/ Ay 7 7 f?<^ Hy-iy^fy /i-/p-'^y n z/-/,/^^?/ ii ^ ^ 1 1 - / 0 - 9 / ii-y-n /m- ?/ /ZL-02-9y Comments: LO O O 00 tn nicl_l ,doc 10141994 1035 n i'.«tiiMi!r 1.0 BLANK SUMMARY FORM Blank ID 1 '^^^ cen ^ cr. n :i I ^^^ Pycn P/c<^k — I — : / " ' • - ' - Analyte Be rY 111 ^^^ /4 K+i'u^«?Hv / J . \rou\ Mac, Hc.r,'uu^ •^ y 7 /' k o Blank Result (units) 0 . \ u c f L 7. 2 U c / l - H i . s uyL - 1 1 . 0 UCfU 7. OS- u y i Action Level C . r uv/Z. • • 3^31^ r 1^1 L ^r UJL IS'.Zl-T^tt/l Associated Samples / i l l Sc^\y.y>lc-^ /lU Sot^^lt^s All Sci li^y/cs A l l ScM^xflcs A l l i^c^u.^lej' Qualifier u CFT A/o ^1«. Of C p T I l l y ' ^ h r u C / ^ j i ll II //foj Comments: o o 00 inel_l.,l,)C 10141994 1035 12 Fooii MI!T1.0 Summary and Conclusions -f ^ t A C " ^ ^ t ^ c - f t - Z x S - b ! p < ^ > ^ g & O V / - C - | / ' / g v r f a / / / l ^ g > O I ^ ^ I T A A ^ - j k c < K C C C p i - C \ I ^ C Q , C y l F c i r i , f\ 0.(1 J e / e t ^ / C ^ * ^ , Fk&lh'cAL^ , ( X H A a H J ! i-^ot^y lycy ly l + s Uuxyc fceg.1^ QUCt-l/plcJ cyylI/lyi^t^ V-cs^^lF •('oy P T ^ l l o h o ^ ^ t kccyi ci(yuliyZirc7 <^S U > ^ c / - c + c c P e / A'^e (xStTocio-FecA 'kict.uxh c o ^ ^ c c ^ t y u A i ' t n ^ s . n l { Cc^l Ci'ty jr^ . i^i^o.c,u\e .City, i'i.^ cx.^A \y\otv\c,eA>yi.cSc y c y t.t. I-hy a-i--c t^Ut^lF-flcc/ a.j e j frt,~v»tfe F ^ / ^ cjir^a ly-f-lca-l f/p.'A' IU \^,'it\ e, i^exu/f-f nci_\ye. L ^ci^ ^ u d / ' f i c c / H- JiJL c.y,y^-hrc/ C 7 / ( A i ) - P T /<>?• I Ay\.ii in-^yy^y , ICCKCI , / " C / C H I M . ! ^ A ^ t / ikcll,'iA.u^ 7 ^ /^.S 110 "i /tKf/uvoMv . <^^-j^e*T."c , IcciA , ,r<.l<-^i ^^-^ CKi^tJl tkoi 11 y L^i^^ FT llio Lc^4 ^^7 fkotji,yy^. P T ^ l / o A^i'f'i y ^ o ^ y , Icctdl CjnJ t U u I l( PTl SDG No.: Lab Sample ID: UN£ Date Received: 11/ Concentration Units (ug/L or mg/kg dry weight): UG/L 1 1 1 Mil |CAS No. 1 Analyte |Concentration|C| Q |M | 1 1 1 II I I 17429-90-5 1 Aluminum | 145 |B1 |P | 17440-36-0 lAntimony I 1.4 |U1NW T jF | 17440-38-2 lArsenic | 8.6 |B| IF | 17440-39-3 IBarium 1 10.6 |B| IP j 17440-41-7 IBerylliuml 0.10 |U| |F | 17440-43-9 (Cadmium | 3.3 |U| |P | 17440-70-2 (Calcium 1 50700 ( (E T |P ( (7440-47-3 (Chromium ( 4.5 (U( |P ( (7440-48-4 (Cobalt ( 9.5 (U| (P | (7440-50-8 (Copper ( 11.9 (U( (P ( 17439-89-6 |Iron | 516 ( | |P | 17439-92-1 (Lead | 0.92 |B|W T |F | (7439-95-4 (MagnesiumI 23300 ( (E J |P | [7439-96-5 (Manganese 1 315 ( | E T |P 1 (7439-97-6 (Mercurv | 0.20 (U[ (CV| (7440-02-0 (Nickel | 25.8 (U( (P | (7440-09-7 (Potassium( 30800 1 ( (P 1 17782-49-2 (Selenium ( 2.0 [U[NW 7 (F ( 17440-22-4 iSilver | 4.1 |U| |P | 17440-23-5 (Sodium | 513000 j | |P | (7440-28-0 (Thallium | 1.5 (U(NWT IF [ (7440-62-2 (Vanadium I 5.9 (U( (P | (7440-66-6 (Zinc | 278 ( ( (P | (57-12-5 (Cyanide j 10.0 IU( |AS( 1 1 i l l l l Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Texture: Clarity After: CLEAR Artifacts: : VALIDATED, Revievved oy i "^^--^^ : iz:—c— . Date.. /-^"-I£I — FORM I - IN 300188 w.C! EPA - CLP EPA SAMP2 1 INORGANIC ANALYSIS DATA SHEET Lab Name: PACE Contract: Lab Code: GULF case No.: HLA SAS No.: Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L I PT211 I SDG No.: OS Lab Sample ID: UNS002 Date Received: 11/05/ 1 i 1 i (CAS No. j Analyte j Concentration j C I I I ( (7429-90-5 (Aluminum ( 641 ( 17440-36-0 1 Antimony | 1.4 (U (7440-38-2 (Arsenic [ 21.6 ( (7440-39-3 (Barium ( 19.2 |B (7440-41-7 IBerylliuml 0.10 (JB- (7440-43-9 (Cadmium | 5.1 | (7440-70-2 (Calcium | 245000 | (7440-47-3 (Chromium | 17.3 | [7440-48-4 (Cobalt ( 9.5 |U (7440-50-8 (Copper 1 15.9 IB [7439-89-6 (Iron | 3230 [ 17439-92-1 (Lead { 9.7 ( [7439-95-4 (MagnesiumI 29100 | 17439-96-5 (Manganesej 1090 [ 17439-97-6 (Mercury { 0.20 [U (7440-02-0 (Nickel | 34.1 [B 17440-09-7 |Potassium( 30300 ( 1 1 Q |M 1 1 1 IP 1 NWJ- IF 1 IF 1 IP 1 U (F 1 IP 1 E 7 IP 1 IP 1 IP 1 IP 1 IP 1 W J IF [ E J- IPI E T IP 1 |CV| 1 IP 1 ( IP 1 17782-49-2 (Selenium | 20.0 |U|NJ IF 1 [7440-22-4 (Silver | 4.1 (Ul (P ( [7440-23-5 (Sodium | 501000 ( | (P | (7440-28-0 (Thallium ( 1.5 [UINWCT IF | [7440-62-2 (Vanadium | 12.7 |B| |P | [7440-66-6 jzinc \ 1460 j | |P | 157-12-5 (Cyanide | lO.o |U| jASI 1 1 1 i l l ! Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Clarity After: CLEAR Texture: Artifacts: NO VALIDATED, Reviev/8d By ^hzz^/y±^Z^7^Z^:^^S^±A^ 7Ak Date . l-^z2£r— -~^ — ^ — - FORM I - IN 500189 'ILM02, 080006 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Organochlorine Pesticides and Polychlorinated Biphenyls Analysis Case Number : J 1 1 1 ^ Project Number 2 J ? 1 2 l o . } Site: T s l c ^ i ^ J C k e . y , c d , i Ct,. Contractor Laboratory: p^^cc ZE^c.^ Ne.\Ay OirJe'^>^s VaUdator: K . A. l<<^lp QC Reviewer: ^/. p k l l / l p s Validation Date: / s / z y A y , / ^ / p c / f ^ Review Date: / / S / 7 5~ Sample Matrix: Wc( -hev Analytical Metho± S A ' h L C Wo A f^/f:^ Sample Designations: Lcil> St^^^fc TUP PTl n o p l ^ no P T l<^2l UNS o o ( ( A N S 0 0 2 U M S o o 3 Data for the above samples are: X Acceptable for use Acceptable for use as qualified Unacceptable for use Is action required by the ftsiect Manager? Yes ( N O ) Comments: T k c cluic, ^ < i r ^ v c l i ' d c ^ i c d (ys'ii^y t k t ' ' u S E P A C L P Nu-i-t'ci^y p t ^ ^ c i t ' t ^ ^ a i G u , ' c / e / ; ^ c j TO)- C^l-^^-^/c K?^-}-^ / ^ e W e v y " ^ F e i . / ^ ^ y . C( ocp_l.tioc 10141994 1032 Fom OCP IJ) 3 0 0 1 9 0 DATA COMPLETENESS CHECKLIST JC Included, no problems J; Included, problems O Not included NA Not applicable Quality Control Summary X Case Narrative •^ Surrogate Recovery Summary AZ MS/MSD Summary Z7 Reagent Blank Siunmary Sample Data yA Chain of Custody Forms y Holding Times y Organic Analysis Data Sheets >v Quantitation Reports X GC/EC Chromatograms M A Pesticide/PCB Identification (for positive detections) Instrument Calibration and Performance Data A\ Initial Calibration Retention Time Summary y\ Initial Calibration Response Factor Summary Z7 Performance Evaluation Mix Summary y Continuing Calibration Verification Summary y C Analytical Run Sequence Summary / Z OPC Galibratteft-and Florisil Cartridge Check Summary y Pesticide/PCB Standards Quantitation Reports "X Pesticide/PCB Standards GC/EC Chromatograms Reagent and Instrument Blank Data y Organic Analysis Data Sheets 7\ Quantitation Reports X GC/EC Chromatograms y 4 - Pesticide/PCB Identification (for positive detections) ocp_l.doc 10141994 1032 Fonn OCP I J 300191 Matrix Spike Data y y Organic Analysis Data Sheets A7 Quantitation Reports y GC/EC Chromatograms Comments: ocp.l'lo' Form OCP 1.0 10141994 1032 1 300192 SPECMC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly presemd and received in good condition? y 7 ^ No Comments: Holding Times Were sample extractions performed within holding times? y y ^ No Were sample analyses perfogoied within holding times? yyz.?, J No Comments: ocp_l.dDC 10141994 1032 Fonn OCP 1.0 3 0 0 1 9 3 Initial Calibration Did the laboratory meet the guidelines regarding the minimum number of calibration standards for an acceptable initial calibration? ^____.^^ X Y C S X NO Were the calibration standards analyzed at the correct concentrations? TesA No Did the calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? fes) No Were retention time windows^ovided and correctiy calculated? y ^ y ^ y No Were peak resolutions acceptable? (^^7Z> No Comments: Individual Mix Standards (Continuing Calibration) Did the individual mix standards meet the linearity criteria for maximum percent difference (%D)? / J ^ No Did the individual mix staijdards meet the retention time criteria? /'Yesy No Comments: Fonn OCP 1.0 ocp_l.doc 10141994 1032 5 3 0 0 1 9 4 Performance Evaluation Mix Standards (Continuing Calibration) Did the performance evaluation mix standards meet the linearity criteria for maximum percent difference (%D)? (^^^s) No Did the performance evaluation mix standards meet the retention time criteria? ( f e s ) No Analytical Sequence Were standard and sample anises performed following the correct analytical sequence? / Y e / / No Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes ( ^ ^ If the spike recoveries were unacceptable, were the samples reanalyzed? Yes / m Comments: y i ^ ^ Ocp_! 10141994 1032 Form OCP 1.0 300195 Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in this sample delivery group (SDG)? c^zy No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Comments: Blank Analyses Were the appropriate number of blank analyses performed? / ^ ? No Were instrument blanks analyzed at the correct frequency? (^y^ No Were analytes reported in the blanks? Yes ( 1 ^ If analytes were reponed in the blanks, were the same analytes also reported in the associated investigative samples? Yes (No, Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes CMA Comments: Fonn OCP 1.0 ocp_l.doc 10141994 1032 7 300196 Instrument Performance Were the percent breakdowns for 4,4'-DDT and endrin correctiy reported? / Y ^ No Were the percent breakdowns for 4,4'-DDT and endrin within acceptance limits? (fes) No Comments: —" zzzy^z/7''^^ ^ . i % GPC and Florisil Cartridge Check Was GPC cleanup performed on the,s^ple extracts? Yes (^n/) Was the GPC column check acceptable? ^-^::=::^ Yes No f NA) Was a Rorisil cartridge check performed? fYes) No Was the Rorisil cartridge check acceptable? A ^ No NA ocp__l.doc 101419941032 Fonn OCP 1.0 300197 Laboratory Control Samples Were LCS analyses performed? Yes / ^ o ) Were the LCS recoveries within acceptable Imjits? Yes No ( ^ ^ y ) Sample Results Were target analytes reported in thejnyestigative samples? Yes C ^ ^ Were chromatograms provided for all target analytes reported in the investigative samples? (23) No Were chromatograms of acceptable quality and were analytes correctiy identified? (Z^A No Were the quantitated results for target analytes calculated using the appropriate standard and were the retention times (RTs) acceptable? CjJ^ No Comments: Fonn OCP 1.0 ocp_l.doc 10141994 1032 9 300198 Calculation Check Initial Calibration Retention Time Window: y \ ^ e ^ /y/,Zih<^ ^ B I ^ C ^ ( V ^ n o i ) ~ J Z 7 ^ to.-?-? - ' ^ - ^ 7 -iLtO-f %RSD: ^bO-Cov) ^ , i , ^ , y o - n . n -^'^^ , /o o'jjAyfzz7 ro^^o - ^'^o-^'^o ^ yt^A !Z\L f f r r r z ^ ^ 7 7 - ^.aJridUr- ^isoc^o &noddo ^ rd^^'° u7^3^^^ (^.^..-^ ^w Continuing Calibration ^ ^ ^ ^ ^ ^ ^ / / / / r / ^ ^ / 7 / ? (<;^ .r?^^ 5-?J) ^ - ^ - . ^ Z ^ / P / ' D ^ Z t ^ ^ - ^ . P , ^ ^ % , , ^ • ' ^ ^ ""T:^^^? >^/^o- 7.^7. Surrog^Rec^very ^ ^ ^ (^p ^ ^ , ^ ^ / ) / ^ ^ . . C O ^ % ^ . / . ^ % Matrix Spike Recovery '^ yA " " — T i / Z/y p •=- ^ - — r r ^ ^ p . ^ ^ ^ , , Fonn OCP 1.0 ocp_l.doc 10141994 1032 1 0 3 0 0 1 9 9 Sample Results prio;n ' I ' ' ' ' Ad^LisVy./ CRQL o-oi ut^fl X / S e t t l e ^t^Ui^c o.cffo L ^ = 0 0 , ( , ^ / ^ Positive Result: yy/i^_yyy^iytfA C P^7a^7y _ySViioz7 ^-ec-^yu^t^—lyi^C' yy ^./i^y^AA'^iA'Apo^yA^y I • jjjftzrjjL^ ocp_l.doc 10141994 1032 11 300200 HOLDING TIME QUALIHCATION SUMMARY FORM OJ o o IO o Sample Identification PT ni-0 fTiyiio ?T-lo^l Date Sampled h - ^ - 9 ¥ L Date Prepared //-f-P/ / I Date Analyzed l l - i ^ - ' i V j A Prep. Holding Time 5'td.^v s 1 y Analysis Holding Time T^cl t^-yS. y Qualifier yi/t^iyy -e. 1 . d Comments: ocp^l .doc 10141994 1032 12 Fenn OCP 1.0 INITIAL CALIBRATION QUALIHCATION SUMMARY FORM Date/Time Instrument Analyte . / ; n z - ^ ' " • RF ^ RSD yy Samples Affected ^ ' . Qualifier Comments: u> o o IO o to ccp_l .doc 10141994 1032 Fom OCP 1,0 13 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instrument Analyte A// A ' y - - ^ " ^ %D Al b^y^- ' Samples Affected Qualifier U) o o to o w Comments ocp_l.doc 10141994 1032 Fom OCP 1.0 14 BLANK SUMMARY FORM Blank ID Analyte Blank Result Units 5x Result Associated Samples Qualifier Comments: Ui o o to o ocfJAx 101419M 1032 Fom OCP 1.0 15 Summary and Conclusions ^ ^ - y - ^ ^ ' j i t r a v c (Kcc ^pjoi^lc •^\y ^Jg • Validator's Signature: < ^ ^ . ^ ^ ^ > ^ ^ ^ Vahdator's Initials: O A.y / Valida IZ^'lZ Validation Date: /^ / ; Y d ^ y y / f V r QC Reviewer's Signature: ^ T ^ y y * ^ T'- r y U Z y 1 Met j-i 0 V ych 1 Endrin ket Endrin ftId alpha-Chlo — g,5mma-Ch 1 o To K a ph e n e Aroclor-10 ftroclor-l£ flroclor-l£ Arocl 01^-1 £ Ar 0 c10 r-1 £ Aroclor-l£ -. Aroc 1 or-1 £ (Lindane) 1 t D 0 >• ide ! I 1 II 1 sulfate 1 or 1 one 1 e h V d e 1 rdane 1 rdane 1 16 1 £1 1 3 c! i 4£ 1 48 1 54 1 6 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 011 . 011 01 1 011 1 1 !U 1 ! U 1 !U 1 IU 1 0 1 1 1 U 1 . 01 1 IU 1 0 1 1 1 U 1 , 01 1 0£1 . 0£1 . 0£1 IU 1 iU 1 !U 1 IU 1 .0£11U 1 .0£11U 1 . 0£1 , 0£1 0. 11 . 0£i . 0£1 .011 IU 1 IU 1 IU 1 IU 1 iU ! IU 1 . 0 1 1 1 U 1 1. 1 0.£1 0. 43 IU 1 IU 1 IU 1 0. £ 1 i U 1 0.£1IU i 0.£1 IU 1 0.£11U 1 0. £1 IU 1 1 1 Reviewsd By Date /y/^Y-Z'^ FORM I PEST 300206 3 / 9 0 o30on7 l-iisnU t CD X b u P "A S H E L T PTl110 Lab Name: G S E L I Lab Code: PACE Case No. : HLA Matrix: (soil/water) WATER Sample wt/vol: 910.0 (g/mL) ML '/• Moisture: decanted: (Y/N) Contract: HLA SAS No.: SDG No.: 94195 Lab Sample ID: UNS001 Lab File ID: Extract i on: (SepF/Cont/Bone) Concentrated Extract Volume: In.jection yolume: 1. 00 (uL) GPC Cleanup: (Y/N) N CONT £000 (uL) pH: a.3 Date Received; 11/05/94 Date Extracted: 11/09/94 Date Analysed: 11/15/94 Dilution Factor: 1. 00 Sulfur Cleanup: (Y/N) N CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 319-84-6 319-85-7 319-86-6 58-69-9 76-44-B 309-00-£ 10£4-57-3— 959-98-8 60-57-1 7£-55-9 7£-£0-8 33£13-65-9- 72-54-6 1031-07-S— 50-£9-3 "/£—43—5 53494-70-5- 74£1-93-4— R "i iTl "^ — *7 A Cl 5103-74-E— 8001-35-2— 1£674-11-2- 1il04-£e-£- 11141-16-5- 53469-£l-9- l£67£-£9-b- 11097-69-1- 11096-82-5- alpha-BHC beta-BHC delta-BHC_ gamma—BHC Heptach1 or Aldrin Heptach1 or Endos ulfan Di eIdrin 4,4'-DDE Endrin Endosulfan 4,4'-DDD Endo!3 ul fan 4,4'-DDT Methoxych1 Endrin ket Endrin Aid ^ • l p - ^ - - ^ (~-i~T.- a1pha Lh i 0 gamma-Chlo T 0 X a ph e n e _ Aroclor-10 Aroclor-l£ Aroclor-12 Aroclor-12 Aroclor-i£ Aroclor-12 Aroclor-1£ (Lindane) t epoxide 1 I 1 II 1 sulfate 1 or 1 one 1 e h V d e ! rdane 1 rdane 1 16 1 £1 1 w'lZ.* 1 4£ 1 48 i 54 1 60 . j 0. 011 0. 01 1 0. 011 0. 011 0. 011 0. 011 0. 011 0. 011 0. 0£2 0. 022 0. 022 0. 022 0. 022 0. 022 0. 022 0. 11 0. 022 0. 022 0. 011 0, 01 1 1.1 0, 22 0. 44 0. 22 0. 22 0. £2 0. 2£ 0. £2 IU IU IU IU IU IU IU IU IU IU iU IU IU IU IU ly IU IU !U IU IU IU IU IU IU IU IU IU VALIDATED Reviewed By (l'-i i_ 12674-11-2 lll'04-£B-£ 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHC -delta-BHC -gamma-BHC -Hept act"i 1 or -Aldrin -Heptachlor -Endosulfan -Di eIdrin -4,4' -DDE -Endrin —Endosulfan -4, 4' -DDD -EindoEul fan -4,4'-DDT —Methoxych1 —Endrin ket -Endrin Aid -alpha-Ch10 -gamma-ChIc -Aroclor-10 -Aroclor-12 -Aroclor-1£ -Aroclor-l£ -Aroclor-12 -Aroclor-12 —Aroclor-12 (Lindane) 1 e D 0 X i d e 1 I 1 II 1 s u l f a t e ! OY" 1 one 1 e hi V d e 1 rdane 1 rdane 1 16 1 21 i ^'C! 1 42 1 46 1 54 1 60 1 01 1 011 01 1 011 011 011 011 011 022 0. 022 0. 022 0. 022 0. 022 0. 022 0. 022 0. 1 1 0. 022 0. 022 0. 011 0.011 1. 1 0. ££ 0. 44 0. 22 0. £2 0. ££ 0. 22 0. 22 IU IU IU IU IU IU IU IU IU !U IU IU IU IU IU IU IU IU IU IU IU IU IU !U IU IU IU IU VALIDATED Reviev.'ed By f?/flC FORM I PEST • Date 300208 U30024 3/90 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Semivolatile Organic Compound Analysis Case Number: Site: Contractor Lab: Validator: QC Reviewer: Sample Matrix: Analytical Method: 94195 Project Number: Island Chemical Company Pace Incorporated, New Orleans Kirsten Meier h.Pk.Allpj- Validation Date: Review Date: Water SW 846, Method 8270, Pyridine only 29872 10.1 January 6, 1995 //?/^r- Sample Designations: Client ID (Lab Sample ID) PT-1/110494 (UNS-001) PT-2/110494 (UNS-002) PT-102/110494 (UNS-003) Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Comments: The investigative samples were validated in accordance with the "USEPA CLP National Functional Guidelines for Organic Data Review", February 1994. 300209 boa_cVjc.n 12291994 1330 Form BNA 1.1 Cue Number: 94193 PiojectNunAer: 29872 10.1 Site ID: bbmd Cbendcal Company DATA COMPLETENESS CHECKLIST [x] Included, no problems [*] Included, problems [O] Not included [NA] Not applicable Quality Control Summary X Case Narrative * Surrogate Recovery Summary * MS/MSD Summary X Reagent Blank Summary X GC/MS Instrument Performance Summary Sample Data X Chain of Custody Forms * Holding Times * Organic Analysis Data Sheets X Quantitation Reports * Reconstructed Ion Chromatograms X Mass Spectra Printouts NA TIC Mass Spectra Library Searches Initial Calibration Data X Calibration Summary X Standards Quantitation Reports * Standards Reconstructed Ion Chromatograms Continuing Calibration Data X Calibration Summary X Standards Quantitation Reports * Standards Reconstructed Ion Chromatograms * Internal Standards Summary Instrument Performance Data * DFTPP Mass Spectra X Reconstructed Ion Chromatogram X DFTPP Mass Listings 300210 bna_clcc. 11 12291994 1530 2 ~>onn'BNA 1.1 ' Case Number: 94195 ProjeclNumber: 29872 10.1 Site ID; Isbusd Chemical Company Reagent Blank Data X Organic Analysis Data Sheets X Quantitation Reports * Reconstructed Ion Chromatograms X Mass Spectra Printouts NA TIC Mass Spectra Library Searches Matrix Spike and Matrix Spike Duplicate Data * Organic Analysis Data Sheets X Quantitation Reports * Reconstructed Ion Chromatograms Laboratory Control Sample NA Organic Analysis Data Sheets NA Quantitation Reports NA Reconstructed Ion Chromatograms NA Mass Spectra Printouts NA TIC Mass Spectra Library Searches Comments: The Reconstructed Ion Chromatograms showed peak areas from the scan 350 and higher, while the compound of interest. Pyridine, appears at aproximately scan 210. A visual comparison of data for Pyridine was not possible. 300211 biB_elcc.ll 12291994 1530 3 Fo™ BNA 1.1 Caae Number: 94193 ProjectNumber: 29872 10.1 Site ID: Isbmd Cbemicol Company SPECIFIC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? Yes[x] No Were custody transfers correctly and completely documented? Yes[x] No Comments: None Holding Times Were sample extractions performed within holding times? Yes[x] No Were sample analyses performed within holding times? Yes[x] No Comments: The associated matrix spike samples were extracted on 11-23-94, exceeding hold time by 12 days. No qualification of data. Instrument Tuning Did the instrument perfonnance checks meet acceptance criteria? Yes[x] No Were samples analyzed within the 12-hour period following an acceptable performance check? Yes[x] No Comments: Tune on 11/9/94,9:26:00: For obtaining the mass spectrum, the background subtraction included a small peak. The analyst should insure, that only baseline scans are used for background substractions. No qualification of data. Tune on 11/29/94, 13:42:00 : The baseline is not visible on the Ion Chromatogram. It is assumed, that it is identical to the x- coordinate of the chromatogram. No qualification of data. ^ ^ u 3 0 0 2 1 2 bna_clcc. 11 12291994 1530 4 — - » . ^ « . » T ^ rrr Caae Number: 94195 ProjectNvimber: 29872 lO.l Site ID: Island Chnnical Company Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration? Yes[x] No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yes[x] No Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes[x] No Comments: This review is only based on the evaluation of Pyridine. The initial calibration QC criteria were met for Pyridine. As stated previously, the chromatograms do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered or affected the quantitation of the target analyte,Pyridine, cannot be evaluated. The concentrations of the initial and continuing standards are listed in the header as twice as high as the concentrations used in the quantitation section of the data. The injection volume is not clearly defined, but appears, that the same amount of 1.0 ul was used for standards and samples. Since no detections of Pyridine were reported, no qualification of data is necessary. Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (%D)? Yes[x] No Did the continuing calibration meet the ininimum RRF criteria? Yes[x] No Comments: This review is only based on the evaluation of Pyridine. The continuing calibration QC criteria were . met for Pyridine. As stated previously, the chromatograms do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered or affected the quantitation of the target analyte^Pyridine, cannot be evaluated. 300213 biD_elee.ll 12^1994 1530 5 Form BNA 1.1 Cose Number: 94195 ProjectNumber: 29872 10.1 Site ID: kUnd Chemical Company Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes[x] No If the spike recoveries were unacceptable, were the samples reanalyzed? Yes No NA[x] Comments: The lab provided a summary of the surrogate recoveries and the recoveries were within the lab specific windows. The concentrations of the surrogates used were not provided and recalculation of data was not possible. No qualification of data. Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes[x] No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes[x] No Comments: The matrix spikes were performed with a 8270 mixture, which does not include Pyridine. The lab provided a summary of matrix spike recoveries, recoveries were within 8270 QC limits. The concentration of the added matrix spike solution was not provided and recalculation of the recoveries was not possible. No qualification of data. Internal Standards Were the internal standard areas and retention times within the required limits? Yes[x] No If the internal standard requirements were not met, were the samples reanalyzed? Yesx[x] No NA Comments: No internal standard area and retention time summaries were provided. The associated peak responses were compared and the QC criteria were met. No qualification of data. 300214 bna_clcc.ll 12291994 1530 6 F O T O B N A I - I Case Number: 94193 ProjectNumber: 29872 10.1 Site ID: Island Chemical Company Blank Analyses Were the appropriate number of blank analyses performed? Yes[x] No Were analytes detected in the blanks? Yes No[x] If analytes were detected in the blanks, were the same analytes detected in the associated investigative samples? Yes • No NA[x] Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes No[x] Conunents: This review is only based on the evaluation of Pyridine. The target analyte was not detected in the associated prep blanks and qualification of data was not necessary. Laboratory Control Samples Were laboratory control sample (LCS) analyses performed at the correct frequency? Yes No NA[x] Were the LCS recoveries within acceptable limits? Yes No NA[x] Comments: Not applicable. 300215 bna_clcc. 11 12291994 1530 7 Form BNA 1.1 Cose Number: 94195 ProjectNumber: 29872 10,1 Site ID; Island Cbemicol Company Sample Results Were target analytes reported in the investigative samples? Yes No[x] Were mass spectra provided for the target analytes detected in the investigative samples? Yes No NA[x] Were the mass spectra of acceptable quality and analytes correctly identified? Yes No NA[x] Were the quantitated results for target analytes calculated using the appropriate internal standards and were the relative retention times (RRTs) acceptable? Yes[x] No Comments: As stated previously, the chromatograms do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered with or affected the quantitation of the target analyte. Pyridine, cannot be evaluated. Therefore, the reported results for Pyridine in the investigative samples were qualified as estimated (I). Tentatively Identified Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? Yes No NA[x] Were non-target peaks evaluated as required? Yes No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes No Comments: Not applicable. 300216 bm_elec,ll 12291994 1530 8 Form BNA 1.1 Case Number: 94193 PiDJeaNumber: 29872 10.1 Site ID: Isbmd Chemical Compony Log Books Were sample preparations properly documented and performed in accordance with method protocols? Yes[x] No NA Were sample analyses properly documented and performed in accordance with method protocols? Yes[x] No Comments: None 300217 bna_clcc. 11 12291994 1530 9 Form BNA 1.1 • Case Number: 94193 ProjectNumber: 29872 10.1 Site ID: Island Chemical Conqiany Calculation Checks Instrument Tuning m/z of 127, 11/16/94, 11:20:00, BP111694D Relative Abundance: 864/1758x100% =49.147 Initial Calibration Std 50, 11/9/94, D5-Phenol RRF: 16823*20/10117/25=1.330 %RSD: 0.071/1.309*100% =5.422 Continuing Calibration Std 50, 11/16/94, Pyridine RRF: 10826*20/9825/25=0.882 %D: (0.918-O.882)/0.918*100% =3.922 Surrogate Recovery Concentration used unknown 300218 boa_etcc.ll 12291994 1530 1 0 Fonn BNA 1.1 Case Number: 94193 ProjectNumber: 29872 10.1 Site ID: Island Chemical Company Matrix Spike Recovery Concentration used unknown RPD: Sample Results CRQL: Water sample Detected Result: No detection TIC Result Not required 300219 boa_clcc.n 12291994 1530 1 1 Form BNA 1.1 Case Number: 94195 ProjectNumber: 29872 10.1 Site ID: Island Cbetiuoil Company HOLDING TIME QUALIHCATION SUMMARY FORM Sample Identification Date Sampled Date Prepared Date Analyzed Prep. Holding Time Analysis Holding Time Qualifier LO O O to to O Comments: None bi«_elec. 11 12291994 1530 12 Form BNA 1,1 Case Number: 94193 Pn^eclNwnbef. 19ST1 VO.I Site ID: Island Chemical Company INITIAL CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instrument Analyte RF RSD Samples Affected Qualifier Comments: None o o to to br«_clcc.l I 12291994 1530 13 Form BNA 1,1 Case Number: 94195 PitjjeclNumber: 29872 10,1 Site ID: Island Oiemical Company CONTINXnNG CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instrument Analyte \ RF %D Samples Affected r Qualifier o o to to to Comments: None hTU_eleo.I I 12291994 1530 14 Form BNA 1.1 Case Number: 94195 ProjectNumber: 29872 10.1 Site ID: bland Chemical Company BLANK SUMMARY FORM Blank ID Analyte • Blank Result (units) Action Level Associated Samples OJ o o to to t J Comments: None 1 btu cleu.l! 12291994 1530 15 Form BNA l.l Case Number: 94195 ProjectNumber: 29872 10.1 Site ID: Island Chemical t^otnpany Summary and Conclusions The analytical results for Pyridine are acceptable for use as qualified. The reported results for Pyridine in the investigative samples were qualified as estimated (J) since a visual comparison of the peak acquisition was not possible. Validator's Signature: I / J ^ W L t t u A - / Validator's Initials: JI p\ Validation Date: I - ( , - ' ^ 5 QC Reviewer's Signature: ^^yty-