9//JT (J I fc^ I DtC 9 1924 NEW YORK ACADEMY OF SCIENCES SCIENTIFIC SURVEY OF Porto Rico and the Virgin Islands VOLUME II—Part 2 The Geology of the Humacao District, Porto Rico— Charles K Fetike NEW YORK: Published by the Academy 1924 f NEW YORK ACADEMY OF SCIENCES SCIENTIFIC SURVEY OF Porto Rico and the Virgin Islands VOLUME II—Part 2 The Geology of the Humacao District, Porto Rico- Charles R. Fettke NEW YORK: Published by thk Academy 1924 THE GEOLOGY OF THE HUMACAO DISTRICT, PORTO RICO By Charles R. Fettke CONTENTS Page Introduction 118 Location of the district 118 Field work and acknowledgments ll{) Previous work 120 Physiograpliy 120 Upland area 121 The upper peneplain 125 Monadnocks 127 The lower peneplain 127 Caguas basin 128 Coastal area 129 Promontories 130 Playas 130 Drainage 133 General geology 134 Formations present 134 Older series .' 137 Tuffs and volcanic breccias 137 Andesites 142 Felsite 147 Limestones 148 Collores limestone 149 Tuffaceous limestones and calcareous tuffs 150 Shales 151 Sandstones 152 Intrusives in the older series 152 Intrusive sheets and sills 152 Stocks, bosses, and batholiths 153 Juncos gabbro 153 San Lorenzo quartz diorite 153 Yabucoa granite 159 Patillas quartz monzonite 161 Dikes 163 Siliceous dikes 1^3 Granite and granite pegmatite dikes 164 Aplite dikes 165 Granite and rhyolite porphyry dikes 165 Rhyolite 167 Dikes of intermediate and basic composition 167 (117) 118 SCIENTIFIC SURVEY OF PORTO RICO Page Latite and monzonite dikes 167 Dacite and quartz diorite dilves 168 Andesite and diorite dilves 168 Diabase dikes 170 Contact metamorphism 170 Hornblende schists and associated rocks 170 Metamorphosed limestone 176 Quartz diorite gneiss 178 Folding 179 Faulting 179 Alluvial deposits 179 Historical geology summary 181 Economic geology 184 Magnetite deposits 184 Road metal 194 Limestone 195 Brick clay 195 Kaolin , 195 Thermal springs 195 Bibliography 197 INTEODUCTIOlsr Location of the District The district described in this report covers an area of approximately 400 square miles in the extreme southeastern portion of Porto Eico. It has been arbitrarily bounded on the north by the parallel of 18° 15' north latitude and on the west by the meridian of 65° 5'' west longitude. The Caribbean Sea lies to the south and east. The district has been named after the town of Humacao, the capital of the Department of Humacao^ the southern half of which is included within the area de- scribed . Important towns along the coast, starting at the southwestern end, are Arroyo, Patillas, Maunabo, Yabucoa, Humacao, and Naguabo. Interior towns in the northern portion of the area are Caguas, San Lorenzo, Juncos, and Las Piedras. The interior portion of the district is a rugged mountainous area in which only small villages are located. Caguas, in the northwestern corner, is connected with San Juan, the capital of Porto Rico, by an electric and steam railroad. In 1916 constru^ction work -was under way to similarly connect Humacao with Caguas. The only other railroad lines in the district have been built along the playas and interior valleys to furnish transportation facilities from the sugar- cane fields to the centrals or sugar mills. These are of only light con- FETTKE, GEOLOGY OF THE HUMACAO DISTRICT 119 structioii and are not connected with one another. Good roads connect the coastal towns and those of the northern portion of the district, hut the interior is only accessible by native trails which have to be traversed on horseback or afoot. Field Work and Acknowledgments The geological survey of the Humacao district was made during the summer of 1916 under the auspices of the Kew York xVcademy of Sciences and the Insular Government of Porto Eico. Field work on the area was commenced on Jul}^ 8 and completed on Septeml)er 3. A map of the Island of Porto Kico, compiled by the Bureau of Public \¥orks of the Porto Eican Department of the Interior under the direc- tion of John A. Wilson, Commissioner of the Interior, and dated May 13, 1912, upon which the locations of the principal streams, roads, rail- roads, towns, and villages are shown, was available as a base. The charts of the United States Coast and Geodetic Survey, which accurately show the configuration of the coast^ were also used. In the southwestern corner of the district, the Arroyo-Patillas sheet of the Porto Rico Irrigation Service, drawn to a scale of , covers a small area in great detail. 12,000' ^ The various towns along the coast and in the northern portion of the district were used as headquarters as the work progressed. Pace and compass traverses were made along all of the roads and also along the greater portion of the coast, as well as along many of the trails which follow the principal valleys into the interior. Two north and south traverses were run across the eastern extension of the Sierra de Cayey in the western part of the district. On account of the limited time avail- able and the fact that much of the work was done during the rainy season, heavy tropical showers being encountered nearly every day, no attempt was made to sketch the topography. Seven hundred ninety-six rock specimens were collected during the course of the investigation, from 394 of which thin sections were later cut and examined under the microscope. All the data gathered have been assembled on a map drawn 1 to a scale of . 62,500 The office and petrographic work in connection with the preparation of this report has been carried on in the geological and mineraloglcal laboratories of the Carnegie Institute of Technology at Pittsburgh, Penn- sylvania. Its completion has been unduly delayed, first, by the entrance of the United States into the World War which attracted the writer's 120 SCIENTIFIC SURVEY OF PORTO RICO attention to other imperative calls, and later, by an investigation started at an earlier date for the Pennsylvania Bureau of Topographic and Geological Surve}^, for whose completion funds became available. The present investigation was undertaken at the suggestion of Pro- fessor Charles P. Berkey, of Columbia University, who furnished the writer with much valuable information derived from his own experience in making a reconnaissance survey of the Avhole island. Dr. E. T. Hodge, who had made a geological survey of the Coama-Guayama district, which adjoins the Humacao area on the west, during the previous summer, also gave helpful advice. The writer is also indebted to Colonel George E. Shanton, Chief of the Insular Police. The hearty co-operation of the insular police of the various towns of the district, obtained through his letter of introduction, did much toward facilitating the work. Eduardo Martinez, of Comerio Falls, acted as assistant and interpreter during the entire field season. His faithful and intelligent service was an important factor in enabling the field work to be brought to a successful completion within the limited time available. Previous Work Berkey's (1915) report on the general geology of Porto Eico, based upon a reconnaissance survey made by him and C. N. Fenner in 1914, was found an invaluable aid in carrying on detailed work in the Humacao area, and frequent reference to it was made in the field. Other articles dealing with the geology of Porto Eico, published prior to this, make only casual reference to the geology of the southeastern portion of the island and give very little information of a specific nature. A list of such articles is included in the bibliography attached to Berkey's paper. Since 1916, detailed reports on the geology of the San Juan (Semmes, 1919), Coamo-Guayama (Hodge, 1920), Ponce (Mitchell, 1922), and Lares (Hubbard, 1923) Districts and the Physiography of Porto Eico (Lobeck, 1922) have been published by the Kew York Academy of Sciences. The information contained in these has been very helpful in interpreting some of the data obtained on the geology of the Humacao district. PHYSIOGEAPHY The Humacao district, taken as a whole, has a mountainous aspect. It is a region of rugged relief. A considerable portion of the west cen- tral part is occupied by the eastern end of the Sierra de Cayey, some of wdiose peaks reach an elevation of 3000 feet. To the north lie the FHTTJ\h\ (U-:iHJ)rought about the developmeut of a tine textured topograpliy. Weathering nearly cvery- wduu-e has proceeded to consid'erable depths so tliat outcrops of tfie bed^ rock fomiatituis are scarce even in the extremely uiouotaiuoug portiims or tlH^» disti'ittt. except where the streams have eui througli the soil mantle, rroruineut talus slopes, so cluiracferistie of mouutainoiis regions wliere nujre rig(u'ous diuiates i)revail, are praetieally absent. Figure 1 shows the appearaiu-e of the ridge in the Sierra de Cayey wdd,cli ttmns tfie divide between tfie PatiUas and Del Flspiru^ draiu,ag<'S. Only in a few places along it do any outcrops of tfie underlying fornudi(»ns appear. 122 ,s('!EXTIFJ€ 8('in'MY OF PORTO HH'O (liemical dei-omposition Mather tliiui inccJiaiiicHl disinro^ixmiion, has lioeii tlio prevailing process of weathering. Rofk< likf> quiirtz diorite frtM|ueiitly sbow etelied surfaces, where the soil has been removed, .^iinihir to those oi"«li]iari;ly associated with the outcrops of more ^ohilde rocks such as limestone. Outcrops of quartz diorite affected in this luanni'jr appear in tig'unis 2, 3, and 4. As may be seen in fiofiire 2. the tiixuriaiit tropical Yegctation^ probably plays au imporliiut role in, llic devclupjuent (d' thcs<' wcatlicred surfaces widcli are so unusual for quartz cJioritc. \"cry tenaeiou,s (daytjy soils arc formi'd. Hteep slopes, ranginii' from ;>(> to do degrees with cuchillo or knife^ed,ge divides, are cbaraetcristic of —Oiiterop of qtnirtz dh tli(» mature topography de\-eloped, aiid the striking feature is tluit the soil clings to tliem ajul frequently tliey are under cultivation. Figure 5. taken near tlie headwatx:»rs of the Turaho lliver wdiere the l)edrock is largely an aiidesitie tuff, is typical y tlie surface run-o,tf wldcli flows along the depression started by tlie traffic over it. The steep walls on either side are very characteristic of the manner in which the residual soils of Forto tiico stand uji, Bcrkcy (191,5, p. :ii) b(d,ieves tliat the three ,factors tluit are largely FETTKK, CEiUJMlY Of THE HUMAiWd IUf a niiiiiininn, and ifie low (X)nt<>iit of hwrX or refractory materials, snoli as (jnartz, in tlie rock;^ ^^fc'lfttf&^Rfcin Fi<;. A.^^^-DetaU of (lutiHti hHuwh in figure 3 SCJEXTIFIV ISUEVEY OF IHilfTO RH'O wliuHC ll hrts furni^ihwl the soi'l^. Lt^hei-k (1!»22, ]>. /.OS) ihi,|iks that aiujtlier factor is ilie 9\\mi cliiratioii ix\\{\ 1i>rromi}il clinriu-tcr of tJu' riiiiifall whifh n-sults in ati execcHliiigiy hcavv and rapid nui-ojr ovi;r the surface of t'he iiiiperviuiis soil. Ill iny opiidoji, tlic ehariieter of the weatlu'rijig process iiiuler condi- tions such MS prevail in^ an extreiiiel_Y Jiunud ti'opieal climate, whieli Unii^-. :|iH.i)i n ciKii!ir:!l i!cMUnpositio!i r;il!h-i- Shan a mt tv ni-'-hiinicni diHn!c;M';nu^j: .:i ll,c *xp.is>.| vuik> iUid. u- a i-csuh. i>n>din-rv a ^crv FhTTKI'I, (IBOLOiiY Of THE IICMAVAO UJiSTRli'l' ia5 the behavior noted. Thi.> t^oil k not >iihjet*t to the action o1* frost which i.« mivh a potent factor in bringing rtbout shmiping in uokltn- climates. Its impervious imtnre vamei^ mueli of the rain whieli falk upon it to rmi off reaedrock forina^ irm Uidiic, a imrtUtii nf Jahiivun Hfunr tiojis along the divides, howev(»r, are of much more common occurKince in the region underlain by this rock. Tlic drainage system develfjped upoJi tlie upland area is of tlie typical dondritio type. In general it may l)e said that the character of the under]yin4' formations and tbcir structure bias had very little influence upon^ the directions iji which tlie streams lurw flow. Much of the area underlain by cpjartz diorite has been ^ worn to a somewhat lower level tlian those portions of the district in whieli in,du,rated volcanic tuffs and breccias and aJidesites constitute the bedrock. On tlie other liand, Panduras Kidge. sliowii in figure 1', wliic-h etuistitutcs one of the most imposing physiographic features along the soutliern coast, is underlain by (pnirtz diofite. TITK i:ri'KR FEX-EPLAIX Over mucb of the western portion of the u|)land area the c-m-u crest line, formed by the genera! aceordaiu-e of tlie snmmit levels of the in- numerable rido-es, is a particularly striking feature. Bucks, including SCfEX'llFie HVh'VEY OF POUTO RH'O jiuiiii-ulfcd ujii:tiiiJA: luilri iiiui bi:t:i-cja>, aJidu^ik-c. ijLUjrLz diuriu;;-, aihi irKtii;roximate]y from San Lorenzo to Yabueoa, On the north it is bounded h}- flie (Jaguas lowhuid and on the south it extends nearly to Pic. 0. ilattirelv Mssected upper peneplain in t'Mmty of Mulns barrio FF.TTKE, ah'OlJ'HJY OF THE HVMJflAO IHHTMICT 12T llif eoast. The cvfrn crest line prodnecMl hv thf erosion rt'Jiiiirtiits of thif> old ])»;'iiepJaiii t-au he Heoii in fiji,iir(;' S irbicli was taken liM)kin, taken in the vieinitv of Hulas barrio. In tiie eentral portion erf the area, this pejiephiiu level lias an eh:'vatiou of approixiniately 2(100 feet. , Xo distinet traees of it \xer(' reeognJzeil along the ,soiith.ern Hlo|)es oC tlie Lucpiillo niountairis within the limits of \h(^ Hnmaeao rlistrict. The peneplain (ieserihed al)Ove is iiiHloiibtedly the one wliieh Berkey (1015, ]). 50) recognlzetl in his reconnaissance study the upper one can be seen in figure 10, wliieli is: a view taken about 4 uiiles northwest of Yaliueoa lookiiiij uortliwest across tlie lower erosiou s^urface toward tlie upper which foririf^ the crest of tlie esear])meut neeii in tlie haekg-roaiHi Tliis Io\Yer }>enc- plain lies alwnt lOOO feet below the upper. ('A the background. The Cagnas basin is drained by the Turabo, De Espiuo, and Ciurabo Rivers wliicli mute to form the Grande de Loiza. The latter stream leaves the basin at its northwest corner where ir has cut a valley into thn upland area. The (jrande de Loiza and its tributaries have developed l)road flood piaijis ahmg tlieir courses which lie from ?M) to :iOO feet below the level of the lo^vland. Lol)ei'k (H)3S, p. Ml 8) belit-ves tlui4. the Caguas lowland was developed at the same time as tlie lower peneplain. It stamls at a scmiewluit lower VF.TTKH, (JHOLO'fjy OF THE HUMAVAO Dh^TRICT *#. .^, |^^:^'J ^;i^i( FUi. 12. -irwr. IM f/ic nrinihi «f Qiiebnula llomla fni.tit levi'], liowever, than the surface of tlii.s pwiepkiii rt.< <'U>vol()|)eo, also het-ween Yabneoa anxl i Candeh'ro |)hiyas, ('andtdero and -< irunja<'ao playas. ajul soidheast of '~ Xa,i;nabu. J In ijhu-es the headlands are I iiotclietl hy wlnit are |n-ot»abIy rem- :?, luuit- of marine terraces. Two I such terraces in tlic vicinity of '^ Qnehra{ier |)ene[>laiii level is readily recjogiiizaljle along the crests of ilie liills which, bor- in most cases tlie i)laYas •jiri' not ternnnated by any pro- nount-eil cliff along their sea- ward margins, one striking ex- ception was noted. Figure 17 sliows a cliff ,^5 feet high cut by the waves into the nnconstilidated playa deposits a] disti'i('t. The uppei' :> feet of the alluvial dei)Osit, as nuiv FETTKE, GEOLOGY OF THE HUMACAO DISTRICT 133 be seen in figure 18^ are extremely fossiliferoiis. Abundant shells of many recent species of gastropods^ pelecypods, as well as coral remains in every way identical with those accumulating along the present beach, are present. Indian pottery fragments occur in the lower portion of this fossiliferous horizon, which are associated with the shells in such a man- ner as to lead one to the conclusion that they were deposited contempo- raneously. The great variety of genera and species and the lateral extent of the shell bed seem to indicate that the deposit does not represent an Indian shell heap, but rather that there has been along this portion of the coast an uplift of from 35 to 30 feet since the region first became inhabitated by the early Indians. Draixage The northwestern one-third of the Humacao district is drained by the Gurabo, Valenciano^ Del Espino, and Turabo Kivers, tributaries of the Grande de Loiza which enters the Atlantic Ocean along the north coast east of San Juan. Some of the headwater tributaries of the La Plata, which enters the Atlantic west of San Juan, also rise within the western limits of the district. The rest of the area is drained by streams flowing southward and eastward into the Caribbean Sea. One of the outstanding features of the drainage is the unsymmetrical position of the divide between the streams which flow northward into the Atlantic and those that flow southward and southeast\yard into the Caribbean. As an example, the Del Espino Kiver, which rises on the northern slopes of the Sierra de Cayey, and its continuation, the Grande de Loiza Eiver, have a total lengtli of 36 miles, while the Patillas Eiver which rises on the southern slopes of the same range opposite it has a length of only 8 miles. Berkey (1915, pp. 39-41) and Mitchell (1922, pp. 266-269) have traced a prominent fault of late Tertiary age along the southern margin of the island extending from the vicinity of Juana Diaz to a point 5 miles east of Point Melones on the west coast. Accord- ing to Mitchell, the displacement in the vicinity of Juana Diaz is at least 900 feet and probably considerably more. The presence of this fault and the unsymmetrical arrangement of the drainage, as well as the comparatively abrupt manner in which the island is terminated at both the east and west ends, has led Berkey to conclude that Porto Eico is probably bounded roughly on three sides by faults (the east, west and south) and is a block tilted gently to the north. Tbis would exphxin the drainage phenomena noted. Lobek (1922, pp. 304-305), on the other hand, believes that the greater length of the streams flowing nortliward is due to the fact that the precipitation is much greater on that side of X34 SCIENTIFIC SURVEY OF PORTO RICO the island. He attributes the phenomena along the south coast^ ascribed by Berke}^ and Mitchell to indicate faulting, to be the result of the sag- ging and collapse of cavern roofs in the Tertiary limestones. If the unsymmetrical drainage is due entirely to differences in rainfall, how- ever, it is difficult to explain why the lofty Luquillo mountain group, with very short streams flowing northward to the sea, should be located in the extreme northeastern portion of the island where the rainfall is heaviest. The character of the rocks that underlie this area does not appear to be essentially different from those of the rest of the island. Stream terraces occur along most of the m-ajor valleys of the Humacao district. Particularly good ones may be seen along the Gurabo, Valen- ciano, Del Espino, and Turabo Elvers. In most instances these can be explained by the fact that the rivers have changed from aggrading to degrading streams within comparatively recent times and they do not necessaril}^ indicate that an uplift has taken place. GENERAL GEOLOGY The interpretation of the bedrock geology of a large portion of the Humacao district is difficult on account of the thick mantle of residual soil which covers most of it. In the lowlands, outcrops are extremely scarce; while in the mountainous areas, where they are more plentiful, they are frequently so badly decomposed as to make the determination of the exact nature of the original rock almost impossible. Pormational boundary lines can, therefore, in many instances be traced only ap- proximately. The best exposures are found along stream beds as shown in figure 19, along the cliffs which the waves have cut back into the headlands, along road cuts, and occasionally at or near the crests of the ridges. Often residual boulders in the thick mantle of soil furnish the only clues available in regard to the character of the underlying rock over large areas. The formations have been folded and invaded by numerous in- trusives, but strike and dip measurements can rarely be obtained on account of the massive character of most of the rocks involved and the scarcity of outcrops. Formations Present The oldest formations exposed in the Humacao district belong to what Berkey has called the Older Series. Berkey (1915, p. 10) considers the whole series to be of Cretaceous age, using the term to include both the Upper Cretaceous and Lower or Comanchean.^ Later workers in other ^ Op. cit., p. 58. FETTKI'I, UEOJAHJY OF TH!-J JIUMAAJAO DIKl'MH'T 135 parLs «tf Portxt Hico {-oDfur with him pretty well in tliis correlatioji.^ Se-iiiHies eonc'liuTos from foratniiiifcTal reiriains foiiruJ in the upper por- tion of the older series in the San Juan distriet, northwest iif tlie Hnma- i'-i 2 Bemmes, I». It. <}»>oI<>gy of the San .luan district. Scientific Siirvfy of Port© Mm and the Virgin Islands, Xew York Aciulemj of Science. Vol. I. Part 1. pp. T2-?S. Hodge. E. T. Geology of the Coatno-Guayamu distiict. Idem., I'ol. I, Part i, pp. Mltcliell, ih .T. Geology of the Ponce dlslrlct. Idem., Yol. I, I'art 3, pp. SSi-iSf.- Hiibbsircl. Bt-la. The geology of the l4ires district. Idem., Vol. II, Psirt 1, pp. S<-tS. 136 SCIENTIFIC SURVEY OF PORTO RICO cao area, that some beds of Eocene age may also be present. In the Coamo-Gnayama district which adjoins the Humacao on the west, Hodge has come to a similar conckision, basing his belief on a specimen of Venericardia alticosta and large numbers of foraminifera, radiolarians, and diatoms which he fonnd in its uppermost beds. He thinks that the lower portion is of Comanchean age. Mitchell and Hubbard, on the other hand, working in the western part of the island, found no evidence of Eocene sediments in the older series. All fossils discovered by them point toward an Upper Cretaceous age for the whole series. In the Humacao district, unfortunately the writer w^as not able to find any fossils that would throw further light upon this problem. The older series of southeastern Porto Kico are made up predominat- ingly of volcanic rocks. They consist chiefly of tuffs and andesites, the former predominating in the western half of the district and the latter in the eastern. The tuffs are largely andesitic in composition, but latite varieties are also present. In texture, some of them are sufficiently coarse to be classed as volcanic breccias. Others contain sufficient amounts of cal- careous material to be classified as calcareous tuffs and these sometimes grade into tuffaceous limestone. The andesites show a rather wide range in texture and mineralogical composition and include some dacites and latites. More siliceous felsites are also present over limited areas. Augite and hornblende andesites are of most frequent occurrence and a porphyritic texture is usually de- veloped in them. Both extrusive and intrusive types are undoubtedly represented but it is difficult to differentiate these in the field. In many instances, a parallel alignment of the plagioclase laths of the ground- mass, indicating a flowage structure, is revealed in them under the microscope. Sandstones, true shales, and limestones make up only a very minor portion of the older series in the Humacao district. On account of the scarcity of outcrops, the rapid alternation from one type of rock to another, both vertically and horizontally, and the com- plexity of structure, it was not found possible to subdivide the older series in the Huitiacao district into a number of distinct formations, such as has been attempted in some of the other districts. Much more detailed work, than was possible in the liriiited time at the writer's dis- posal, will have to be done to make such a subdivision Justifiable. The older series in southeastern Porto Eico has been cut by a great number of intrusive bodies of igneous rock. One of these, a quartz diorite batholith, underlies the major portion of the Humacao district. FETTKE, GEOLOGY OF THE HUMACAO DISTRICT 137 Smaller bodies in the form of stocks^, bosses^, intrusive sheets, and dikes, ranging in texture from granitoid to felsitic and in mineral composition from gabbro and augite andesite to granite and rhyolite, are also present. In many instances the areas covered by their outcrops are too small and too numerous to show on the geologic map. All of these intrusives are older than the oldest of the Tertiary beds that overlie the older series unconformably along the north and south coasts of the island as they are nowhere found to intersect them. The Tertiary limestones and shales, that are so extensively developed along the western portion of the north and south coasts of the island and which according to Hubbard (1923, p. 66) are of middle and upper Oligocene age, are absent from the Humacao district. The recent allu- vial deposits of the coastal playas and the flood plains and terraces of the interior valleys are the only representatives of Berkey's (1915, p. 10) "Younger Series" within the limits of the Humacao district. OLDER SERIES Tuffs and volcanic breccias—The formations of the older series in the Humacao district consist primarily of volcanic ashes, tuffs, and breccias of andesitic composition, tuffs being the most common. In the western half of the district the major portion is made up of materials of this character, while in the eastern part andesites predominate. As a rule, the fragmental igneous rocks are thoroughly indurated so that in many instances they resist weathering even better than some of the associated massive types. Over much of the area igneous rocks, also largely of andesitic compo- sition, are so intimately associated with the tuffs that separate mapping is impossible. On the geologic map, therefore, those areas in which the former predominate are indicated as being underlain by andesite; while those portions where the andesites constitute only minor portions of the formation are shown as tuff. It was not found possible to map the vol- canic ashes, tuffs, and breccias separately on account of their intimate association with one another. Gradations from one type to the other, both vertically and horizontally, are of too frequent occurrence. In the southwestern portion of the Humacao district in the area drained by the Llaunel Eiver, beds of consolidated ash alternate with tuff. Occasionally volcanic breccias are also present. A thin section cut from a greenish gray specimen of the latter type occurring near the head of the west fork proved to consist largely of fragments of andesite. These have a felsitic texture and consist of an interlocking mass of plagioclase laths with occasional phenocrysts of augite. Some have a trachytic type of groundmass developed in them. Chlorite and epidote 1:I8 SCIKNTlF/t' SL'h'VEY OF PORTft Uli'i) are the t;lut>f secondary minerals present;. The iiuilrix i-uii>isr.< largely of seeoriclary (|imrtz mid eiilorite. Microseopie exjmiiiiatioii of n speeimeii (jl)taiiied near the head of the east fork showed it to be a bitite tiiff. Oraiiis of orthnehise, pkgioelase, and aogite eaii l)e ideutilied in it. AJjuiulaut epidote has developed from an«-ite and feld>i)5ir, and hirgv iliuuitities of nceonchiry quartz as well a,s a littU* serieite are i)reHent in the matrix. The trdl's of tiie Patillas Hiver drainage north of th,(' reser- voir are also thoroughly indurated and much altered, (irains of plagio^ idase and ortli millimeters in diameter. Under the microscope they are seen, t« consist of andesites, varying in t(»xtnrc and ,number of phenocrysts as well as in t,l,ie degree of alteration which tliey srjKXTfFie BVh'VEY or porto rico Iiave uiMlfrgoBp, Host ut tliem contain plagioelase pheiioerysts wlricli in iHoiiie instance:^ have been largMily replac-t'd 'by .^ecoiidarv xtnre and traehytie strnctnre in them with occasional ptienocrvsts of plagioelase. i\fueli chlorite ami a little epidotc ami sericite liave developed as alteration prodncts. Fieyoiwl Iv. 40 \'ery uiiieli similar tuffs are exposed. The fragmen,ts of anisis vl minuTon.s grains of plagioelase, aiigite, and in'owu^ horuhleiule imbedded in a line matrix. ph <>{ hitili; fiiff Situtliirc miith f,f T()m:.o tltc ifetwait .V<( ]<]pidote has partially replacetl the fehlspar grains. Between Iv. 13 ami K. W, a small cpiarry has heeu opened in a tulfaeixnis limestone inter- bedded witli tJici aude.sitic tulfs. Altout 30 j'eet of the i'onner arc exposed. Soutliwest of the magnetite deposit, stmth of Torres, a'ttdii bed of latite tuf! occurs associated with daciies aud aiidesites, a ])hotoonero- grapli of which is shown in figure 23, It is composed of raggnni and 142 SCIENTIFIC SURVEY OF PORTO RICO rounded grains of plagioclase^ orthoclase, and a little augite imbedded in a fine matrix in which some pale green amphibole and chlorite caji be distinguished. A little magnetite is also present. In the eastern portion of the district the greatest area of predomi- natingly tuffaceous rocks lies to the north of the Humacao playa. Some of these consist of consolidated ash beds. Numerous grains of plagio- clase are usually present, some representing broken fragments while others are complete crystals. Small amounts of orthoclase and quartz also occur in them. In many instances the feldspar has been more or less completely altered to epidote, chlorite, calcite and sericite. The matrix, as a rule, is extremely fine and consists of sericite, kaolinite, and calcite—the latter often being very abundant. Coarser fragmental volcanic rocks are interbedded with the ashes. The fragments in almost every instance consist of andesitic material. Thoroughly indurated volcanic ashes of the hdlleflinta type, resembling those along the upper portion of the Turabo valley, also occur along the Santiago valley, north of Naguabo. Plagioclase grains and minute frag- ments of well-rounded andesite can be recognized in them under the microscope. Epidote and needle-like crystals of amphibole can be dis- tinguished in the fine matrix. Where the tuffs come in contact w4th the major intrusive of south- eastern Porto Rico, the San Lorenzo quartz diorite batholith, they are usually metamorphosed into hornblende schist. Similar changes have also taken place in them in the vicinity of the magnetite deposits of the Juncos-Torres region. These are described under contact metamorphism. Andesites.—Andesites rank next to the tuffs in order of abundance in the older series. They show a rather wide range in texture and miner- alogical composition and include some dacites and latites. Augite and hornblende varieties are of most frequent occurrence, but some that are largely fekl spathic in composition are also present. A porphyritic tex- ture is commonly developed in them. Both extrusive and intrusive types are undoubtedly represented but it is difficult to differentiate these in the field. In many instances a parallel alignment of the plagioclase laths of the groundmass, indicating a flowage structure, is revealed in them under the microscope. Andesites are almost everywhere associated with the tuffs, but on the geologic map an attempt has been made to show only the larger areas. Andesites crop out along the headwaters of the west fork of the Patillas Eiver along the southern slopes of the Sierra de Cayey. These range in texture from felsitic to porphyritic, the former type predomi- nating. When phenocrysts are present they consist of plagioclase. Feld- FKTTKH, ai':(flJH!Y OF THE JIL'.UACAO DWTHICT J 43 spar laths iii'<- the chi<'f constituents of the inatrix and m«Miietite is the moi^t important accessory mineral. Clilorite, sericiie, and imditc arc the pri,n('i|)al secondary minerals along witli occasional nests or hunclies of cpidote. Here and there tJie anxlesites are cut by vcinlets ol" secondary (juartz. Some pyritc has been jji trod, need. An andesite (sf the honi- hlcndic va.riety occurs on the ojtposite slopes of the Sierra de C'aycy, with an area of tuff intcrvcnin*;-. Plagioclase and a light green horTd>lende oecnr as phcnocrysls in it. The matrix consists chiefly "iidjimss con- nisting of an allotrioniorphie intergrowth of orthoelase and quartz. Orth, Flagioelast!. biotite, nuignetite, and apatite are pre>eiit m luiuor ac- cessories. Linie.HtoHe.i.-—True liiiiestones art; of comparatively raie ui-i-uj-reiice in the older scries of the Ihiinacao district. Those that were encountered during tbe course of the ])resi'nt investigation, had recryslallizcd to snob an^ extent that all traces of organic remains were oblitc-ratcd. Even in, these limestones, in sojne instances, small amounts of tull'aecoUH uui- FETTKE, (JFjOLOGY OF THE HUMACAO DISTRICT 149 terial can be detected. In manv cases the tuffaceoiis material predomi- nates so that the rock becomes a calcareous tiifr, which may in turn grade into an ordinary andesitic tuff. In still other instances, andesitic tuffs have been so completely altered to carbonate that they may readily be mistaken for true limestone. Collores limestone.—The most conspicuous outcrops of limestone ob- served in the Humacao district occur along two belts ; one of which be- gins 11/^ miles east of Juncos and extends S. 53° E. for a distance of about 6 miles. It has been called the Collores limestone on account of its typical development in the barrio of Collores de Piedras. The dip is toward the northeast and ranges from 32 to 41 degrees. The second Ijelt was traced for only a short distance. It lies about 7/10 of a mile nortli- east of the southeast end of the first and apparently dips toward the soutliwest, although the character of its outcrop is sucli as to make it impossible to determine this positively. This makes it appear that a syncline is present and that the two belts may be formed by outcrops of the same bed. xVlong the southwest belt, the best development of the limestone ap- pears in the barrio of Collores de Piedras. The limestone has a strike of X. 50° W. and dips 32° toward the northea(St. Prominent ledges of gray and white crystalline limestone, in some instances 40 feet thick, crop out. The total thickness is estimated to be 250 feet. A tlrin section of the crystalline gray limestone, a pliotomicrograpli of whicli is sliown in figure 2G, reveals an interlocking nu)saic of calcite crystals of medium texture with only occasional minute grains of iron oxide anu)ngst tluMu and a little chlorite. Qualitative analyses indicate a verv ])ure limestone. There is very little residue after treatment with cold dilute hydrocliloric acid and only slight amounts of iron and alumina and a trace of mag- nesium carbonate are present. In the vicinity of the magiu^tite deposit, whicli occurs in its upper portion, the limestone has been converted into an aggregate of calcite, garnet, pyroxene, chlorite, quartz, magnetite, and specular hematite. These clianges in the limestone are referred to again under contact metamorphism. At the northwest end of the belt, just southeast of the Juncos mag- netite deposit, the limestone has been completely metamorphosed into an aggregate of garnet, pyroxene, amphibole, epidote, clilorite, and talc. Only minor amonnts of calcite are still present in it. x\t the southeast end, 1500 feet northwest of the most southeasterly of the magnetite de- posits shown on the geological map, prominent ledges of white crystalline limestone can also be seen. Some garnet rock is associated with them. Along the northeast belt, outcrops of limestone were ol)served at only 150 .SCIEXTIF/C ^I'RVEV OF PORTO h'ICO one laertlity iiboiit 9/Hl of a mile south oC Torres, it is a dark gray, fine grained variety which litis not been nietrtinorphosecl to the extent that the linie^^tojie of the first belt has. Jn thin^ seetion, it is seen to consist prineipaJly of ealeite, hot occasional grains of (itiartz, angiie. and l^lagioclfisc are also present, Tbe lalter nndonbtedJy represent tntTaceoirs Mnitcrial lieposited .sijnnJtaiieoiisly with the ejileareons coostitiients, A few small grains of pyrite are also present. Figure "il' shows a photf)- niicrogra|)li of tliis limestone. Southeast of tliis limestone ahmg the strike, a pixnninent ledge of metamorphosed roek was noticed at one place, wtiieh, under tlie jnicroseope, was foiunl to consist ahnost entirely of an aggregate of garnet grains. A Jittic pale green amphihole and deep brown Iriotite occur betweciu tlie former. This rock apparently rep- resents metamorphosed portions of the limestone. TntTacerms limeston,e.s am] calcareous tiilts.— Sontlieast of I\. 12, along the Jnneos-Caguas roail northwest of the town of dnncos, a small h'HTTKK, ilFJUJtCY OF THE Hl'MAFAtt DlHTUIVT 1.31 qiiiiriT ha,s been opened in a tufrawous limestone iiiterl)e, form eonspieuous outcrops in the quartz diorite area. The highway lead- ing across i'nnduTas liidge from Mauriabo to Yahucoii nho aifonk exeei- e)it «)pportiinities to examine the quartz diorite at eloi^e range. A similar (juarty. diorite crops out abng the (luralio valley uortht'ast of Junc'os and als.-:.^d is! dm uini; '^^:AJ, (l<']}th with the main Saii Lorenzo batholith. Another similar but some- what smaller stock occurs in the vicinity of (Jaguas. ^!ucli smaller satel- litie stocks of from '^4 to % of a mile in diameter were ol)served along tlie cast fork of the Lbrunel Kiver, along the military road about '4 jniies soulliwest of Caguas, and about % mile east of tlu' main hathtilitb, east of Las I'iedras. I'luter tlie ml(!rosco|ie, the San Lorenzo quartz diorite is seen to he composed principally of plagioclase of an andesiue or acid lal>raflorite variet}', quartz, and a dark brownish -green liomble.nde. Orthoclase, hio- tite. occasionally augite, magnetite, tilanite, and apatite are the chief accessory constituents. The rock, as a rule, possesses a motleratcly coarse granitoid texture. This phase is by far the predtunimiting type, but sometimes (piart'K drops out almost entirely so that the rock her«l»l)n). Oeeasioiml'ly, in the case of tlie sinaUer satcllitiji stock!>, the texture m porphyritic. Figure -10 shows a ]jhotoiiiicrograpli of th.e (piartz dioritc from a spcei- men obtained from an mitf/rop .south of the Ban LorenKo-Las Fiedras roiu] al)out B^X. miles !>iout;lieast of tlie former town. Playioehi.se, quai'tx, and liornhleiid(! art; the iIhhh' chief constitnent.s present. The phigioehisu shows maAinium extijietioji angles of 25 degrees in seetiou!^ at right angles to the allute lamelhn and frequeiitlv exhibits pronoiun^ed zonal growtli. The liornblenth; is marl biotitc. An augite rliorite phase of the 8an Lm-enzo ipiartz diorite occurs ah>ng the nortliern slopes of J^^mduras Ridgt! abcuit 2 ndles t^ist of 'Yabucoa. Figure 31 shows a jdiotoinicrograjdi of this rock. Hornhhmde, plagio- clase, and augite are the principal constituents. The hornblende is in- tensely pleoehroic, ranging from yellowish brown through greenisli brown to brownish gri'cn. Tbe plagiochnse sliows maximum extinction angh's of 35 degrees in sections at. right angles to tlie albite bunelbn. The augite freepiently is enveloped l>y reaction rims of hornblemje. Basal 150 ,srlEXTIFI€ Sl'RVEY OF PORTO KIPO f^wtiouH of fiiiirite .sniTimiHletl by liorJihJt?ii(lt' may be seen iii tbiii heetioii, eadi witli lifi typical prisniiitic cleavage (levelopes in sections at right angles to the albite lamella?, and an, intensely ])leoebroic brownish green liornithi-mle. Quartz is only a Jiiinor ejuistitueuf.. Ttic other ac- cessory minerals are orthodase, biotite, magnetite, apatite, and titanite. A little sericite has developed from tlie fchlspar and chlorite and epidote from the hi<4.ite. One ,mile south of Humacao a gahbro phase occurs. Plagioelase ami aogite are its main c,-o,rnpoi]ents. The plagioclasc shows FHTTKE. (lEOJjmY OF THE II VMACAO IHBTRIOT 157 jiiHX 1111 mil I'xriiietioji angles itf -iSV, iU»«;ret'H in seeliuD.s sit right angle? t(> the albite himcliii'. The augiti; is a pale gTeenish-gniv iHiii-phwchroic variotj. Jt sometimes contains iiiternal growths of dark brownish green hoi-jibleinlc! in paraUel orientation with, one another, and is neeasionall}- sHrre»iinder aci'etrio)nor|)hic inforgrowth.s. Its aeeessory eniistitnents are [dagioelaHe. dark In'ouii hiotilf. ma^jiictite, and a]:nitite. Figure 3»i represents a photomicrograph of tln^ granit<=. In the vicinity of FraiU» Point tlie granite still has a very mueJj siinilar oompo.sition. A little zireon^ appears iji sections of t!ie rock from this locality. At I'atiUas Landing a mierographie intergrowth of orthoda^? a.nd quartz is a [)roininent feature in the roc-lv' which was nut noted else- wJiere. The coHrHe, aliriost pegmatitic Yabueoa granite 1 mile Jiortti- east oi" Las Pieilras consists largely of light pink ortlioelase and (piartz. }*lagioelase and hiotite are its cliief a('cessory mile in diameter. The lar(>"est of these intrusive bodies, that in tlie vicinity of the Patillas reservoir, however, is nearly 4 miles long and ha^ a maximum width of about 2 miles. Tn most instances plagioclase, orthnclase, hornblende, and quartz are the main constituents of the Patillas quartz monzonit'\ while maunetite, apatite, and titanite are the principal accessory minerals. Wliile the texture is usually granitoid, it is considerably finer tlian that develo])ed in the San T orenzo quartz diorite and Yabucoa izranite. Occasionally alon^T the borders of the larger stocks or throughout in tlr^ case of some of the smaller ones it is porphyritic. The Patillas quartz monzonite at the southeastern end of the stock, which occurs along the Patillas valley in the vicinity of tlu^ Patillas reservoir, is a fine granitoid dark greenish-grav rock in wliich feldspar, hornblende, and a little quartz are visible. In thin section the chief constituents are found to l)e orthoclase, pla^^ioclase, green pleochroic hornblende, and quartz. ^Maii'iietite is an abundant accessory mineral. Tlie feldspar is cloudy from tlie development of kaolinite and sericite. The hornblende has altered in part to epidote and chlorit^. Along the southern margins of the stock the texture is porphyritic. Phenocrysts ju^edominate over groundmass. They consist chiefly of plairioclase with maximum extinction angles of IS degrees in sections at rigbt angles to 1(32 SCIENTIFIC SURVEY OF PORTO RICO the albite laniell^e, indicating andesine, a ferromagnesian mineral now complete!}^ altered to epidote and chlorite, and a little orthoclase. The gronndmass consists of an allotriomorphic intergrowth of plagioclase, orthoclase, and quartz. Micrographic intergrowths of quartz and feld- spar are common. Considerable sericite has developed from the feldspar. At the northeastern end of the Patillas reservoir the rock possesses a fine granitoid texture. Plagioclase, ortlioclase, augite frequently sur- rounded by rims of green hornblende^ and quartz in part in micrographic intergrowth with orthoclase^, are the principal constituents. Magnetite in abundance and apatite are the accessory minerals. Considerable sericite and kaolinite as well as some chlorite have developed from the feldspar by alteration. The augite and hornblende have also in part been altered to chlorite and epidote. A small stock of the Patillas quartz monzonite on the west side of the Llaunel valley along the playa border consists of a fine granitoid gray rock in which feldspar, hornblende, and quartz are likewise visible. Under the microscope, plagioclase, orthoclase, quartz, and pale green hornblende are seen to be the important constituents. Almost colorless cores of augite surrounded by pale green hornblende are also present. The quartz occurs in part as micrographic intergrowths with the ortho- clase. Magnetite in abundance and apatite occur as accessory minerals. Some kaolinite and a little sericite have developed from the feldspar. The hornblende has partially altered to chlorite and epidote. The two small intrusive masses of Patillas quartz monzonite occurring 3 miles east of Juncos along the contact between the San Lorenzo batho- lith and the older series possess a porphyritic texture with phenocrysts in excess. The predominating minerals are plagioclase, orthoclase, and a dark greenish-brown hornblende. The groundmass is made up largely of feldspar and quartz occurring in part as micrographic intergrowths. Magnetite, apatite, and titanite are the principal accessory constituents. Abundant sericite has developed from feldspar. Small amounts of chlorite and epidote also occur in the rock as alteration products. The other areas of Patillas quartz monzonite, shown on the geologic map, are very similar in texture and mineralogical composition to those described. The relationship of the Patillas quartz monzonite to the Yabucoa granite is shown along the coast, 2 miles southeast of Patillas where their contact is exposed, as shown in figure 34. The rock at the left is the quartz monzonite and that at the right the granite. The point of the hammer rests upon the contact. The quartz monzonite 15 feet from the contact possesses a fine granitoid texture. Orthoclase, plagioclase, augite, FHTTKf], ilKOLOdY (JF THH HUMAVAff D/h'TIf/Cf and quartz are its inain C'onstitiunits. 8i>iTie of tlie ([oartz occurs in iiiicrograjiliic iiitergrowth with tlie orthoclase. A little green hornblende is prt'sent in the ftirni of reaction rims around the aogite. Magnetite, a|)atite, and tiititito an; acjcesaory minerals. Sericite has dev(!loped from ' felds^iinr, <,:Iilorite from augite, and a little eoidote occurs along minute fractnres in tln^ r resent. Y abucoa FETTKE, UEOLOCY OF TEE HEIIAXliO DIBTMICT Apliie cH/i'fts'.—ApJite dikes are of mucli more freiiuent oceiirreuee thai) the pegmatite varieties aiir! are not eoiiliiiecl to the Ban Loreiizu quartz diorite areas but also oeeiir in the YaI)iieoa granite, and in one place along the military road southwest of (^'agnas in tlie viein,ity tif K. 41, a 12-foot dike of tliis type eutsi a quartz moiizonite p«)rphyry that has been ecsrreiatcd witi) the Patilla^s. Figure o(» sliows a niuriher of aplite dikes eiitting the Yahueoa granite in^ thi^ vieinitj of Yahucoa Point. The majority of these dikes do not ex{;eed 1 foot in tliick:ncs.s and nsiially tliey are eonKiderably ill inner, lliey always possess a rather fine granitoid iextnre and are composed j»rim;i pally of otlio- elasc and quartz. Phigiochise, bio- tite, muHCovite, and nuigrietite are only very minor constitncnts. frinnHi'- imd rhyoUte porphyrij ilikf'S.—The granite and rhyolite porpli\i'y dikes are tlie most; aiinii- dant and important of the silieeous group. 'J'he two differ from one another onli^ in tln^ relative al)un- dau(;e of tlie phenocrysts present in them and the texture of tlieir gronndmasses. In the former phe- nocrysts predominate, while in the latter tin:' grcmndmass Is in excess. (»ranlte and rhyt)]ite porphyry dikes are rather widely distributed throughout the Humacao district. They eut the formations of the ohh-r series as well as the San Lorenzo (pnirtz diorite ami the yahn<'(ia granite, but were nowhere found iuterseetiog tlie Patillas quartz umnzonite. It is probable, thtsrefore, that they fotlowed closely after the intrusion of the former and before tln^ appesiranee of the latter. The granite and rhyolite porphyries ean tie studied to good yilvajilago in the vicinity of Yabueoa Point where their intrusive relaliou to the Yahucoa granite is well shown. The dikes of this locality consist of a liglitgray coarse i>or])hyritic rock in which, abundant euhedral as well as anhedral crystals of both orthoelase and <|uartz and oeeasional flakes of biotite are visibh^;. The phenocrysts of orthoelase fre(pn:«ntlv reach lengths H5a SClEXTIFiC PURVEY' OF I'ORTO RfVO of 2% and diameters of i% eentiiiieters. Tliey eoiisi^^t of simple crystals boiiJided I'y a prip]ii and basal and (•liiHH)i]uu-ojds, Carlsbad twin!:* with the same foriiiH dt'vylopod on tbcni may also be seen. TLie eidiedral crystals of (jnartz sometimes reach lengths of 2 eentimelers and diameters of 1.2. 'Fliey eoiisist of <-ombiinitions of the hexag'onal prism with the positive and negative rliombohedrons, t)ne instanee was jmted where two crystals occurred in parallel growth in the form known as scepter 'w/ritiih fif rhiinUl€ P'trphpi'n cutlintf l^ati Lot the ririiiitij of gnrhniiln Hoiflii PninI qnartz. Wliile iiumer(His plienocrysts (tf ciiiartz arc; enhedral, the nni- jority are rounded at lea.st at tire t-orners. j^liotite is not a etnispicuous^ eoustitucnt. ()ligoela«e, magnetite, titanite. and zircon are minor acces- sories- The gronndnirtss consists of a fine niosHie of ortlioclasc ami quartz. A little chlorite and epidotc Inivc developed from the biotite and serieite from the feldspar. A ])liot(nnicrograph of the rhyolite porphyry from a dike 3(1 feet thick eutting the San Lorenzo qnartz diorite in the vicinity of (^nelirada Honda FETTKE, GEOLOGY OF THE HUMACAO DISTRICT 167 Point is shown in figure 37. It possesses a coarse pornhyritic texture. The phenocrj'Sts consist of euhedral and anhedral orthoclase and quartz. The orthoclase occurs in simple crystals and as Carlsbad twins. Oliogo- clase and minute flakes of biotite are accessory constituents. The latter indicate a fiowage structure by their parallel alignment around the hirger phenocrysts. The groundmass is cryptocrystalline. A little sericite has developed from the feldspar and chlorite and epidote from the biotite. Several dikes of rhyolite porphyry, cutting a felsite, may l)e seen in a quarry for road rock ak)ng the west bank of the Patillas Eiver where the road from Patillas to Arroyo crosses it. The phenocrysts consist prin- cipally of orthoclase and quartz but the rock is particularly exceptional in that occasional small trapezohedrons of garnet up to 1 millimeter in diameter occur in it. Sometimes the garnets appear in the ground- mass but often they are present as inclusions in the orthoclase. Occa- sional plagioclase phenocrysts may also be seen. The groundmass con- sists of a fine allotriomorphic intergrow^th of orthoclase and (juartz. Sericite in abuiulance has developed from the feldspar. Bhyolite.—About 14 i^^^l^ "^^P ^^^^ Quebradillas valley from the military road southw^est of Caguas, a dike of rhyolite about 10 feet tliick occurs in the rocks of the older series. In thin section ouly occasional small phenocrysts of orthoclase are visilrle. The groundmass. which consists largely of orthoclase and quartz, is extremely tine. A little epidote and chlorite are present in it. Dikes of intermediate and htmc com position.—The dikes of this group range in mineralogical composition from latites and monzonites on tlie one hand to augite and andesites and diabase on the other, and ])ossess textures ranging from felsitic through porphyritic to granitoid, the felsitic and porphyritic types being the more common. They are encoun- tered most frequently in the older series, but are also abundant in tlie marginal portions of the San I^orenzo batholith and are occasionally present in the Yabucoa granite and Patillas quartz monzonite. While some of these dikes may be older thau the San Lorenzo quartz diorite, it is believed that the majority followed shortly after the intrusion of that rock. Latite and nionzonite dikes.—jyikes of the mineralogical composition of latite and monzonite wTre found cutting the older series, the San Lorenzo quartz diorite, and the Yabucoa granite. A latite dike about 20 feet thick cuts the volcanic breccias of the older series along the w^est fork of the Llaunel Eiver. IMacroscopically it is a dark gray almost black felsitic rock. I'nder the microscope a few phenocrysts of plagioclase and orthoclase may be ol)served. :Magnetite 168 SCIENTIFIC SURVEY OF PORTO RICO occurs as an accessory constituent. The groundmass is composed largely of minute interlocking feldspar crystals and a little augite. Southeast of Naguabo Playa^ latite and monzonite porphyries are present amongst the numerous dikes that cut the andesitic rocks of the older series in that vicinity. A thin section from a latite porphyry dike only 11/2 inches wide contains numerous phenocrysts of plagioclase, ortho- clase, and hornblende in an extremely fine crypto-crystalline groundmass. Biotite, quartz, and magnetite are accessory constituents. Flowage is indicated by the parallel alignment of the phenocrysts, particularly the smaller ones, x^ear by, a thicker dike of monzonite porphyry, with pheno- crysts predominating over groundmass, has almost an identical min- eralogical composition. In the vicinity of Quebrada Honda Point, a quartz monzonite porphyry dike only 8 inches wide cuts the San Lorenzo quartz diorite. Plagioclase of the andesine variety, orthoclase, microcline, quartz, and biotite are its prominent constituents. Magnetite, apatite and titanite occur in it as accessory minerals. Along the coast near Patillas Landing, a dike of latite porphyry, 20 feet thick, cuts the Yabucoa granite. The prenocrysts consist of ortho- clase and plagioclase of the oligoclase variety: The groundmass shows a spherulitic structure. Apatite is present as an accessory mineral. Chlorite, sericite, and epidote occur as alteration products. Da cite and quartz diorite dilces.—Dacite and quartz diorite dikes are not very abundant. Along the coast west of Kaguabo Playa, a dacite dike, 12 feet thick, intersects a felsite belonging to* the older series. In thin section, the rock shows a felsitic texture. Plagioclase and quartz can be identified in it. Chlorite, calcite, and epidote are present as alteration products. At one place along the Guayanes valley, a dike of quartz diorite porphyry, 3 feet thick, w^as found cutting the San Lorenzo quartz diorite. Labradorite, quartz, hornblende, and biotite are its predominating min- erals. Orthoclase, a little magnetite, and apatite occur as accessory constituents. Andesite and diorite dikes.—Dikes of andesitic composition are the ones most frequently encountered in the Humacao district. Hornblende and augite varieties are about equally abundant. They are mostly con- fined to the older series and the San Lorenzo quartz diorite, but instances were also noted where augite andesites cut the Yabucoa granite and the Patillas quartz monzonite. In texture they range from felsitic to porphyritic. A hornblende andesite porphyry with very prominent large crystals FETTKE, GEOLOGY OF THE HUMAGAO DISTRICT 169 of hornblende cuts the older series near the crest of the Sierra de Cayey at the head of the west fork of the Patillas Eiver. In thin section^ phenocrysts of greenish-brown hornblende and lesser amounts of plagio- clase are prominent. Magnetite is present as a minor accessory. The groundmass consists principally of plagioclase and hornblende. Some epidote has developed as an alteration product from the hornblende. Along the coast in the vicinity of Naguabo Playa, a hornblende ande- site dike, 3 feet thick, cuts andesitic rocks belonging to the older series. Its texture is felsitic and under the microscope the structure is seen to be diabasic, but bluish-green hornblende containing inclusions of biotite occupies the space between the plagioclase laths instead of augite. In the vicinity of Quebrada Honda Point, a felsitic hornblende andesite dike, 2 feet thick, cuts the San Lorenzo quartz diorite. A greenish-brown pleochroic hornblende and plagioclase are its chief constituents. Mag- netite is abundant. An occasional grain of augite and a little titanite are also present. A flowage structure is indicated by the parallel align- ment of the amphibole crystals. A 55-foot dike of augite andesite intersects the volcanic rocks of the older series along the Llaunel Kiver a short distance below the forks. It is a dark gray, almost black porphyritic rock in which phenocrysts of plagioclase and augite are visible. In thin section, plagioclase pheno- crysts of the labradorite variety are seen to predominate but pale brown- ish-green non-pleochroic crystals of augite are also prorninent. The groundmass contains abundant microlites of plagioclase. A little mag- netite is also present. Small amounts of sericite have developed from plagioclase and chlorite and calcite from augite. Near the northeastern end of the Patillas reservoir, a felsitic dike of augite andesite, 15 feet wide, cuts the San Lorenzo quartz diorite. Its chief constituents are plagioclase and augite. A little magnetite is also present. Some calcite, chlorite, and epidote have developed by altera- tion from the plagioclase. Along the coast not far from Patillas Landing, a 15-foot dike of augite andesite cuts the Yabucoa granite. It is felsitic in texture and plagioclase and augite are its main components. Magnetite occurs as a minor constituent. Some chlorite is present as an alteration product. On the point which projects into the Patillas reservoir at the east end of the dam, a dike of augite andesite cuts the Patillas quartz mon- zonite. It is a felsitic dark gray, almost black rock. Under the micro- scope, a few phenocrysts of labradorite felspar and augite are visible. The groundmass is made up largely of feldspar laths with augite inter- 170 SCIENTIFIC SURVEY OF PORTO RICO spersed between. Abundant magnetite also occurs in it. A little chlorite associated with augite and calcite are pr^ent as alteration products. A diorite porphyry dike, 2 feet thick, cuts the San Lorenzo quartz diorite in the vicinity of Quebrada Honda Point, as shown in figure 38. It consists chiefly of labradorite feldspar and hornblende. Orthoclase, magnetite, titanite, and apatite are minor accessory constituents. A little epidote has developed by alteration from the plagioclase. D'mhase dikes.—Only two occurrences of diabase dikes were noted in the Humacao district, in both of which the diabase cuts Patillas quartz monzonite stocks in the Llaunel valley region. The diabase ranges from fine granitoid to porphyritic in texture. Labradorite feldspar, frequently zonal, and a pale green non-pleochroic augite are its chief constituents, the latter filling the space between the feldspar laths. Magnetite and highly pleochroic brown biotite are the accessory minerals. CoxTxVCT Metamorphism Contact metamorphic plienomena in the older series are confined ])rin- cipally to the immediate vicinity of the San Lorenzo batholith. Tlie metamorphism has resulted largely in the conversion of the tuffs and associated andesites of the former into schists and gneisses, cliiefly of a hornblendic variety. This has been brought about by a recrystallization of the original constituents of the former and the development of ^ foliated structure in the resulting rock. Apparently, no new material has been added from the outside. The pressure exerted ])y the invading magma upon its w^alls as it was making room for itself appears to have been responsible for the development of the foliated structure. The schistosity everywhere is parallel to the contact. The conversion of portions of the Collores limestone into an aggregate of lime iron silicates is also believed to have been the result of the intru- sion of the quartz diorite magma of the San Lorenzo batholith, but in this case emanations from the magma itself reacted with the calcium carbonate of the limestone to produce the metamorphic minerals. In the vicinity of Yabucoa Playa, the intrusion of the Yabucoa granite has converted the San Lorenzo quartz diorite into a gneiss just as the invasion of the latter converted the tuffs and andesites into scliists. HORNBLENDE SCHISTS AND ASSOCIATED ROCKS The Maunabo Eiver, along a considerable portion of its course, fol- lows rather closely the contact of the San Lorenzo quartz diorite with the tuffs of the older series and the effects of this intrusive upon the FHTTKtL (lEOLOar OP THE HVMACAO lHHTh'li'T latter cau, therefore, lie .K of iiietHinoi'pliie rock appear about SU. m\\v< the town of MciiiiialM) ami eoiitimie at intervals for Jienrlv o niileH mil up HtroHin the imi Oulei'ops eiieoiinteri>(l jhk.h'ss h, dark ^niy color and line erystalline texture. The foliated ntrurture is imi very iiotieoahlo to the oakwl cje. Under the iiuVroHi'<»pe, the ruck \< nvn t<» crjiisisf of on iiiterloekino- luosair of au^u'ilt'. orthoelaso and a littic oiiartz. .Small 172 l-. A little further upstream plagioehise and a little Fig. 30. I'lioti Orth liornhlemlc also appear in the schist. About a mile above the first lo- eality, typical hornblende 'sctdsts make their appearance. TJiese also possess a tine to medium crystalling texture and show a slightly foliated strnetnj'e dne to rfie more or less parallel alignment oi the liornbleiide gi'aijis. In tldn seid'on, the ro(;k is foimd to consist of a mosa.ic of horn- blende, plagictelase. orthoclase, ami (piartz gj'ains. Sume magnetite is also present. "TIjc h. Hivcr and alou,^ the divide hctwccn that stream and Uh' Did I'^spin-. hhvcr. A dark .ya-ay line (awstallinc spctdnieii from iho hitter l..cnlii> I'xdiihitiim- a (h'stinetlv roliahnl striudiire wa^^ iunnd under the niiernsrup,. ii|. ed' alternate Imnds uf aimate. feld.spar and and lu.rnhhaide. The au-ite is nearly erincipally oi: pla.^lu(dase. urthoehi.M.. and rpjartz. Th.- hornldemle is a dark hrowninh-ea-een^ j.leeehmie variety. While its graJiis are al.Mi in more or less parallel alieannent alun-- eertain hands, patches of them do lint behavi. opti<-ally as units when viewed helween crossed nieh>ii(|(. <;it.vt.l<.|K-;iirt.--8an Lnreiizo yivm] lu.rtliwest of Sais J.uTenzo, in the vi<-inity of K. 8, rhe ineiiriijorpliit: hell is rtpproxiiiiatelv : ..f plagiu- ela«%"qnarte. and possihlv orthcchise. The foliated stru.'tnre is dvie to the mniUvl alignm.'ribf.<-L Toward tho soriihoaHt. tlie lungiu'titp ih'ixisit »-ast ol: .fiiiieos is ^w,^ (ioedcMl by a belt ol* niftrtiuorphic roek whieli is hi'liovecl to bavsto-|)(y fH-rhii};)s a toJTaeeous phase. Kii- rneroiis ytromiiieiit \(H\tiotitr. ,itiriss.^^^^^^An tlie vicinity of Valiurlay«. the Hiiii Lorenzo (jiifirtz diorite lias heoii eoiiverted iiitu a giiei-s by 1Ih> ii)fri!si(»i) of the Yahueoa u-ranite. The mieiss itself Is mi hv imiiierons totii.'-ue!> of the eoarw Yahiieoii granite and l)y aplite diken. The reek posses.^eri a mr'iliiiiu t-rystalliiie texture and n green ish-g-ray <:olor. It Hhn\v.< a din- tiiuily giH.i.! >, pally of ])higieelas(\, qnartz. some *)rth(iehise, and brown ish-greeij horn- hh-nde. ::\!a^uing from the FliTTixi:. CFJHJKIY hF '111 F. fK^h'ACU) FHSTh'ICT ^•ii»H)<'lH uiiv Vn,-H> ilo|)n. with the (>x|Kisiiri' ill fi.mm. d:. ivliii-li ui-i-ur^ =i|.u!..- P,..,., |»nl>,v Cn-ok. i!' "^ ' ^ ;' . ^ ': -^"Tf^$^^^4 ^If^. ^, fH ii-^m^ -#::. _,, iKPl. -w : ' " -ji^- ''^ :^'^'' iiiil :V ;: »J ' T .:.,. ' • > '* "• 1 "'. ' . >:!^ . 3-2»'li •». .'HSi'iUiallv vuui;-^ from a uvnl, 'nni- <;l til lluiuarnt. .Ifstrirl; mIim'UII. While )M, U,y.ii tliere is a {)ossil)iIity that a |)ortion of the ]o\\"er ])art may be lower Cretact'oiis in age and sonu' Eocene sediments may he included in its up[)erinost niem!)ers. During Cretaceous times, Porto Rico was the scene of intense volcanic acti\ity, largely of the ex[)losive type. Enormous (juantities of frag- mental material were extruded, cliiefly of an andesiti(^ character, that ]»uilt u]) the great beds of volcanic tuffs ami breccias that now comprise the major portion of the ohUu; scries of tlie Humacao district. A por- tion of the eruptions, liowe\er, was of a quieter ty])e and resulted in the Java flows, also largely andesitic. that are interbeddtMl with the frag- mental rocks. I^ot all of tlie latter, liowever, readied tfie surface, as some are clearly of an intrusive cliaracter, having forced themselves as slieets and sills amongst tfie layers of tuif and breccia extruded by ])revi- ous eruptions. ]\luch of this volcanic del)ris, ]>er]ia])s the major portion of it. un(h)ubt- edly accumulated under sub-aerial conditions. Tlie oecurr<'nce of occa- sional beds of limesto]u\ such as the (N)llores, interstratihed with the volcam'c rocks, however, indicates that the district did ]H)t stand above sea-level throughout the (*retaceous |)eriod, but that oscillation with res|)ect to sea-le\el took place from time to tinu\ which resulted in at least j)artial sul)mergence of the area at iirtervals. Toward the close of the Cretaceous, a general uplift took place which was accompanied by the folding of tlie volcanic and a^soeiatsMl sedinuui- tary rocks tliat comprise the older series. Fresh accessions of magmatic material appeared which invaded the Cretaceous formations, and in the Humacao district resulted in the formation of the San Lorenzo batholith and the Luquillo and Caguas stocks. AMiile practi(^ally all of the volcanic^ rocks, both massivf^ and f rag- mental, are either amlesites or closely related types, the later intrusions sliow a nmch wider range in chemical and mineralogical composition. Ap])arently, the primary magnuis from which the various igneous rocks of the llumac^ao district ha\e betvn derived were of an amh^^itic or dioritic character. During the earlier stages of igneous activity. wIkmi cf)mpa ra- ti vely ive(' commum'cation with the sivrfacH^ pr(nailed, s'crv little differ- entiation occurred in this magma. Later on, however, wIkui new acces- sions of igneous material bceanu' largely of an intrusive chara(^ter. such differentiation did take ])lac(>. As a result, (]uartz (lio!'it(\s are followed by granites ami quartz nionzonites in the form of batholith^ and stocks. Firi'TK/j, aiu>L(>(;y of Tin: hi wiacao Dh^TRjcr iSo The (like rocks aceoiii])aiiyiiig' this [Period oi' io-neous activity show ev(vu greater variation, ranging all the way from aplites and granite pegma- tites at the one (extreme to diabase at the other. The diabase dikes that are occasionally founng ])ortions of the eoast also exist in the form of wave cut terraees, raised ])eaehes, and eliffs ent into I'lHHMit ])laYa de|)0sits containing marine fossils. K(^()X()MJ(^ (;F.()LO(iY A]A(JX!7riTK I) K POSITS Magnetite deposits that liave attracted some attcMdion as possihie future sources of iron ore occur at a nund)er of localities in ihe ohhu" series of tlie llumacao district. The ])rincipal {)n(\^, which have ah-eady heen descrihed hy the writer in a })revious |)aper (Fettke, 1i>*^4) oeeur in association with the l)elt of ('(dlores limestone, trending approximately S. 5:]° E. wlneli l)egins It^ nndes east of J uncos and can he traced for a distanee of al)()ut (> nn'les toward the coast. Four outcrops of magnetit*^ were ot)ser\e(l along it. whicli are designated as Xos. 1, 2, i), and I, respectively, starting at tlie northwestern end ou tli(* ge()l()gi('al map accompanying tliis report. Otliers are j)rol)ah]Y present hut (^sca])e(l notice on account of t!ie thick mantle of resi^ there are jio fuels availahle in I'orto KNco for the estahlish- nient of a local iron industry, the ores, if ex{)loited, will ha\'e to !)e shippcMl. The two nearest harhors at which shi{)])ing facilities are at pi'es(Mit avail- ahle are San duan and Fajardo Playa. Of these, San duan is hv far the l)ettei'. By way of the (Uiraho and Iiio Orande (h Eoiza vallev, the d uncos dej)osit is .'U miles distant from San duan. The electric and narrow gange steam railroad from San ehian to Oaguas covers tlie dis- tance to the mouth of the Ouraho lii\er. From there it is 10 ndles ui) tl)e ijuraho vallev to the magnetite deposit. Along the greater portion of the latter distance a light Jiarrow gauge track has alreadv heen eon- F/JTTKfJ, (UJOIJXjy OF THN III MACAO DISTRK'T IS5 sti'iu-ted for the transportation of siio-ar cane from the fields to the central '%) uncos." Bv way of the Jieadvvaters of the (xural)O Kiver, across the divide to the Rio Blanco valley, down it to Xagiiabo, and thence [)arallel to the coast to Fajardo Playa, the distance is al)out 27 miles. Ensenada Honda, p,,; 4s. h'clat'ioi) of wdffnctifc outcrop \o. 1 to ^urroundinn foniinf iou.^ Houth of I^Vjar(h) Ilarhor, is T ndles nearer, hut no shij)))ino- facilities are at })res(Mit availahle. Along all hut the iirst 1) miles of this distance light narrow gange tracks are already in existence h)r tlu^ liauling of cane. T\w onlv stec}) grades along this route occur after leaning the lu^ad- waters of the Guraho Biver and going down Pena ro])re (h-eek, a trif)u- tarv of the Bio Illanco. Along this tlie hanl would he down grade. TUv mniiuvtilv tli-|H, vaJlev. that rise- appruxi^ rtivly :JM feel above the h.wlaiuis h> the iioiih ami >ova\\. 'Fipir.. 4H .nsistv uf ii >k.-.u.h inai), lja>«Hl ii|Hai lielil iiote^. whirh a plinto^a-aph t.f the rid-e as it appeiiiv from tlio s.mili lonkino^ north. The oiitfrnp has a strike of \. (id ' \\\ and apparent I v s('sth snurll ananijit.s of snlphides are proi.alily |n-eseui in associatitai with ihe nu-i.y- netda-. thirnet (teenrs with the uia<:iH'tite at the ivesl end oC ihe de|)osit. ruder the niierosenpe. it exldhd,s pruu.uuiiee«l opiieal araanalies and <:ranp1e-x twuriin.ii-. A little lihrous auiphihole has hecni huine.l frojn it by Ft:'l''l KL\ epidorc t.. I..- the piviUnmw.mi miin'ral willi which ihc nin^mici itc is associaietL i.m s^ihmII pati-lu's i,f y'linicf nrv rilsf. |ir.'.-wit. M.^iirc :.(i is si phnioiiiit-rugriVph that of iiui-iHi!t" an. I t'pidnk'. >;uv.>(>.h.il hv a (.f hf ro!IlMH'>: rnorphir r.uk ivhirh i> Ih-Hi'v.-I h. h.ave limc*ti>nc. pi-riiap^ ii 1ufrai-cou> jihan'. X out along thv hWhuU'. A I niii. phicMihoi iho strike; IK N. ;ir^ W. aiHi thr .lip :iN-^ X. K. I.arc.' vug.* ocrur it A iin(T..H-..pii- cvaiuiiialicu of ih.- au.l -arn..t. the s.niriH-t ha pill ftM't brvr.llil Ih mcteiuoi'pr.csc! '.<'<-^ m !'" rcvoalH that it >-un P..v,.lupM-.I along unnuU- frai developed prc.«.irt i iss srft:\'nFH' ss(i,'ri-:y of I'oirro uir tuivs. AiH.tlier hiHH-iim.)i i;ik,.ii from tin- walls of uiii. ..f thv vui^h mnmnU hiruvlv ul* --aniet anJ ampliiholo with soim. U\\v. Thv -;:.ri!=.f Hiipiirenlly luniuMl first. Ihcn tiu' Hinpiiihul,., aiul liiiiilly the Inlr, llnnihleiule ainl pyrr.wuv .-.rhi.-^rs iiiHloul.tc.lly denv,..! irnii! luidcKiKi lu!l>, t.vi'riic and iiiiil(»rlic the nu'lamorpluKsed linicsloiu'. A tiiin scrtioji of a ,-4jH-riinen uhtaiiied from aln-v*' tii<> Jiiupstoin^ |h.^.m'>^-=i'- n iliHliucidy fnliatcrl >tructuiv. Ir i< iinde up cidctiy of pla-KHda.^i-. .|narf7., oiilai- cla-u, and a dci'j. .uavcu hoi uiilcudc. A little pymxv^iv ir~ al>u |. resold. I I I LJ^_J Fill' (.iitliiu's of a few ono-inal lVld..par .'ryslals. lanv ri,iH|d,.-i('l v altered pinanHni taken frem I (MHid seme dislanee h..|(.u th.. liinestene alse in^<^v^^v. a sehi>tiw a|.- H-aranee. It is eompused ef an interhjeking^ nu.saie of pale lim^n »yruxeiu-, pda.--iuelar^e. enlioelase. and a lillle dark ,Haver= hiH-nhlende. A .eu larse ervstals uf pvri.xene full ef inrhisien^. inrludijiu^ smaller FfJTTK/'], aiJ()L()(JV OF THIJ HI MACAO DISTRICT IH!> pyroxene lagio(dase. It is coarse in tc>xture. :\ little magnetite and apatite^ are pi'esent. The J uncos deposit lies af)out 2J){)i) feet north of the San Loi'cnzo (juartz diorite hatholith. An olf-shoot of the latter, which is pai't of the Lu(piillo stock, crops out 500 t'eei north of ihe magni^ite occuri'cnce. The magnetite i'<>h- al)ly a calcareous one. North of the tut! along the crest of the ridge, an augite andesite crops out. This iuis a felsitic fexture. Under tlie microscope, the plagioclase laths of the groundmass are seen to he in more or less parallel align- ment, indicating a flowage structure. A few hirge phenocrysts of augite can still he recognized. Dthers have been altered into aggregates of cpif Xo. 2, while it does not make a xery conspicuous show- ing at the siirface, is of considerable interest because the relationship of ihe magnetite and contact metamorphic minerals associated with it to the Coheres limestone is brought out more clearly tlian at any of the other localities. The magnetite associated with the metamorphosed lime- stone occurs very near the top of a nortli west-southeast ridge. Numercms outcroj>s of nearly jiure crystalline light gray and white limestone api)ear on the southwest iiank of this ridge. The strike of the formations is X. 54 "" \y. and tlie dip is :)2° N. E. It is estiuiated that the limestone has a thickness of at least 250 feet. A small qnarry has been opened in it at one place from which limestone has been taken for burning into lime for local use. Qualitative analyses of tlie limestone indicate that it sfiould yield a good grade of lime. A thin section of the crystalline gray limestone below tlie magnetite, rcNcals an interlocking mosaic of calcite crystals of medium texture with only occasional minute grains of iron oxide amongst them and a xei'Y little clilorite. A specimen of the metamorphosed limestone from the hanging wall of the deposit is composed of garnet^, pyi'oxene, and calcite—garnet being the most abundant. Garnet seems to have devel- op(?d somewhat later than pyroxene, and some of tfie calcite in the form of little veinlets cuts all three. Northwest of the deposit proper, promi- luMit ledges crop out that range in mineral composition all the way from crystalline calcite associated with only small amounts of silicates, to those in whicli silicates are the predominant constituents present. A thin section of the least altered rock consists mostly of calcite and a little FJJTTKE, (iEOLOay OF THl] lUMAC \0 Dh^TRK'T \\)\ garnet intersected by fractures along which quartz, specular hematite, and possibly magnetite have been introdnced, replacing tlie calcite. This was followed by the devek)pment of chlorite along fractures and between c-alcite grains^ replacing the latter in part. The final stage was the depositicm of later calcite in the forju of minute veinlets cuttijig the other minerals. The limestone is overlain by an andesite at locality Xo. ;] and under- lain by a metamorphosed and much altered andesite tnlf. The magnetite (h'])osit occurs in the upper portion of the limestone just below its con- tact with the overlying andesite. Tlie San J.orenzo batholith lies al)out V;^ mile to the southwest. The outcrop of the magnetite' deposit at locality Xo. 4 occupies neai'ly the entire crest of a hill about V/U ndles southeast of Xo, -"h It lias a length of nearly 200 feet and a maximum wi(hh of 80 feet at the western en(L At this end scmie coarse inicaceous hematite, associated with (piartz, as well as massive magnetite, are present. The outcrop^ wliile not very large in area, makes a V(^ry prominent showing. (Ireat boulder^ of massive magnetite derived from it are strewn along the hillside to tho south and have accumulated in tlie little \alley at the }>ase. A feldspathic andesite comprises the iiajiging wall of tlic de|K)sit. In fhiji section, it is seen to possess a felsitic texture and distinct fiowag<' structure, brought out by the parallel alignment of the iplagioclase latlis, A few phenocrysts of plagioclase and a light green ]iornl)lcnde (hn'ived possibly from augite are present. Occasional aggregates of epidote also occur. The matrix consists predominatingly of ])lagioclas(^ laths in more or less parallel alignment. Skeleton crystals of iron oxide, possibly magnetite, are prominent. A little hornblende is also pr(\ liia.uiiotitc i)rus^ |iiM-t. u! (.'h'\atii«ii. <.iin-rn|)> of !iini'>toiH> aro cxposiMl. one Icdgv luiving a thickiies> ul" 1(1 ftH-r. Oil acroiiiir of the mussivp t-luiractor ol' the rock, no sf.rik*^ am! dip lueasuivnu'iit^ on tlic liiiH':^toiu« ilstdf wvrv pos^hh'. It: is ovt-rhiiiu liowev»«r. I»y an nuu'ilc aiidositx', ^howiiij^- tlowagf si nu-iuri' imdor the !rii two is X. is" W. and the dip :>'>'' S. W. This makes it appear thai a svnelinc rcrur^ hefwcen tlic depo^it^ of Xos. I and 5 and that the limestone at lr(^alilv Xo. o may In- the sanu' hed that the other four diiinsits areas^^ociat-'d with. W^^-o.*... ;*c^i A jiiirru-copic .'xainination of the limestmic reveal> a rather Hne^^ u-rained rock composed chiefly of an iiiterlockiii.u- jnnsiiie ol' calcite erys^ tals with occasional -rains of quartz, aviu'ite. aJid pla-iochise distrihulet! mnon-sf them. The latter undcnl.tedlv represent tulTacemis .materia! deposited contemporaneously with the ealean-ous constil ueiits. On.' hun- tired and seventv feet >outheast of ilie lunestone outcrops alon.u' the Inlh^ side a proniment. Icd.u^e of inunwi rock, dev.dopi'd from the limest.aie. was nol u-ed. The ^irnet, which is appareiilly an antlradttc variety. sho\v< hirefrineence and is np|icall\- nepitive. It was at (irst nustakeu for \a'su\danite in thin section, fmt posse»cs a liigher ind(>.\ of rtdd-action than the hitler inin DISTRICT YX\ (i()in<>- in the (lirectioii of dij), augite aiidesite and latite occur between the liniestoiie and magnetite (mte structure. The wall rocks of the maixnetite d(^|)osit itself are not exposed. A latite tuif ovcudies tlie nui.u'uetite, but it was not o})served iu direct contact with it. Tins in turn is succeeded by dacites and andesites toward the soutbwest. Tbe magnetite deposit lies IV:^ miles n(U'tlieast of the San Lorenzo batbolitb contact and l-/;; miles southeast of the lAKjuillo stock. The maguetite de|)osits described are cl(>arly of tlie type ordinarily termed contact metamor])hic deposits. In eacli case tbey [)oss(\>^s mineral associations and oc^-ur in such relation to the sun-ouinling rocks as to lead one to conclude that they have been formed by the re])lacement at high tem])eratures and ])ressures of either a nearly pui'e limestone, a tulfaceous lim(\stone, or a calcareous tuff. A study of ti\(^ geology oi' southeastern ]\u"to Hico leads one to tbe conclusion tbat tlu^ magma, wbich gave rise to the Saj] I^orenzo (puirtz diorit<^ batbolitb, as well as the Lufiuillo and other smaller satellitic stocks, and from wliicli tbe later intrusions that surr(uind, and in soim^ instances penetrat(> tlie (piartz diorite, were derived l)y magmatic differentiation, was also responsible for tbe (mianations tbat formed the magnetite deposits in tbe luiu'e cal- careous portions of the older series of eastern Porto liico. Tiic pi'oximity (d' the San Ijorenzo batbolitb and tbe liUipiillo stock, as wtdl as sniallci* olfsboots, to the magnetite deposits, indicates tbat tbe . nil rhe utlipr hnii.l, .'inaiirtt iojis hum the inii.i;-i!ui itself ii!frO(lu(-'0(! Inruv annmiits .if iniii.Tiil matter, eoiisistiu-' vhwih uf silica and iron o.\i in rho ininKMliafe vieinity r.f tdie ininisivc imlil thiw eariie m idrti;cs wh./re llie rra.1iin>< inrcr.^eried the m-arhy hiiiestuKes Hud (^dc^aroous tulfs. The htun: r.- aeted wifli th." Ierru-siliee..ii,'< cmannt iuii^ miwh im.rp rea>ire>aiid nrdiiuirv tiul'^ with whirh thev are iiitaa-hefhled and re|d,a«-.- th- IwlT *.ki-^- " "' 3%g iruii ore deposits ihiavrnre. the bells alonjr whieh the ealeareuiis iiiuld tlie ones whii-li >!)uuJd he pro>|)eeletl most thorough ly. Iloek syilal)Ie iV.r roai MJ'TAI. eojisirnctinii js alrundanl'ly distrihiits'd ilirtniuii- out the Ilhnnaeaii district. Ainonext l!a> various ty|H-.s that, have be.'ti na of tlie llumacan district are predominatingly of a plastic ferruginous clayey nature, they are not snitahle for making a good grade of huilding hrick. The writer did not come across a single locality in the district Avhere hricks were heing made from them. KAOLIN At several places along the military road southwest of Caguas and west of K. 45, rhyolite ])orphyry dikes are exposed that have heen almost C(un- pletely altered to kaolin. In some instances these are almost pure white in color, Avhile in other cases they are hadly stained hy limonite. The mo\'ed by (^arefiil washing. There is a possibility that commercial (le])osits of kaolin may be present in this locality. THERMAL S PRIMES One thermal spring, the Yirella, located out on \\w ])laya northwest of Arroyo, lies within tlie borders of the Humacao district. ITodge (102t). pj). 225-22()) quotes the following analysis made l)y ^\v. Louis irernan- dez, of the Porto Pican Service of Sanitation, of the waters of this spring: Ich; SriEXTIFW survey of PORTO RICO Quantitative analysis Amon lit of water Tarts uer used. ("'ul)ic million. centimeters. Nitrates 02 100 Fi'ee aniinoiiia 04H2 .... Albuminoid ammonia 04S .... Total annnonia 01)12 KKK) Potassium (W,)! 5(X) Sodium 819 500 Litliium 00287 lO(KK) Sulphates 4598 1000 .Alau^nesium (K>12 1000 Calcium 1 . 0877 KKK) Olilorine l.:]5790 KM) Silicon dioxide :i078 KKK) (Vn-bonates as (^O, 1.00577 KK) Feiric oxide 00402 5.94702 1' »rts per million. Sodium nitrate i \7H9 Ammonium chloride l.*)74 Lithium chloride tM).*>4o Potassium chloride 1409 Sodium chloride 2.1991 Ma.irnesiinn suli)hate (K)4 < 'alcium sulphate 1 . K)88 Feri'ic cai'bonate 00759 Silicon dioxide *U)78 Calciiuji carbonate 1 .7721 5.82K)2 Total solids 5.8242 Q ua litativc ana his is I'romine neij^ative Iodine nej^ative HydrojLren sulphide ne,ij:ative Carbonic anhydride (free) nejj^atiA^e Free suli)hiU'ous anhydride ne,u:ative l*liosphoric aidiydride ne.irative P»oric acid negative Lithium (speetroscopically ) 1 positive Specific .gravity 1 . 0(K) Tem])erature .*>0° C. Alkaline to litmus and phen(»li)hthalein. FETTKIJ, GEOLOGY OF THE HUMACAO DISTRICT 197 Hodge attributes the high chloride content of the water from this spring to wind-carried salt spray from the near-by coast and to the fact that the w^aters issue through recent coastal plain deposits, which have not as yet been completely freed of their connate sodium chloride. Several small hath houses were at one time erected at the Yirella Spring, but these have now fallen into a state of disre])air. BIBLIOGRAPHY Daly, li. A. 1014. Igneous roeks and their origin, p. 90. New York. Berkey, C. p. 1915. (^Jeological reconnoissance of Porto Rico. Ann. N. Y. Acad. Sci., XXVr, pp. 1-70. Semmes, I). R. 1919. (Geology of the San Juan District, Porto Rico. Scientific Survey of I*orto Rico and the Virgin Islands, I, part 1. HouGE, E. T. 1920. Geology of the C'oamo-Guayama District, I^orto Rico. Scientific Survey of Porto Rico and the Virgin Islands, I, part 2. I.OBECK, A. K. 1922. The Physiography of I'orto Rico. Scientific Survey of I*orto Rico and tlie Virgin Islands, I, part 4. Mitchell, G. J. 1922. Geology of the I'once District, Porto Rico. Scientific Survey of I*orto Rico and the Virgin Islands, I, part o. HCCBARD, B. 1923. Geology of the Dares District, I*orto Rico. Scieutiftc Survey of l»orto Rico and tlie Virgin Islands, II, part 1. Fp:ttke, C. R. 1924. Magnetite deposits of eastern Porto Rico. Mining and Metallurgy. No. 1294-M. Feb., 1924. m I; ^mt M H5 B 528020 I UNIVERSITY OF MICHIGAN / 3 9015 03458 5615 I, ? 5" j». / ^\ f-, \ *^*fe.*a^*«*»- i i ,*l Ifc^^itJS^ . * 4.4^! >*^ ,